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Start Over Author "Clément Guibert" Publisher royal society of chemistry
1 results on '"Clément Guibert"'

1. 1-Phosphabarrelene complexes of palladium and their use in Suzuki–Miyaura coupling reactionsElectronic supplementary information (ESI) available: Experimental procedures and characterization data for 2, 3and 4, literature references for the prepared biaryls, Cartesian coordinates and energies for the optimized structures, three lowest frequencies, detailed information of the CDA calculations, and X-ray crystal data for 2, 3and 4. CCDC 699913–699915. For ESI and X-ray crystal data in CIF or other electronic format, see DOI: 10.1039/b814886d

Author

Matthias Blug, Clément Guibert, Xavier-Frederic Le Goff, Nicolas Mézailles, and Pascal Le Floch

Subjects
*PALLADIUM compounds, *COMPLEX compounds, *CHEMICAL reactions, *CHLORINE compounds, *CATALYSIS, *CHLORIDES
Abstract

A bulky 1-phosphabarrelene, 2, was obtained from the reaction of a phosphinine with benzyne; two palladium complexes of 2were successfully employed in the Suzuki–Miyaura coupling of several aryl chlorides with phenylboronic acid at a relatively low catalyst loading, and activated aryl chlorides were coupled at room temperature in the absence of strong bases. [ABSTRACT FROM AUTHOR]

Published
2009

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