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Theoretically, cuprous oxide (Cu 2 O) is a particularly excellent potential material, for the hole transport layer (HTL) of perovskite solar cells (PSCs). However, the photoelectric conversion efficiency (PCE) of its experimental samples is still not ideal. The main reasons for this include the material, and inherent and interface defects of Cu 2 O, but this can be improved by doping. In this research, Te- and Se/Te-doped Cu 2 O were experimentally and numerically studied to check the improvement of the material and interface properties. It was found that, for both the electrical and optical properties, the Se/Te-doped Cu 2 O performed considerably better than that which had been Te-doped and the pure Cu 2 O. Compared with the pure Cu 2 O thin film, the carrier mobility of the Se/Te-doped Cu 2 O thin film is improved from 60 cm 2 V -1 s -1 to 1297 cm 2 V -1 s -1 , and the bandgap changed from 2.05 eV to 1.88 eV. According to the results calculated using solar cell simulation software SCAPS, the cell efficiency of the Se/Te-doped Cu 2 O is improved by 22% when compared to that of pure Cu 2 O. This efficiency can be further improved to 34% by optimizing the thickness of the Se/Te-doped Cu 2 O thin film and the defect density of states between the material interfaces., Competing Interests: The authors declare that they have no known financial interests or personal relationships that could appear to influence the work in this paper., (This journal is © The Royal Society of Chemistry.)