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The production of energy carriers based on renewable electricity via the Power-to-X (PtX) approach holds the key for a holistic transformation of our global industries from fossil fuels towards renewable energy sources. To compete with cheap fossils, PtX products demand energy-efficient processes and low-cost renewable electricity. Therefore, the import of PtX products from countries with high renewable energy potentials to countries with high energy demand presents a promising pathway. However, the question which set of PtX products qualifies as suitable for long-distance transport has not yet been answered. In this context, this paper assesses the energy and cost efficiency of five PtX energy carriers (methane, methanol, ammonia, liquefied hydrogen and hydrogen bound in LOHC). Furthermore, we evaluate the influence of fluctuating renewables, availability of water and transport distance in a case study for large-scale PtX production in Morocco. Our results show that the evaluated PtX pathway efficiencies vary between 40–52% (base cases) and 44–58% (optimistic cases). None of the pathways assessed is significantly affected in its overall efficiency by a ship transport over an exemplary distance of 4000 km. However, for longer transport distances the cost difference between the assessed pathways increases. The production cost of the PtX energy carriers (124–156 € per MWh) depends on the availability of excess heat, energy density of the product and, if required, liquefaction efforts. In summary, the paper reveals that the long-distance transport and import of PtX products present an interesting option for the ongoing integration of renewable electricity into our energy system and industries. The petrochemical and steel industries in particular, as well as heavy goods transport, shipping and aviation, will be highly dependent on these imported synthetic energy sources.

Oxymethylene Dimethyl Ethers (OMEs) are promising diesel fuel alternatives and interesting solvents for various industrial applications. In this report, a well-to-wheel life cycle assessment of short OME oligomers as produced via a Power-to-Liquid (PtL) pathway has been conducted. Variations in electricity and carbon dioxide supply as well as the hardware demand for the PtL plant components (e.g. PEM water electrolysis, carbon capturing, and 36 kta OME plant capacity) have been considered. Conventional diesel fuel is used as the comparative benchmark. In scenarios with a high share of renewable electricity well-to-wheel greenhouse gas emission for OME3–5 fuel is advantageous compared to fossil diesel. For the best case, well-to-wheel greenhouse gas emissions can be reduced by 86%, corresponding to 29 g(CO2eq) km−1 (OME3–5-fuel) compared to 209 g(CO2eq) km−1 (diesel fuel). However, these results are highly sensitive to the applied method with regard to system multifunctionality. A sensitivity analysis indicates that input electricity at ∼50 g(CO2eq) kWhel−1 enables well-to-wheel greenhouse gas emissions of

The synthesis of sustainable methanol based on renewable electricity generation, sustainable hydrogen (H2) and recycled carbon dioxide (CO2) represents an interesting sustainable solution to integrated renewable energy storage and platform chemical production. However, the business case for this electricity based product (denoted hereafter as eMeOH) under current market conditions (e.g. vs. conventional fossil methanol (fMeOH) production cost) and the appropriate implementation scenarios to increase platform attractiveness and adoption have to be highlighted. The aim of the following study was to perform a dynamic simulation and calculation of the cost of eMeOH production (where electricity is generated at a wind park in Germany), with comparison made to grid connected scenarios. Consideration of these scenarios is made with particular respect to the German energy market and potential for the reduction in fees/taxes (i.e. for electrolyser systems). This evaluation and indeed the results can be viewed in light of European Union efforts to support the implementation of such technologies. In this context, CO2 is sourced from EU relevant sources, namely a biogas or ammonia plant, the latter profiting from the resulting credit arising from CO2 certificate trading. Variation in electricity cost and the CO2 certificate price (in the presented sensitivity study) demonstrate a high cost reduction potential. Under the energy market conditions of Germany it is found that eMeOH production costs vary between €608 and 1453 per tonne based on a purely grid driven scenario, whilst a purely wind park supplied scenario results in €1028–1067 per tonne. The reported results indicate that the eMeOH production cost in Germany is still above the present (although variable) market price, with the economical evaluation indicating that electrolyser and H2 storage represent the lion share of investment and operational cost. Substitution of fMeOH results in CO2 avoidance costs between €365 and 430 per tonne of CO2eq avoided for green methanol produced in Germany. The presented assessment indicates that the eMeOH production cost in Germany will reach market parity in ca. 2030–2035 with the price for the avoidance of CO2eq turning from a cost to a benefit at around the same time. Optimistically, the cost is predominantly influenced by rapidly reducing renewable electricity costs as is already the case in South American and Arabic countries offering the potential for methanol production at a cost of