1. Regulating the stability of 2D crystal structures using an oxidation state-dependent molecular conformation
- Author
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Katsuhiko Ariga, Amy L. McCarty, Francis D'Souza, Jonathan P. Hill, Melvin L. Zandler, Lionel R. Milgrom, Takashi Nakanishi, Tohru Tsuruoka, Yutaka Wakayama, and Wolfgang Schmitt
- Subjects
Models, Molecular ,Porphyrins ,Surface Properties ,Stereochemistry ,Molecular Conformation ,Electrons ,Crystal structure ,Crystallography, X-Ray ,Photochemistry ,Catalysis ,law.invention ,Metal ,chemistry.chemical_compound ,Adsorption ,Phenols ,Microscopy, Scanning Tunneling ,Oxidation state ,law ,Materials Chemistry ,Molecule ,Crystallization ,Metals and Alloys ,General Chemistry ,Porphyrin ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials ,chemistry ,Metals ,visual_art ,Ceramics and Composites ,visual_art.visual_art_medium ,Oxidation-Reduction - Abstract
The oxidation state of the phenol-substituted porphyrin TDtBHPP is coupled with its structure so that its 2-electron oxidation leads to a coplanarization of the molecule and a substantial stabilization of its surface self-assembled structures adsorbed at metal substrates.
- Published
- 2006
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