50 results on '"Kingsley J"'
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2. Twisting the arm: structural constraints in bicyclic expanded-ring N-heterocyclic carbenes
3. N-alkyl functionalised expanded ring N-heterocyclic carbene complexes of rhodium(I) and iridium(I): structural investigations and preliminary catalytic evaluation
4. CHAPTER 9. NHC–Palladium Complexes in Catalysis
5. Abnormal NHCs: coordination, reaction chemistry and catalytic applications
6. Expanded ring N-heterocyclic carbenes: A comparative study of ring size in palladium (0) catalysed Mizoroki–Heck couplingElectronic supplementary information (ESI) available: Synthetic protocol and characterisation data for compounds 9, 10, 11, 13and 14with 6- and 7-membered R group comparison figures. See DOI: 10.1039/c1dt10596e
7. Rhodium and iridium complexes of an asymmetric bicyclic NHC bearing secondary pyridyl donorsCCDC reference numbers 820461and 820462. For crystallographic data in CIF or other electronic format see DOI: 10.1039/c1dt10582e.
8. A cw EPR and ENDOR investigation on a series of Cr(i) carbonyl complexes with relevance to alkene oligomerization catalysis: [Cr(CO)4L]+(L = Ph2PN(R)PPh2, Ph2P(R)PPh2)Electronic supplementary information (ESI) available: Figure S1: FSED EPR spectra; Figure S2a–S2g: Experimental and simulated cw EPR spectra; Figure S3a–S3g: Additional 1H ENDOR data; Figure S4: Additional 14N ENDOR data; Figure S5: Additional 31P ENDOR data; Table S1: Catalysis data. See DOI: 10.1039/c0dt00127a
9. Telomerisation of long-chain dienes with alcohols using Pd(IMes)(dvds) catalyst.
10. Expanded ring and functionalised expanded ring N-heterocyclic carbenes as ligands in catalysisElectronic supplementary information (ESI) available: Displacement ellipsoid plots for compounds 15band 22/23/24a,band graphs for alkene hydrogenations. CCDC reference numbers 733086–733106. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/b909834h
11. Oxidative addition of 2-substituted azolium salts to Group-10 metal zero complexes—A DFT studyElectronic supplementary information (ESI) available: Coordinates for metal zero reactants, 2-substitued azolium reactants, precursor complexes, transition structures, products, radicals, simple organics, and palladium alkyl complexes for bond energies; LANL2DZAUG:6-311+G(2d,p) basis set implementation. See DOI: 10.1039/b709914b
12. Synthesis of N-heterocyclic carbene palladium(ii) bis-phosphine complexes and their decomposition in the presence of aryl halidesElectronic supplementary information (ESI) available: Detailed synthesis and characterisation of [Pd(tmiy)X(P–P)]BF4, PdX2(P–P) and Pd(Me)X(P–P) complexes; crystal structure of Pd(dppp)I2. See DOI: 10.1039/b706053j
13. Chiral N-heterocyclic carbene ligands based on a biisoquinoline template.
14. The influence of N-substitution on the reductive elimination behaviour of hydrocarbyl–palladium–carbene complexes—a DFT study.
15. Influence of geometry on reductive elimination of hydrocarbylpalladiumcarbene complexes .
16. Palladium(ii) complexes of new OPN phosphine ligands and their application in homogeneously catalysed reactions of CO with alkenes or alkynes.
17. Theoretical studies of the oxidative addition of azolium salts to a model Wilkinson's catalyst.
18. Complexes of dimolybdenum(II) and dichromium(II) with 2-hydroxy-6-methylpyridine (Hmhp) and m-dimethoxybenzene (HDMP). Enthalpies of formation of [Mo2(mhp)4], [Cr2(mhp)4], [Mo2(mhp)2(OAc)2] and [Cr2(DMP)4].
19. Enthalpies of formation of hexakis(isopropoxy)-dimolybdenum and octakis-(isopropoxy)-dimolybdenum and the metal–metal bond enthalpy contributions.
20. Enthalpies of formation of homoleptic dimethylamido compounds of tantlum (V), molybdenum (III), molybdenum (IV), tungsten (III) and tungsten (VI). Enthalpy contributions of metal–metal triple bonds.
21. Enthalpies of combustion of tris-(acetylacetonato) derivatives of aluminium(III), gallium(III) and indium(III).
22. Carbonylation of hydrocarbylpalladium(II) complexes containing substituted pyridinecarboxylate chelating ligands. Steric and electronic manipulation of the CO-insertion mechanism.
23. Synthesis of methyl-palladium(II) and -platinum(II) complexes containing labile chelates and olefinic tertiary phosphine ligands: intramolecular insertion of an olefin into a palladium–carbon bond, and activation of a carbon–hydrogen bond by a platinum(II) complex
24. Synthesis and carbonylation studies on methylpalladium(II) complexes containing chelating pyridinecarboxylate ligands: dynamic behaviour of the ligands and implications for the carbonylation mechanism.
25. Unusually labile organoplatinum complexes: a mechanistic study of insertion–deinsertion into platinum–alkyl complexes of pyridine-2-carboxylic acid.
26. Molecular structures of mixed-ligand palladium(II) and platinum(II) alkyl complexes, including three isomorphous compounds.
27. Oligomerization and isomerization of olefins by catalysts derived from nickel complexes of dithio-β-diketonates.
28. Synthesis and carbonylation reactions of alkyl and phenyl complexes of palladium- and platinum-(II) containing β-diketonate type ligands.
29. A unique application of acid-Nafion as a co-catalyst and support.
30. Standard enthalpy of formation of bis(diethyldithiocarbamato)nickel(II) at 298 K and the nickel–sulphur bond energy.
31. Standard enthalpies of formation of the tetra-µ-acetato-derivatives of dimolybdenum(II), chromium(II)–molybdenum(II), dichromium(II), and dichromium(II) dihydrate, and di-µ-acetato-bis(pentane-2,4-dionato)dimolybdenum(II), and their metal–metal bond enthalpy contributions
32. Standard enthalpy of formation of bis(diethyldithiocarbamato)copper(II) at 298 K and the copper–sulphur bond energy.
33. The standard enthalpies of formation of tris(pentane-2,4-dionato)-molybdenum(III) and dioxobis(pentane-2,4-dionato)molybdenum(VI), and the molybdenum–pentane-2,4-dionate bond-enthalpy contributions.
34. Abnormal NHCs: coordination, reaction chemistry and catalytic applications
35. Ethene insertion into a palladium–acetyl bond: crystal structure of [Pd(CH2CH2COMe)(NC5H4CO2Me-2)(PPh3)]BF4, a novel reaction intermediate from the insertion process.
36. Twisting the arm: structural constraints in bicyclic expanded-ring N-heterocyclic carbenes.
37. N-alkyl functionalised expanded ring N-heterocyclic carbene complexes of rhodium(I) and iridium(I): structural investigations and preliminary catalytic evaluation.
38. Variable coordination of a chiral diphosphine containing an amidinium/NHC group within its backbone: μ-P,P', κ2-P,P' and κ3-P,C,P' coordination modes.
39. Monovalent chiral-at-copper complexes: halide-controlled diastereoselectivity.
40. Rhodium and iridium complexes of an asymmetric bicyclic NHC bearing secondary pyridyl donors.
41. A cw EPR and ENDOR investigation on a series of Cr(I) carbonyl complexes with relevance to alkene oligomerization catalysis: [Cr(CO)4L]+ (L = Ph2PN(R)PPh2, Ph2P(R)PPh2).
42. Expanded ring and functionalised expanded ring N-heterocyclic carbenes as ligands in catalysis.
43. Oxidative addition of 2-substituted azolium salts to Group-10 metal zero complexes--a DFT study.
44. Synthesis of N-heterocyclic carbene palladium(II) bis-phosphine complexes and their decomposition in the presence of aryl halides.
45. Chiral N-heterocyclic carbene ligands based on a biisoquinoline template.
46. The influence of N-substitution on the reductive elimination behaviour of hydrocarbyl-palladium-carbene complexes--a DFT study.
47. Influence of geometry on reductive elimination of hydrocarbyl-palladium-carbene complexes.
48. Palladium(II) complexes of new OPN phosphine ligands and their application in homogeneously catalysed reactions of CO with alkenes or alkynes.
49. Theoretical studies of the oxidative addition of azolium salts to a model Wilkinson's catalyst.
50. C-H activation of imidazolium salts by Pt(0) at ambient temperature: synthesis of hydrido platinum bis(carbene) compounds.
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