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Your search keyword '"Krumov, Mihail"' showing total 3 results
Start Over Author "Krumov, Mihail" Publisher royal society of chemistry
3 results on '"Krumov, Mihail"'

1. Reduction of (pddi)Cr reveals redox noninnocence via C–C bond formation amidst competing electrophilicity: [(cpta)CrMen]− (n = 0, 1) and [(pta)Cr]−.

Author

D'Arpino, Alexander A., Wolczanski, Peter T., MacMillan, Samantha N., Cundari, Thomas R., and Krumov, Mihail R.

Subjects
OXIDATION-reduction reaction, CYCLOPROPANE, CHELATES, ANIONS
Abstract

Reversible cyclopropane formation is probed as a means of redox noninnocence in diimine/diamide chelates via reduction and complex anion formation. Competition from imine attack renders complications in the latter approach, and electrochemical measurements with calculational support provide the rationale. [ABSTRACT FROM AUTHOR]

Published
2024
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2. Reduction of (pddi)Cr reveals redox noninnocence via C–C bond formation amidst competing electrophilicity: [(cpta)CrMen]− (n = 0, 1) and [(pta)Cr]−.

Author

D'Arpino, Alexander A., Wolczanski, Peter T., MacMillan, Samantha N., Cundari, Thomas R., and Krumov, Mihail R.

Subjects
*OXIDATION-reduction reaction, *CYCLOPROPANE, *CHELATES, *ANIONS
Abstract

Reversible cyclopropane formation is probed as a means of redox noninnocence in diimine/diamide chelates via reduction and complex anion formation. Competition from imine attack renders complications in the latter approach, and electrochemical measurements with calculational support provide the rationale. [ABSTRACT FROM AUTHOR]

Published
2024
Full Text
View/download PDF

3. Reduction of (pddi)Cr reveals redox noninnocence via C-C bond formation amidst competing electrophilicity: [(cpta)CrMe n ] - ( n = 0, 1) and [(pta)Cr] .

Author

D'Arpino AA, Wolczanski PT, MacMillan SN, Cundari TR, and Krumov MR

Abstract

Reversible cyclopropane formation is probed as a means of redox noninnocence in diimine/diamide chelates via reduction and complex anion formation. Competition from imine attack renders complications in the latter approach, and electrochemical measurements with calculational support provide the rationale.

Published
2024
Full Text
View/download PDF

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