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The development of environmentally benign methods for the synthesis of nanomaterials has become increasingly relevant as chemists look to shape a more sustainable future. In this critical review, we present current work towards developing alternative methods for synthesizing a wide range of high-quality nanomaterials with predictable and controllable size, shape, composition, morphology and crystallinity. In particular, we focus on the inherent advantages of utilizing porous membrane templates, ultrasonic and microwave irradiation, alternative solvent systems, as well as biologically-inspired reagents as reasonably cost-effective, environmentally responsible methods to generate metal, metal oxide, fluoride, sulfide, selenide and phosphate nanomaterials. [ABSTRACT FROM AUTHOR]

Rare earth elements and several metals formerly uncommon in commerce are being introduced into new products, particularly as nanoscaled materials. Until recently, little attention has been paid to their sustainability issues. This perspective addresses these elements, their commercial uses, health and environment issues, sustainability, and suggests a path forward.