Search

Abstract To study the influence of the thickness of a weak interlayer on the deformation and failure characteristics of composite rock mass. Based on the measured data of sand-mudstone interbedded floor rock mass in the Yima mining area, Henan Province, China. Using quartz sand, gypsum, and cement as similar materials make composite rock-like specimens with weak interlayers. The mechanical properties, deformation evolution process, failure characteristics, and acoustic emission laws of rock samples with different interlayer thicknesses under uniaxial compression were studied using the digital image correlation method and acoustic emission monitoring technology. The results show that: (1) With an increase in the thickness of the weak interlayer, there is a corresponding decrease in the compressive strength of the specimen. When the thickness of the weak interlayer exceeds 5 cm, the compressive strength of the composite rock specimen is even less than that of the single weak rock-like. (2) Under uniaxial compression conditions, the strain concentration zone first appears in the weak interlayer part of the composite rock-like specimen. As the pressure continues to increase, the specimen is the first to fail at the position of the maximum strain concentration zone. (3) The thickness of the weak interlayer is an important factor affecting the failure mode of composite rock-like specimens. With the increase of the thickness of the weak interlayer, the composite rock-like specimens change from overall failure to local failure. (4) With the increase of the thickness of the weak interlayer in the middle of the composite rock specimen, the maximum value of the energy released by the single acoustic emission event and the maximum value of the cumulative acoustic emission energy decrease during the compression failure process. The research results can provide a reference for the manufacture of composite rock mass with a weak interlayer and the deformation and failure analysis of composite rock mass.

Abstract The further practical applications of Li-rich layered oxides are impeded by voltage decay and redox asymmetry, which are closely related to the structural degradation involving irreversible transition metal migration. It has been demonstrated that the superstructure ordering in O2-type materials can effectively suppress voltage decay and redox asymmetry. Herein, we elucidate that the absence of this superstructure ordering arrangement in a Ru-based O2-type oxide can still facilitate the highly reversible transition metal migration. We certify that Ru in superstructure-free O2-type structure can unlock a quite different migration path from Mn in mostly studied cases. The highly reversible migration of Ru helps the cathode maintain the structural robustness, thus realizing terrific capacity retention with neglectable voltage decay and inhibited oxygen redox asymmetry. We untie the knot that the absence of superstructure ordering fails to enable a high-performance Li-rich layered oxide cathode material with suppressed voltage decay and redox asymmetry.

All-solid-state lithium batteries performance is affected by the solid electrolyte interphase (SEI) and electrically disconnected (“dead”) Li metal. Here, via operando NMR measurements, the authors quantify the Li metal in the SEI and “dead” regions using various inorganic solid-state electrolytes.

The formation of electrochemically inactive, or “dead”, lithium limits the reversibility of lithium metal batteries. Here the authors elucidate the (electro)chemical roles of ethylene gas produced from electrolyte decomposition on the formation of inactive lithium.

Mass spectrometry titration is useful for studying the chemistry of electrodes and electrolytes in batteries, giving insight into their failure mechanisms. Here, a protocol is established for reproducibly quantifying inactive lithium in anode-free lithium-metal batteries via mass spectrometry titration.