Zhang, Yinli, Zhang, Sheng, Sun, Lin, Yang, Qi, Han, Jing, Wei, Qing, Xie, Gang, Chen, Sanping, and Gao, Shengli
It is a tremendous challenge to prepare solvent-free dense energetic metal–organic frameworks (EMOFs), hence also to improve their stability and energetic performance. In this study, based on in situ microcalorimetry, an interpenetrating EMOF without solvent molecules, [Cu(tztr)]n (1, H2tztr = 3-(tetrazol-5-yl)triazole) was obtained, possessing high stability (Tdec = 360 °C) and outstanding energetic properties (ΔHdet = 7.53 kcal cm−3, D = 8.429 km s−1, P = 40.02 GPa). [ABSTRACT FROM AUTHOR]