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Recently, the natural polymer polysaccharide konjac glucomannan (KGM) has received attention as a promising adsorbent in water treatment due to its low toxicity, cost-effectiveness and biocompatibility. However, the high-level water absorbency of KGM makes it difficult to recover in water treatment. In this study, by combining KGM with magnetic nanoparticles, KGM-based magnetic nanoparticles (KGM-Fe3O4 NPs) with excellent adsorption properties and recyclability for heavy metals were prepared using an one-step precipitation method. The as-prepared KGM-Fe3O4 NPs have a spherical morphology of superparamagnetism with a small particle size (ca. 7.0 nm) and a large specific surface area (160.1 m2·g−1). Taking Cr(VI) as the target heavy metal ion, the above nanoparticles have a high adsorption capacity and fast adsorption rate for Cr(VI). The pseudo-second order kinetic model is more suitable to describe the adsorption process of Cr(VI) by KGM-Fe3O4 NPs, and the maximum adsorption capacity of Cr(VI) onto KGM-Fe3O4 NPs was calculated to be 41.67 mg·g−1 using the Langmuir isotherm model. In addition, KGM-Fe3O4 NPs with adsorbed heavy metal ions can be quickly recovered from a solution, regenerated, and reused in the next cycle. KGM-based Fe3O4 nanoparticles are promising adsorbents that show significant reusability for the removal of metal ions in water and wastewater treatment.

The occurrence of Triclosan (TCS) in natural aquatic systems has been drawing increasing attention due to its endocrine-disruption effects as well as for the development of antibiotic resistances. Wastewater discharge is the main source of water contamination by TCS. In this study, the removal of TCS in microbial fuel cells (MFCs) was carefully investigated. A 94% removal of TCS was observed with 60 mV electricity generation as well as a slight drop in pH. In addition, we found that adsorption also contributed to the removal of TCS in aqueous solution and 21.73% and 19.92% of the total mass was adsorbed to the inner wall of the reactor and to the electrode, respectively. The results revealed that the attenuation of TCS depends on both biodegradation and physical adsorption in the anode chamber. Thus, the outcomes of our study provide a better understanding of the TCS removal mechanism in MFCs.

Au nanoparticles decorated mesoporous MnFe2O4 nanocrystal clusters (MnFe2O4/Au hybrid nanospheres) were used for the electrochemical sensing of As(III) by square wave anodic stripping voltammetry (SWASV). Modified on a cheap glass carbon electrode, these MnFe2O4/Au hybrid nanospheres show favorable sensitivity (0.315 μA/ppb) and limit of detection (LOD) (3.37 ppb) toward As(III) under the optimized conditions in 0.1 M NaAc-HAc (pH 5.0) by depositing for 150 s at the deposition potential of −0.9 V. No obvious interference from Cd(II) and Hg(II) was recognized during the detection of As(III). Additionally, the developed electrode displayed good reproducibility, stability, and repeatability, and offered potential practical applicability for electrochemical detection of As(III) in real water samples. The present work provides a potential method for the design of new and cheap sensors in the application of electrochemical determination toward trace As(III) and other toxic metal ions.