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This study aims to produce green zinc oxide nanoparticles (ZnO-NPs) derived from red seaweed (Pterocladia Capillacea) and evaluate their potential to absorb Ismate violet 2R (IV2R) ions from an aqueous solution. UV-vis spectrophotometry, Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), X-ray diffraction (XRD), and a Brunauer–Emmett–Teller surface area analysis (BET) were used to analyze the structural, morphological, and optical features of the synthesized nanoparticles. The change in color of the chemical solution revealed the formation of zinc oxide nanoparticles. The FTIR examination confirmed the synthesis of both Zn and ZnO nanoparticle powder, with a BET surface area of 113.751 m2 g−1 and an average pore size of 2.527 nm for the synthesized adsorbent. Furthermore, the maximum removal effectiveness of IV2R was 99% when 0.08 g ZnO-NPs was applied at a pH of 6, a temperature of 55 °C, and a contact time of 120 min. The dye adsorption capacity of the ZnO-NPs was 72.24 mg g−1. The adsorption process was also controlled by the Freundlich adsorption model and pseudo-second-order reaction kinetics. The adsorption of IV2R ions onto the ZnO-NPs could be represented as a nonideal and reversible sorption process of a nonuniform surface, according to Freundlich adsorption isotherms. In addition, the constant values of the model parameters were determined using various nonlinear regression error functions. Moreover, thermodynamic parameters such as entropy change, enthalpy change, and free energy change were investigated; the adsorption process was spontaneous and endothermic. The high capacity of the ZnO-NPs synthesized by red seaweed promotes them as promising substances for applications in water treatment for the removal of IV2R dye from aqueous systems.

Based on their functional groups, the use of various seaweed forms in phytoremediation has recently gained significant eco-friendly importance. The objective of this study was to determine whether a novel, sustainable, and ecologically acceptable adsorbent could be employed to remove toxic textile dye (Ismate Violet 2R (IV2R)) from an aqueous solution. The low-cost adsorbent was prepared from the nanoparticles form of the native red seaweed species, Pterocladia capillacea. Before and after the adsorption procedure, comprehensive characterization experiments on the bio-adsorbent were carried out, including BET, SEM, FTIR, UV, and dynamic light scattering (DLS) examination. The adsorption performance of the prepared nano-Pterocladia capillacea was optimized by adjusting operating parameters such as the initial dye concentration of 60 mg L−1, pH of 2, and contact time of 15 min, all of which were obtained by batch experiments in the lab. At the optimum conditions, the prepared adsorbent had maximum removal effectiveness of 87.2%. Most typical kinetics and isotherm models were used to test the experimental results. The equilibrium data fit well with the Langmuir isotherm model, with comparatively higher R2 values and fewer standard errors, while the pseudo-second-order kinetic model fits better with a decent correlation coefficient. Thermodynamic parameters revealed that the sorption process on nano-alga was exothermic and spontaneous.

Type 2 diabetes mellitus has been a major health issue with increasing morbidity and mortality due to macrovascular and microvascular complications. The urgent need for improved methods to control hyperglycemic complications reiterates the development of innovative preventive and therapeutic treatment strategies. In this perspective, xanthone compounds in the pericarp of the mangosteen fruit, especially α-mangostin (MGN), have been recognized to restore damaged pancreatic β-cells for optimal insulin release. Therefore, taking advantage of the robust use of nanotechnology for targeted drug delivery, we herein report the preparation of MGN loaded nanosponges for anti-diabetic therapeutic applications. The nanosponges were prepared by quasi-emulsion solvent evaporation method. Physico-chemical characterization of formulated nanosponges with satisfactory outcomes was performed with Fourier transform infra-red (FTIR) spectroscopy, differential scanning calorimetry (DSC), and scanning electron microscopy (SEM). Zeta potential, hydrodynamic diameter, entrapment efficiency, drug release properties, and stability studies at stress conditions were also tested. Molecular docking analysis revealed significant interactions of α-glucosidase and MGN in a protein-ligand complex. The maximum inhibition by nanosponges against α-glucosidase was observed to be 0.9352 ± 0.0856 µM, 3.11-fold higher than acarbose. In vivo studies were conducted on diabetic rats and plasma glucose levels were estimated by HPLC. Collectively, our findings suggest that MGN-loaded nanosponges may be beneficial in the treatment of diabetes since they prolong the antidiabetic response in plasma and improve patient compliance by slowly releasing MGN and requiring less frequent doses, respectively.

In this work, the quasi-solid-state polymer electrolyte containing poly(vinyl alcohol)-polypyrrole as a polymer host, potassium iodide (KI), iodine (I2), and different plasticizers (EC, PC, GBL, and DBP) was successfully prepared via the solution casting technique. Fourier transform infrared spectroscopy (FTIR) was used to analyze the interaction between the polymer and the plasticizer. X-ray diffraction confirmed the reduction of crystallinity in the polymer electrolyte by plasticizer doping. The ethylene carbonate-based polymer electrolyte showed maximum electrical conductivity of 0.496 S cm−1. The lowest activation energy of 0.863 kJ mol−1 was obtained for the EC-doped polymer electrolyte. The lowest charge transfer resistance Rct1 was due to a faster charge transfer at the counter electrode/electrolyte interface. The polymer electrolyte containing the EC plasticizer exhibited an average roughness of 23.918 nm. A photo-conversion efficiency of 4.19% was recorded in the DSSC with the EC-doped polymer electrolyte under the illumination of 100 mWcm−2.

Environmental nanotechnology has received much attention owing to its implications on environmental ecosystem, and thus is promising for the elimination of toxic elements from the aquatic surface. This work focuses on Cu-doped ZnSe nanoparticles using the co-precipitation method. The synthesized Cu-doped ZnSe nanoparticles were examined for structural, optical, and morphological properties with the help of XRD, FTIR, UV/vis diffuse reflection spectroscopy (DRS), FESEM, TEM, and XPS. The synthesized Cu-doped ZnSe nanoparticles revealed the presence of Cu2+ in the ZnSe lattice, which has been shown to take a predominant role for enhanced catalysis in the Cu-doped ZnSe nanoparticles. The synthesized Cu-doped ZnSe nanoparticles were investigated for their catalytic and antibacterial activities. The 0.1 M copper-doped ZnSe nanoparticles exhibited the highest rate of degradation against the methyl orange dye, which was found to be 87%. A pseudo-first-order kinetics was followed by Cu-doped ZnSe nanoparticles with a rate constant of 0.1334 min−1. The gram-positive and gram-negative bacteria were used for investigating the anti-bacterial activity of the Cu-doped ZnSe nanoparticles. The Cu-doped ZnSe nanoparticles exhibited enhanced photocatalytic and antibacterial activity.

This paper presents an estimation of the adsorptive potential of multiwalled carbon nanotubes (MWCNTs) and modified poly (acrylonitrile-co-styrene) with activated carbon for the uptake of reactive red 35 (RR35) dye from aqueous solution by a batch system. MWCNT adsorbent was synthesized by encapsulation via in situ polymerization. The copolymer material of poly (acrylonitrile-styrene) P (AN-co-ST) was prepared in a ratio of 2:1 V/V by the precipitation polymerization process. The prepared composites’ properties were characterized by FTIR, SEM, Raman, mean particle size (PSA), and XRD analysis. The PSA of the copolymeric material was determined to be 450.5 and 994 nm for MWCNTs and P(AN-co-St)/AC, respectively. Moreover, the influences of different factors, for example pH (2–10), adsorbents dosage (0.005–0.04 g), contact time (5–120 min), initial dye concentration (10–50 mg L−1), and temperature (25–55 °C). The optimum values were determined to be 2 and 4 pH, 10 mg L−1 of RR35 dye, and 0.04 g of adsorbents at early contact time. Furthermore, the adsorption isotherm was studied using Langmuir, Freundlich, Tempkin, and Halsey models. Maximum capacity qmax for MWCNTS and P (AN-co-St)/AC was 256.41 and 30.30 mg g−1, respectively. The investigational kinetic study was appropriated well via a pseudo second-order model with a correlation coefficient around 0.99. Thermodynamic study displayed that the removal of RR35 is exothermic, a spontaneous and physisorption system. The adsorption efficiency reduced to around 54–55% of the RR35 after four cycles of reuse of the adsorbents at 120 min.

In this study, a multi-walled carbon nanotube (MWCNT) was synthesized and used as an adsorbent for the removal of Ismate violet 2R dye from contaminated water. The morphology and structure of the synthesized adsorbent were examined via the Brunauer–Emmett–Teller (BET) surface area, X-ray powder diffraction (XRD) analysis, infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), and Raman spectroscopy. The effects of an MWCNT on the removal of IV2R were examined via a batch method using different factors such as pH, agitation time, adsorbent dosage, temperature, and initial dye concentration. The results showed that, at the acidic pH 4, 0.08 g of an MWCNT with 10 mg L−1 at 120 min realized the favorable removal of IV2R dye using an MWCNT. Under these operation conditions, the maximum elimination efficiency for real wastewater reached 88.2%. This process benefits from the ability to remove a large amount of dye (approximately 85.9%) in as short as 10 min using 0.005 g of MWCNTs. Moreover, the investigational isotherm data were examined by different models. The equations of error functions were used in the isotherm model to show the most appropriate isotherm model. The highest adsorption capacity for the removal of the dye was 76.92 mg g−1 for the MWCNT. Moreover, the regression data indicated that the adsorption kinetics were appropriate with a pseudo-second order and an R2 of 0.999. The thermodynamic study showed that the removal of IV2R is an endothermic, spontaneous, and chemisorption process. The MWCNT compound appears to be a new, promising adsorbent in water treatment, with 91.71% regeneration after three cycles.