1. Low-Cost CuIn1−xGaxSe2 Ultra-Thin Hole-Transporting Material Layer for Perovskite/CIGSe Heterojunction Solar Cells
- Author
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Ewa Popko, Lung-Chien Chen, Chzu-Chiang Tseng, Liann-Be Chang, Kuan-Lin Lee, K. Gwozdz, Ming-Jer Jeng, G.M. Wu, Lucjan Jacak, and Wu-Shiung Feng
- Subjects
Materials science ,Annealing (metallurgy) ,02 engineering and technology ,Substrate (electronics) ,010402 general chemistry ,01 natural sciences ,lcsh:Technology ,law.invention ,lcsh:Chemistry ,law ,Solar cell ,General Materials Science ,Instrumentation ,lcsh:QH301-705.5 ,perovskite ,Perovskite (structure) ,Fluid Flow and Transfer Processes ,MoSe2 ,business.industry ,lcsh:T ,Process Chemistry and Technology ,Photovoltaic system ,Energy conversion efficiency ,General Engineering ,Heterojunction ,CIGSe ,021001 nanoscience & nanotechnology ,lcsh:QC1-999 ,0104 chemical sciences ,Computer Science Applications ,lcsh:Biology (General) ,lcsh:QD1-999 ,lcsh:TA1-2040 ,Optoelectronics ,C60 ,0210 nano-technology ,business ,lcsh:Engineering (General). Civil engineering (General) ,Layer (electronics) ,lcsh:Physics ,hole-transporting material (HTM) - Abstract
This paper presents a new type of solar cellwith enhanced optical-current characteristics using an ultra-thin CuIn1&minus, xGaxSe2 hole-transporting material (HTM) layer (<, 400 nm). The HTM layer was between a bi-layer Mo metal-electrode and a CH3NH3PbI3 (MAPbI3) perovskite active absorbing material. It promoted carrier transportand led to an improved device with good ohmic-contacts. The solar cell was prepared as a bi-layer Mo/CuIn1&minus, xGaxSe2/perovskite/C60/Ag multilayer of nano-structures on an FTO (fluorine-doped tin oxide) glass substrate. The ultra-thin CuIn1&minus, xGaxSe2 HTM layers were annealed at various temperatures of 400, 500, and 600 °, C. Scanning electron microscopy studies revealed that the nano-crystal grain size of CuIn1&minus, xGaxSe2 increased with the annealing temperature. The solar cell results show an improved optical power conversion efficiency at ~14.2%. The application of the CuIn1&minus, xGaxSe2 layer with the perovskite absorbing material could be used for designing solar cells with a reduced HTM thickness. The CuIn1&minus, xGaxSe2 HTM has been evidenced to maintain a properopen circuit voltage, short-circuit current density and photovoltaic stability.
- Published
- 2019
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