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Synthetic solutions of flutamide were subject to degradation using three advanced oxidation systems, namely UV/TiO2, UV/H2O2 and UV/H2O2/TiO2. Optimum conditions and degradation kinetics has been established for all three systems. The experimental results showed that all three systems can be successfully used for flutamide degradation with efficiencies higher than 99% and that advanced oxidation processes are showing good potential for degradation of organic pollutants that cannot be suitable removed/degraded using conventional wastewater treatment processes.

The degradation of some toxic pollutants like chlorobenzenes, nitrobenzene and 4-chloroaniline in various advanced oxidation system such as: UV/ H2O2, UV-VIS/Fe-TiO2 and UV-VIS/TiO2/ H2O2 were studied. The influence of working conditions (pH0, H2O2 dose, photocatalyst dose, pollutant initial concentration and irradiation time) on pollutant degradation rate constant and efficiency were investigated. For any studied advanced oxidation systems, pollutant degradation followed a pseudo first order kinetics. The degradation pathway of chlorinated and nitro aromatic pollutants includes initial •OH radicals attack to aromatic ring with hydroxylated intermediates formation, followed by their step by step oxidation up to carboxylic acids. Inorganic ions like Cl-, NO3-, NH4+ are also formed as mineralization products.

Collagen production is generating wastewater with high organic loading. This type of wastewater is still containing valuable compounds that can be reused in other applications. In order to investigate the possibility to recover and reuse these compounds the membrane based processes were investigated. Four types of commercial available membranes were characterised and then used to recover the proteins. The results proved that membrane based processes represent a viable alternative to treatment of wastewater generated by collagen production facilities when recovery of valuable compounds is envisaged. It has to be stressed that on the other hand only membrane processes do not assure too reach the quality norms imposed by the legislation for treated wastewater discharge into sewerage systems or natural receivers. Therefore, when proteins recovery and reuse is wanted, the membrane processes represent only the first step of wastewater treatment and should be followed by biological processes in order to obtain the organic loading quality indicators required for wastewater treatment plants discharges.

International Symposium "The Environment and the Industry", 26-27 September 2019, Bucharest, Romania, pp. 89-90

International Symposium "The Environment and the Industry", 26-27 September 2019, Bucharest, Romania, pp. 18-19