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Techniques based on electrical resistance and near-infrared (NIR) spectroscopy were used to determine the moisture content (MC) of logging residues and sweet sorghum. The MC of biomass is a factor to be controlled that can affect the quality of final products. To accurately measure the moisture in fragmented materials, it is essential to increase the bulk density of the materials by compression. The low bulk density increased the error from the oven-drying MC and the variation between repeated measurements. The calculated correction factor made it possible to use a commercial wood moisture meter for biomass materials. Ordinary least squares regression models built with the electrical resistance data achieved coefficients of determination (R2) of 0.933 and 0.833 with root mean square errors (RMSE) of 0.505 and 0.891, respectively, for the MC predictions of logging residue and sweet sorghum. Partial least squares regression models combined with NIR spectroscopy achieved R2 of 0.942 and 0.958 with RMSE of 1.318 and 3.681 for logging residue and sweet sorghum, respectively. In contrast to the electrical resistance-based models, the NIR-based models could predict the MC regardless of the bulk density of the materials. Data transformation by the second derivative and removal of outliers contributed to the improvement of the prediction of the NIR-based models.

A timber-concrete composite (TCC) slab composed of nail-laminated timber (NLT) and topping concrete (TC) was developed for flooring applications. The NLT was laminated alternately with lumber and plywood. To investigate the dimensional behavior of the TCC slab, the temperature, relative humidity (RH), and dimensional changes of the slab exposed to outdoor air were monitored for 205 days. Temperature change was directly transmitted to both components, and RH change was gradually transmitted to the NLT. Concrete pouring caused a sharp increase in NLT width, which was the laminating direction of the nails. This resulted from swelling of the wood because of the moisture in the concrete mixture and loosening of the nail lamination. The member composition for the nail-laminating system, fastener type, and concrete volume help to secure the dimensional stability of the NLT. Cracks in the TC caused width deformation, which was recovered by drying shrinkage of the TC. Correlation analysis among temperature, RH, and strain indicated that dimensional changes in NLT correlated strongly with RH, while those in TC correlated strongly with temperature. The correlation between longitudinal strain in the TC and strain in the three directions of the NLT was attributed to the notches designed for mechanical connection.

Techniques based on electrical resistance and near-infrared (NIR) spectroscopy were used to determine the moisture content (MC) of logging residues and sweet sorghum. The MC of biomass is a factor to be controlled that can affect the quality of final products. To accurately measure the moisture in fragmented materials, it is essential to increase the bulk density of the materials by compression. The low bulk density increased the error from the oven-drying MC and the variation between repeated measurements. The calculated correction factor made it possible to use a commercial wood moisture meter for biomass materials. Ordinary least squares regression models built with the electrical resistance data achieved coefficients of determination (R2) of 0.933 and 0.833 with root mean square errors (RMSE) of 0.505 and 0.891, respectively, for the MC predictions of logging residue and sweet sorghum. Partial least squares regression models combined with NIR spectroscopy achieved R2 of 0.942 and 0.958 with RMSE of 1.318 and 3.681 for logging residue and sweet sorghum, respectively. In contrast to the electrical resistance-based models, the NIR-based models could predict the MC regardless of the bulk density of the materials. Data transformation by the second derivative and removal of outliers contributed to the improvement of the prediction of the NIR-based models.

A timber-concrete composite (TCC) slab composed of nail-laminated timber (NLT) and topping concrete (TC) was developed for flooring applications. The NLT was laminated alternately with lumber and plywood. To investigate the dimensional behavior of the TCC slab, the temperature, relative humidity (RH), and dimensional changes of the slab exposed to outdoor air were monitored for 205 days. Temperature change was directly transmitted to both components, and RH change was gradually transmitted to the NLT. Concrete pouring caused a sharp increase in NLT width, which was the laminating direction of the nails. This resulted from swelling of the wood because of the moisture in the concrete mixture and loosening of the nail lamination. The member composition for the nail-laminating system, fastener type, and concrete volume help to secure the dimensional stability of the NLT. Cracks in the TC caused width deformation, which was recovered by drying shrinkage of the TC. Correlation analysis among temperature, RH, and strain indicated that dimensional changes in NLT correlated strongly with RH, while those in TC correlated strongly with temperature. The correlation between longitudinal strain in the TC and strain in the three directions of the NLT was attributed to the notches designed for mechanical connection.

A carboxymethyl cellulose (CMC)/polyethyleneimine (PEI) hybrid hydrogel was successfully prepared under green processing conditions. The CMC and PEI formed a polyelectrolyte complex, and the three-dimensional (3D) network structure was hardened by chemical crosslinking, resulting in suitable hydrogel properties. In the prepared CMC/PEI polyelectrolyte hydrogel, the surface charge was easily switched according to the pH change, and the resulting swelling and contraction was reversible. The pH sensitivity of the CMC/PEI hydrogel was effective in removing ionic dye contaminants, and as a result, it showed an excellent removal capacity of 319 mg/g for anionic acid orange (AO) and 129 mg/g for cationic methylene blue (MB). In addition, the CMC/PEI polyelectrolyte hydrogel maintained structural stability despite repeated changes in surface charge characteristics and shrinkage-swelling due to repeated pH conversion. As a result, in the reuse process through repeated adsorption and desorption, it showed an excellent reuse efficiency of more than 93% even after 10 reuse cycles.

Intumescent coating was studied relative to the fire performance of nail-laminated timber. Three NLT specimens were coated with three different intumescent coating thicknesses (1, 2, and 3 mm) in even-numbered laminae and compared to uncoated NLT specimens. As a result of the coating, the internal temperature of the coated specimen increased more slowly than that of the uncoated specimen. The average charring rate of the intumescent coating specimen was reduced by 12.8% (1-mm thickness), 14.1% (2-mm thickness), and 15.4% (3-mm thickness) compared with the uncoated specimen. However, statistical analysis showed there was no significance between 1-, 2-, and 3-mm coating thicknesses. The combustion of wide surfaces of timber laminae between the plywood was delayed due to the coated plywood, and the timber laminae became a one-dimensional charring rate problem. Therefore, if even laminae are coated with an intumescent, then the NLT can be designed with a one-dimensional charring rate condition.

Intumescent coating was studied relative to the fire performance of nail-laminated timber. Three NLT specimens were coated with three different intumescent coating thicknesses (1, 2, and 3 mm) in even-numbered laminae and compared to uncoated NLT specimens. As a result of the coating, the internal temperature of the coated specimen increased more slowly than that of the uncoated specimen. The average charring rate of the intumescent coating specimen was reduced by 12.8% (1-mm thickness), 14.1% (2-mm thickness), and 15.4% (3-mm thickness) compared with the uncoated specimen. However, statistical analysis showed there was no significance between 1-, 2-, and 3-mm coating thicknesses. The combustion of wide surfaces of timber laminae between the plywood was delayed due to the coated plywood, and the timber laminae became a one-dimensional charring rate problem. Therefore, if even laminae are coated with an intumescent, then the NLT can be designed with a one-dimensional charring rate condition.

A carboxymethyl cellulose (CMC)/polyethyleneimine (PEI) hybrid hydrogel was successfully prepared under green processing conditions. The CMC and PEI formed a polyelectrolyte complex, and the three-dimensional (3D) network structure was hardened by chemical crosslinking, resulting in suitable hydrogel properties. In the prepared CMC/PEI polyelectrolyte hydrogel, the surface charge was easily switched according to the pH change, and the resulting swelling and contraction was reversible. The pH sensitivity of the CMC/PEI hydrogel was effective in removing ionic dye contaminants, and as a result, it showed an excellent removal capacity of 319 mg/g for anionic acid orange (AO) and 129 mg/g for cationic methylene blue (MB). In addition, the CMC/PEI polyelectrolyte hydrogel maintained structural stability despite repeated changes in surface charge characteristics and shrinkage-swelling due to repeated pH conversion. As a result, in the reuse process through repeated adsorption and desorption, it showed an excellent reuse efficiency of more than 93% even after 10 reuse cycles.