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Thanks to the VIR spectrometer onboard NASA’s Dawn spacecraft, which orbited Vesta in 2011–2012, thousands of hyperspectral images of its surface have been collected. The mission confirmed the HED (Howardite–Eucrite–Diogenite) meteorite composition of Vesta. Moreover, the VIR spectrometer detected the 2.8 µm absorption band, due to the presence of the OH molecule. In this work, we took advantage of the newly calibrated data of the VIR spectrometer by characterizing new spectral features thanks to the improved signal-to-noise (S/N) ratio for these spectra. The main goals of this work are as follows: (1) to characterize Vesta’s surface in the visible range and (2) to confirm, reinforce and characterize the OH distribution on Vesta by studying the 2.8 µm band and looking for OH combination bands around 2.2–2.4 µm. A possible relation between the 1.9 µm absorption band due to the presence of pyroxenes and the one at 0.5 µm was analyzed. Finally, the analysis of hydroxyl absorption bands evidenced an anti-correlation between the abundance of hydroxyl-bearing molecules and the surface reflectance. This confirms that the hydroxyl presence is linked to the dark units on Vesta.

Linear features are very common on asteroid surfaces. They are generally formed after impact and provide information about asteroid evolution. This work focuses on a mineralogical and spectral analysis of the main linear features on the 1/Ceres surface, having both tectonic (Samhain Catena’s pit chains) and geomorphic origins, i.e., generated by ejecta material (Occator ejecta, Dantu’s secondary radial chains, secondary radial chains generated from the Urvara impact). The analysis is based on spectral parameters defined by the Dawn’s VIR imaging spectrometer data, as albedo and depths of the bands centered at approximately 2.7, 3.1, 3.4 and 3.9 mm. The geomorphic linear features show spectral variations with respect to the surroundings, i.e., ammoniated phyllosilicates band depth shallowing is caused by the presence of material originating in a different region or dehydration caused by impact. The Samhain Catena does not show any mineralogical variation, due to its tectonic origin. The spectral behavior of Ceres’ linear features is similar to that observed on other asteroids (Vesta, Eros) and can be diagnostic in discerning the origin of linear features. Then, we searched spectral signatures of organics in the Samhain Catena region, since they are expected to form at depth due to internal processes: the absence of such signatures indicates that either they form at a larger depth or that their subsurface distribution is uneven.

Visual-to-infrared (VIS-IR) remote sensing observations of different classes of outer solar system objects indicate the presence of water ice and organics. Here, we present laboratory reflectance spectra in the 0.5–4.2 μm spectral range of binary particulate mixtures of water ice, organics analogue (kerite), and an opaque iron sulphide phase (pyrrhotite) to investigate the spectral effects of varying mixing ratios, endmember grain size, and mixing modality. The laboratory spectra are also compared to different implementations of the Hapke reflectance model (Hapke, 2012). We find that minor amounts (≲1 wt%) of kerite (investigated grain sizes of 45–63 μm and &lt, 25 μm) can remain undetected when mixed in coarse-grained (67 ± 31 μm) water ice, suggesting that organics similar to meteoritic insoluble organic matter (IOM) might be characterized by larger detectability thresholds. Additionally, our measurements indicate that the VIS absolute reflectance of water ice-containing mixtures is not necessarily monotonically linked to water ice abundance. The latter is better constrained by spectral indicators such as the band depths of water ice VIS-IR diagnostic absorptions and spectral slopes. Simulation of laboratory spectra of intimate mixtures with a semi-empirical formulation of the Hapke model suggests that simplistic assumptions on the endmember grain size distribution and shape may lead to estimated mixing ratios considerably offset from the nominal values. Finally, laboratory spectra of water ice grains with fine-grained pyrrhotite inclusions (intraparticle mixture) have been positively compared with a modified version of the Hapke model from Lucey and Riner (2011).