Search

Cucurbit[n]uril supramolecular chemistry has developed rapidly since 2001 when different cucurbit[n]uril homologues (Q[n]) were successfully separated in pure form. The combination of Q[n] cavity size and various types of external stimuli has given birth to numerous types of Q[n]-based mechanically interlocked molecules (MIMs), including (pseudo)rotaxanes, catenanes, dendrimers and poly(pseudo)rotaxanes. In this review article, the important advances in the field of Q[n]-based MIMs over the past two decades are highlighted. This review also describes examples of heterowheel (pseudo)rotaxanes and poly(pseudo)rotaxanes involving Q[n]s, and reflects on the opportunities and challenges of constructing Q[n]-based stimuli-responsive MIMs. [ABSTRACT FROM AUTHOR]

The nature of mechanically interlocked molecules (MIMs) has continued to encourage researchers to design and construct a variety of high-performance materials. Introducing mechanically interlocked structures into polymers has led to novel polymeric materials, called mechanically interlocked polymers (MIPs). Rotaxane-based MIPs are an important class, where the mechanically interlocked characteristic retains a high degree of structural freedom and mobility of their components, such as the rotation and sliding motions of rotaxane units. Therefore, these MIP materials are known to possess a unique set of properties, including mechanical robustness, adaptability and responsiveness, which endow them with potential applications in many emerging fields, such as protective materials, intelligent actuators, and mechanisorption. In this review, we outline the synthetic strategies, structure-property relationships, and application explorations of various polyrotaxanes, including linear polyrotaxanes, polyrotaxane networks, and rotaxane dendrimers. [ABSTRACT FROM AUTHOR]

We present the successful construction of a new family of organometallic rotaxane-terminated dendrimers using neutral platinum–acetylides as the main scaffold. The fourth generation dendrimer has 24 rotaxane moieties on the surface termini in a monodisperse manner. [ABSTRACT FROM AUTHOR]

The development of multicomponent (supramolecular) systems that can perform predetermined functions under external control -- i.e., molecular devices -- is a challenging task in chemistry and a fascinating objective in the frame of a bottom-up approach to nanostructures. In this context light signals can be conveniently used both for supplying energy to the system and for probing its states and transformations. The aim of this tutorial review is to recall a few basic aspects of light-induced processes that can be used to "write" and "read" onto molecular and supramolecular systems. These principles are illustrated through some examples of artificial molecular devices and machines taken from our work, which provide a flavour of current research. They are molecular and supramolecular systems that operate and/or perform valuable functions by exploiting photoinduced energy- or electron-transfer processes, photoisomerization reactions, or photoinduced proton transfer. The choice of these examples was based on both their intrinsic importance for the referred topic and their educational value. In the last section of the review potential applications, limitations and future directions of the research in the field of artificial molecular devices and machines are also discussed. [ABSTRACT FROM AUTHOR]

Mechanically bonded macromolecules constitute a class of challenging synthetic targets in polymer science. The controllable intramolecular motions of mechanical bonds, in combination with the processability and useful physical and mechanical properties of macromolecules, ultimately ensure their potential for applications in materials science, nanotechnology and medicine. This tutorial reviewdescribes the syntheses and properties of a library of diverse mechanically bonded macromolecules, which covers (i) main-chain, side-chain, bridged, and pendant oligo/polycatenanes, (ii) main-chain oligo/polyrotaxanes, (iii) poly[c2]daisy chains, and finally (iv) mechanically interlocked dendrimers. A variety of highly efficient synthetic protocols—including template-directed assembly, step-growth polymerisation, quantitative conjugation, etc.—were employed in the construction of these mechanically interlocked architectures. Some of these structures, i.e., side-chain polycatenanes and poly[c2]daisy chains, undergo controllable molecular switching in a manner similar to their small molecular counterparts. The challenges posed by the syntheses of polycatenanes and polyrotaxanes with high molecular weights are contemplated. [ABSTRACT FROM AUTHOR]

Type III-B first generation [3]rotaxane and second generation [4]rotaxane dendrimers have been synthesized via (1) a modified copper-catalyzed alkyne–azide cycloaddition (CuAAC), (2) Glaser–Hay's acetylenic oxidative homo-coupling, and (3) amide formation. The dendron does not reveal obvious cytotoxicities in L929 fibroblast cells. The rotaxane dendrimers can capture ammonia and are switchable both in solution and on surfaces. [ABSTRACT FROM AUTHOR]