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Accurate quantitative 13C NMR spectra can be accelerated by using EXACT (EXtended ACquisition Time) NMR methods which reduce Nuclear Overhauser Enhancement (NOE) during the FID. This allows 30–50% shorter experiment times to be used when achieving a given level of quantitative accuracy. [ABSTRACT FROM AUTHOR]

Pure-shift NMR enhances spectral resolution, but the optimal resolution can only be obtained at the cost of acquisition time. We propose to accelerate pure-shift acquisition using optimised ‘burst’ non-uniform sampling schemes [I. E. Ndukwe, A. Shchukina, K. Kazimierczuk and C. P. Butts, Chem. Commun., 2016, 52, 12769] and then reconstruct the undersampled signal mathematically. Here, we focus on the reliability of this reconstruction depending on the sampling scheme and present a workflow for the sampling optimization. It is ready to be implemented in routine measurements and yields a great improvement in reconstruction of challenging cases. [ABSTRACT FROM AUTHOR]

Accurate quantitative 13 C NMR spectra can be accelerated by using EXACT (EXtended ACquisition Time) NMR methods which reduce Nuclear Overhauser Enhancement (NOE) during the FID. This allows 30-50% shorter experiment times to be used when achieving a given level of quantitative accuracy.

Pure-shift NMR enhances spectral resolution, but the optimal resolution can only be obtained at the cost of acquisition time. We propose to accelerate pure-shift acquisition using optimised 'burst' non-uniform sampling schemes [I. E. Ndukwe, A. Shchukina, K. Kazimierczuk and C. P. Butts, Chem. Commun., 2016, 52, 12769] and then reconstruct the undersampled signal mathematically. Here, we focus on the reliability of this reconstruction depending on the sampling scheme and present a workflow for the sampling optimization. It is ready to be implemented in routine measurements and yields a great improvement in reconstruction of challenging cases.