1. Fluid Evolution, H-O Isotope and Re-Os Age of Molybdenite from the Baiyinhan Tungsten Deposit in the Eastern Central Asian Orogenic Belt, NE China, and Its Geological Significance
- Author
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Yunpeng Guo, Zhaochong Zhang, Qingdong Zeng, Jinhang Lu, and Ruiliang Wang
- Subjects
inorganic chemicals ,Wolframite ,lcsh:QE351-399.2 ,010504 meteorology & atmospheric sciences ,H-O isotope ,Geochemistry ,engineering.material ,010502 geochemistry & geophysics ,01 natural sciences ,complex mixtures ,Re-Os dating ,Petrography ,Magmatic water ,Fluid inclusions ,Quartz ,0105 earth and related environmental sciences ,Isochron ,lcsh:Mineralogy ,Chemistry ,technology, industry, and agriculture ,Geology ,respiratory system ,eastern Central Asian Orogenic Belt ,Geotechnical Engineering and Engineering Geology ,fluid inclusions ,Molybdenite ,engineering ,Meteoric water ,quartz-vein tungsten deposit - Abstract
The quartz-vein-type Baiyinhan tungsten deposit is located at the eastern part of the Central Asian Orogenic Belt, NE China. Analyses of fluid inclusions, H-O isotope of quartz and Re-Os isotope of molybdenite were carried out. Three stages of mineralization were identified: The early quartz + wolframite + bismuth stage, the middle quartz + molybdenite stage and the late calcite + fluorite stage. Quartz veins formed in the three stages were selected for the fluid inclusion analysis. The petrographic observation and fluid inclusion microthermometry results revealed three types of fluid inclusions: CO2-H2O (C-type), liquid-rich (L-type) and vapor-rich (V-type). The homogenization temperatures of C-type, V-type and L-type inclusions were 233&ndash, 374 °, C, 210&ndash, 312 °, C, and 196&ndash, 311 °, C, respectively. The salinity of the three types of inclusions was identical, varying in the range of 5&ndash, 12 wt%. The H-O isotope analyses results showed that quartz had &delta, 18OH2O and &delta, DSMOW compositions of &minus, 2.6&permil, to 4.3&permil, and &minus, 97&permil, to &minus, 82&permil, respectively, indicating that the ore-forming fluids were mainly derived from magmatic water with a minor contribution of meteoric water. The addition of meteoric water reduces the temperature and salinity of the ore-forming fluids, which leads to a decrease of the solubility of tungsten and molybdenum in the fluids and eventually the precipitation of minerals. Re-Os isotopic analysis of five molybdenite samples yielded an isochron age of 139.6 ±, 7.6 Ma (2&sigma, ) with an initial 187Os of &minus, 0.05 ±, 0.57 (MSWD = 3.5). Rhenium concentrations of the molybdenite samples were between 3.1 ug/g and 8.5 ug/g. The results suggest that the metals of the Baiyinhan deposit have a crust origin, and the mineralization is one episode of the Early Cretaceous tungsten mineralization epoch which occurred at the eastern part of the Central Asian Orogenic Belt.
- Published
- 2020
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