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A comparison of the analysis of respirable crystalline silica direct-on-filter methods using X-ray diffraction (XRD) and Fourier transform infrared (FT-IR) spectroscopy was undertaken using 253 real workplace air samples from road construction and tunnelling, coal mining, and kitchen benchtop manufacturing in Australia. Using pure α-quartz standards, XRD and FT-IR direct-on-filter analyses produced identical test results, however, the real workplace samples showed a clear discrepancy between FT-IR and XRD results with on average a 9% positive bias of the FT-IR results. The cause of the positive bias was due to matrix interferences which was confirmed by using synthetic mixture air samples. Approximately a third of the data by direct-on-filter method using FT-IR was assessed to be invalid based on the peak height ratio criterion due to excessive interferences and weight overload limitations. The XRD method showed better results due to less interference from the common matrices. XRD could handle up to twice the sample loading and at higher loadings up to 7 mg when a correction was applied. It was also able to achieve a lower limit of detection of 2 µg filter−1 when a slower scan condition was utilized. [ABSTRACT FROM AUTHOR]

ABSTRACT We have mapped 20 spectral lines in the Central Molecular Zone (CMZ) around the Galactic Centre, emitting from 85.3 to 93.3 GHz. This work used the 22-m Mopra radio telescope in Australia, equipped with the 8-GHz bandwidth University of New South Wales-Mopra Spectrometer (UNSW-MOPS) digital filter bank, obtaining ∼2 km s−1 spectral and ∼40 arcsec spatial resolution. The lines measured include emission from the c-C3H2, CH3CCH, HOCO+, SO, H13CN, H13CO+, SO, H13NC, C2H, HNCO, HCN, HCO+, HNC, HC3N, 13CS and N2H+ molecules. The area covered is Galactic longitude −07 to 18 and latitude −03 to 02, including the bright dust cores around Sgr A, Sgr B2, Sgr C and G1.6−0.025. We present images from this study and conduct a principal component analysis on the integrated emission from the brightest eight lines. This is dominated by the first component, showing that the large-scale distribution of all molecules is very similar. We examine the line ratios and optical depths in selected apertures around the bright dust cores, as well as for the complete mapped region of the CMZ. We highlight the behaviour of the bright HCN, HNC and HCO+ line emission, together with that from the 13C isotopologues of these species, and compare the behaviour with that found in extragalactic sources where the emission is unresolved spatially. We also find that the isotopologue line ratios (e.g. HCO+/H13CO+) rise significantly with increasing redshifted velocity in some locations. Line luminosities are also calculated and compared to that of CO, as well as to line luminosities determined for external galaxies. [ABSTRACT FROM AUTHOR]

Aims: To determine the antibacterial spectrum and cytotoxic activities of serrulatane compounds from the Australian plant Eremophila neglecta. Methods and Results: Antimicrobial activities of serrulatane compounds 8,19-dihydroxyserrulat-14-ene ( 1) and 8-hydroxyserrulat-14-en-19-oic acid ( 2) were tested against Gram-negative and Gram-positive bacteria including human and veterinary pathogens and some multidrug-resistant isolates. Minimum inhibitory concentrations (MICs) and minimum bactericidal concentrations (MBCs) of the compounds were determined by broth microdilution assay. Both compounds exhibited antibacterial activity against all Gram-positive test strains. They showed antimycobacterial activity against isolates of Mycobacterium fortuitum and Mycobacterium chelonae. Of the five Gram-negative bacteria tested, only Moraxella catarrhalis showed susceptibility to the compounds. Cytotoxic activities were tested in the Vero cell line. Compound 1 showed more activity than 2 in both antibacterial and cytotoxicity assays with cytotoxicity at concentrations similar to the MBC. Conclusions: Serrulatane compounds showed significant activity against medically important bacteria, with 1 exhibiting stronger antibacterial activity. However, they also displayed toxicity to mammalian cells. Significance and Impact of the Study: Serrulatanes are of interest as novel antibacterial compounds for use in biomedical applications; this study reports data obtained with a range of bacterial strains and mammalian cells, essential for assessing the capabilities and limitations of potential applicability of these compounds. [ABSTRACT FROM AUTHOR]

This paper presents a study of the envelope of the young stellar object (YSO) GGD30IR. What distinguishes this from most other YSOs is the elongated absorption feature seen in silhouette against the background emission in the Spitzer Galactic Legacy Infrared Midplane Survey Extraordinaire 8 μm Infrared Array Camera image of the region. The size and the symmetrical placement of GGD30IR in the centre of this feature suggest that it is an extended envelope, perhaps the remnant of the collapse of the GGD30 core. We have used the extinction in the envelope measured from (i) the reduction in the 8 μm background intensity and (ii) field star colour excesses, to estimate the envelope mass, obtaining values of 0.6 ± 0.2 and , respectively. To investigate the envelope further, we have obtained Australia Telescope Compact Array 3 mm continuum and HCO+ line observations of the region. The continuum emission at 3 mm arises from both a compact (unresolved; ≤730 au) core embedded in an extended envelope ∼18 000 au × 38 000 au in extent. We estimate the core mass to be 0.11 ± 0.02 . The HCO+ emission is extended in a direction perpendicular to the long axis of the envelope, suggesting it comes from an outflow. The spectral energy distribution (SED) provides a 2–24 μm spectral index, α= 1.0, which places GGD30IR in the Class I YSO category. Integrating the SED provides a luminosity of . [ABSTRACT FROM AUTHOR]

Gigahertz-peaked spectrum (GPS) radio sources are thought to be young objects which later evolve into Fanaro–Riley type I (FR I) and FR II radio galaxies. We have used the Australia Telescope 20 GHz (AT20G) survey catalogue to select a uniform sample of GPS sources with spectral peaks above 5 GHz, which should represent the youngest members of this class. In this paper, we present e-VLBI observations of 10 such objects which are associated with nearby galaxies and so represent a new population of local, low-power GPS sources. Our e-VLBI observations were carried out at 4.8 GHz with the Australia Telescope Long Baseline Array (LBA) using a real-time software correlator. All 10 sources were detected, and were unresolved on scales of ∼100 mas, implying that they are typically less than 100 pc in linear size. [ABSTRACT FROM AUTHOR]

We have used the Australia Telescope Compact Array (ATCA) at 95 GHz to carry out continuum observations of 130 extragalactic radio sources selected from the Australia Telescope 20 GHz (AT20G) survey. We use a triple-correlation method to measure simultaneous 20- and 95-GHz flux densities for these objects, and over 90 per cent of our target sources are detected at 95 GHz. We demonstrate that the ATCA can robustly measure 95-GHz flux densities with an accuracy of ∼10 per cent in a few minutes for sources stronger than about 50 mJy. We measure the distribution of radio spectral indices in a flux-limited sample of extragalactic sources, and show that the median 20–95 GHz spectral index does not vary significantly with flux density for . This finding allows us to estimate the extragalactic radio source counts at 95 GHz by combining our observed 20–95 GHz spectral-index distribution with the accurate 20-GHz source counts measured in the AT20G survey. Our derived 95-GHz source counts at flux densities above 80 mJy are significantly lower than those found by several previous studies. The main reason is that most radio sources with flat or rising spectra in the frequency range 5–20 GHz show a spectral turnover between 20 and 95 GHz. As a result, there are fewer 95-GHz sources (by almost a factor of 2 at 0.1 Jy) than would be predicted on the basis of extrapolation from the source populations seen in lower-frequency surveys. We also derive the predicted confusion noise in cosmic microwave background surveys at 95 GHz and find a value 20–30 per cent lower than previous estimates. The 95-GHz source population at the flux levels probed by this study is dominated by quasi-stellar objects with a median redshift . We find a correlation between optical magnitude and 95-GHz flux density which suggests that many of the brightest 95-GHz sources may be relativistically beamed, with both the optical and millimetre continuum significantly brightened by Doppler boosting. [ABSTRACT FROM AUTHOR]

The Australia Telescope 20-GHz (AT20G) Survey is a blind survey of the whole southern sky at 20 GHz (with follow-up observations at 4.8 and 8.6 GHz) carried out with the Australia Telescope Compact Array from 2004 to 2007. The Bright Source Sample (BSS) is a complete flux-limited subsample of the AT20G Survey catalogue comprising 320 extragalactic ) radio sources south of with Jy. Of these, 218 have near simultaneous observations at 8 and 5 GHz. In this paper we present an analysis of radio spectral properties in total intensity and polarization, size, optical identifications and redshift distribution of the BSS sources. The analysis of the spectral behaviour shows spectral curvature in most sources with spectral steepening that increases at higher frequencies (the median spectral index α, assuming , decreases from between 4.8 and 8.6 GHz to between 8.6 and 20 GHz), even if the sample is dominated by flat spectra sources (85 per cent of the sample has . The almost simultaneous spectra in total intensity and polarization allowed us a comparison of the polarized and total intensity spectra: polarized fraction slightly increases with frequency, but the shapes of the spectra have little correlation. Optical identifications provided an estimation of redshift for 186 sources with a median value of 1.20 and 0.13, respectively, for QSO and galaxies. [ABSTRACT FROM AUTHOR]

We present results of polarization observations at 1.4 GHz of the two fields imaged by the DASI experiment ( and , respectively). Data were taken with the Australia Telescope Compact Array with 3.4-arcmin resolution and ∼0.18-mJy beam−1 sensitivity. The emission is dominated by point sources, and we do not find evidence for diffuse synchrotron radiation even after source subtraction. This allows to estimate an upper limit of the diffuse polarized emission. The extrapolation to 30 GHz suggests that the synchrotron radiation is lower than the polarized signal measured by the DASI experiment by at least two orders of magnitude. This further supports the conclusions drawn by the DASI team itself about the negligible Galactic foreground contamination in their data set, improving by a factor of ∼5 the upper limit estimated by Leitch et al. The dominant point-source emission allows us to estimate the contamination of the cosmic microwave background (CMB) by extragalactic foregrounds. We computed the power spectrum of their contribution, and its extrapolation to 30 GHz provides a framework where the CMB signal should dominate. However, our results do not match the conclusions of the DASI team about the negligibility of point-source contamination, suggesting taking into account a source subtraction from the DASI data. [ABSTRACT FROM AUTHOR]