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Start Over Author "Anna-Marie Fuller" Publisher royal society of chemistry (rsc)
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1. Mononuclear TiN complexes formed by the facile multiple deprotonation of H3N·B(C6F5)3: the importance of chloride ligands

Author

Simon J. Lancaster, William Clegg, David L. Hughes, Anna-Marie Fuller, and Ross W. Harrington

Subjects
Stereochemistry, Ligand, Metals and Alloys, Nitridoborate, General Chemistry, Chloride, Medicinal chemistry, Catalysis, Surfaces, Coatings and Films, Electronic, Optical and Magnetic Materials, Ion, chemistry.chemical_compound, Deprotonation, chemistry, Materials Chemistry, Ceramics and Composites, medicine, medicine.drug
Abstract

The crystalline ion-pair [TiCl(NMe2)2(NMe2H)2]+[TiCl2{NB(C6F5)3}(NMe2H)2]−, in which the anion has a triply bonded nitridoborate ligand, is formed through the multiple activation of H3N·B(C6F5)3 when treated with [Ti(NMe2)3Cl].

Published
2008
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