1. Platinum-mediated monohydration of SO2.
- Author
-
Gimeno-Prat, Antonio, Cortés-Sanchón, Adrián, Martín, Antonio, Baya, Miguel, and Casas, José M.
- Subjects
- *
SULFUR dioxide , *LIGANDS (Chemistry) , *TAUTOMERISM - Abstract
The monohydration of SO2 has been achieved in solution mediated by a platinum-aquo complex. Benzamidate ligands play a key role along the process, acting as versatile proton shuttles. Finally, the platinum center allows the stabilization of benzimidic acid and a hydrogensulphite anion, the disfavored tautomers of benzamide and sulphonate, respectively. [ABSTRACT FROM AUTHOR]
- Published
- 2018
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