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Your search keyword '"Fraanje, Jan"' showing total 4 results
Start Over Author "Fraanje, Jan" Publisher royal society of chemistry
4 results on '"Fraanje, Jan"'

4. Synthesis of the cyclobutanone core of solanoeclepin A intramolecular allene butenolide photocycloaddition.

Author

Hue BT, Dijkink J, Kuiper S, Larson KK, Guziec FS Jr, Goubitz K, Fraanje J, Schenk H, van Maarseveen JH, and Hiemstra H

Subjects
4-Butyrolactone analogs & derivatives, Bridged Bicyclo Compounds chemical synthesis, Bridged Bicyclo Compounds chemistry, Bridged-Ring Compounds chemistry, Crystallography, X-Ray, Cyclization, Cyclobutanes chemical synthesis, Furans chemical synthesis, Hexanes chemistry, Ketones chemical synthesis, Models, Chemical, Molecular Structure, Photochemistry, Stereoisomerism, Bridged-Ring Compounds chemical synthesis, Cyclobutanes chemistry, Furans chemistry, Hexanes chemical synthesis, Ketones chemistry
Abstract

The compact tricyclic substructure of solanoeclepin A containing the cyclobutanone ring was prepared by using as the key step a highly regioselective intramolecular [2 + 2]-photocycloaddition reaction between one of the [small pi]-bonds of an allene and the CC double bond of a butenolide.

Published
2003
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