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This study investigated the effect of adding La–Ce mixed rare earths and Sr on the microstructure and mechanical properties of AlSi10MnMg alloy. The experiment utilized different combinations of modifiers, including single La–Ce rare earths, single Sr, and the combined addition of La–Ce mixed rare earths and Sr. This study compared their effects on grain refinement, the modification of the α-Al phase and eutectic silicon phase, and tensile properties and hardness. The results showed that the combined modification of Sr and mixed rare earth elements significantly refined the grains, optimized the morphology of the α-Al phase and eutectic silicon phase, and improved the overall mechanical properties of the aluminum alloy. Under the combined modification, the addition of 0.02 wt.% Sr and 0.1 wt.% RE (La–Ce mixed rare earths) exhibited the most pronounced refining effect. The secondary dendrite arm spacing (SDAS) was reduced by 59.18%. The eutectic silicon phase transformed from coarse needle-like shapes to fine fibrous or granular forms, with an aspect ratio reduction of 69.39%. Meanwhile, the alloy’s tensile strength and hardness were significantly improved. The tensile strength increased to 240 MPa, achieving an increase of 23.08%; the yield strength increased to 111 MPa, achieving an increase of 18.09%; and the elongation reached 7.3%, achieving an increase of 73.81%. This indicates that the proper addition of Sr and mixed rare earths can significantly optimize the microstructure and enhance the mechanical properties of AlSi10MnMg alloy, providing an effective method for the preparation of high-performance heat-treatment-free aluminum alloys.

The occurrence of bone disorders is steadily increasing worldwide. Bone tissue engineering (BTE) has emerged as a promising alternative to conventional treatments of bone defects, developing bone scaffolds capable of promoting bone regeneration. In this research, biomimetic scaffolds based on ion-substituted calcium phosphates, derived from cuttlefish bone, were prepared using a hydrothermal method. To synthesize Mn2+-substituted scaffolds, three different manganese concentrations (corresponding to 1, 2.5, and 5 mol% Mn substitutions for Ca into hydroxyapatite) were used. Also, syntheses with the simultaneous addition of an equimolar amount (1 mol%) of two (Mg2+ and Sr2+) or three ions (Mn2+, Mg2+, and Sr2+) were performed. A chemical, structural, and morphological characterization was carried out using X-ray diffraction, Fourier transform infrared spectroscopy, and scanning electron microscopy. The effects of the ion substitutions on the lattice parameters, crystallite sizes, and fractions of the detected phases were discussed. Multi-substituted (Mn2+, Mg2+, and Sr2+) scaffolds were coated with polycaprolactone (PCL) using simple vacuum impregnation. The differentiation of human mesenchymal stem cells (hMSCs), cultured on the PCL-coated scaffold, was evaluated using histology, immunohistochemistry, and reverse transcription–quantitative polymerase chain reaction analyses. The expression of collagen I, alkaline phosphatase, and dentin matrix protein 1 was detected. The influence of PCL coating on hMSCs behavior is discussed.

Strontium is a common radionuclide in radioactive waste, and its release into the environment can cause enormous damage to the ecosystem environment. In this study, the natural mineral allophane was selected as the substrate to prepare solidified ceramic products by cold pressing/sintering to solve the problem of the final disposal of radioactive strontium. Ceramic solidified products with various crystal structures were successfully prepared, and the microscopic morphology and energy-dispersive spectroscopy images of the samples showed a uniform distribution of Sr in the solidified products. Sr2Al2SiO7 and SrAl2Si2O8, which can stably solidify strontium, were formed in the solidified products, and the structural characteristics and stability of the above-mentioned substances were analyzed from the perspective of quantum chemical calculations using density functional theory. The calculation results showed that the overall deformation resistance of Sr2Al2SiO7 was higher than that of SrAl2Si2O8. Considering the isomorphic substitution effect of CaO impurities, we inferred that a mixed-crystalline structure of Ca2−xSrxAl2SiO7 may be present in the solidified products.

Laboratory modeling of Cs, Sr, U, Pu immobilization by phytoplankton of the river Upa, affected after the Chernobyl accident, has been carried out. Certain conditions are selected for strong fixation of radionuclides in bottom sediments due to biogeochemical processes. The process of radionuclide removal from the water phase via precipitation was based on their accumulation by phytoplankton, stimulated by nitrogen and phosphorus sources. After eight days of stimulation, planktonic phototrophic biomass, dominated by cyanobacteria of the genus Planktothrix, appears in the water sample. The effectiveness of U, Pu and Sr purification via their transfer to bottom sediment was observed within one month. The addition of ammonium sulfate and phosphate (Ammophos) led to the activation of sulfate- and iron-reducing bacteria of the genera Desulfobacterota, Desulfotomaculum, Desulfosporomusa, Desulfosporosinus, Thermodesulfobium, Thiomonas, Thiobacillus, Sulfuritallea, Pseudomonas, which form sulphide ferrous precipitates such as pyrite, wurtzite, hydrotroillite, etc., in anaerobic bottom sediments. The biogenic mineral composition of the sediments obtained under laboratory conditions was verified via thermodynamic modeling.

Fusarium keratoplasticum is the Fusarium species most commonly associated with human infections (fusariosis). Antifungal treatment of fusariosis is often hampered by limited treatment options due to resistance towards azole antifungals. The mechanisms of antifungal resistance and sterol biosynthesis in fusaria are poorly understood. Therefore, in this study we assessed the transcriptional response of F. keratoplasticum when exposed to voriconazole. Our results revealed a group of dramatically upregulated ergosterol biosynthesis gene duplicates, most notably erg6A (912-fold), cyp51A (52-fold) and ebp1 (20-fold), which are likely part of an alternative ergosterol biosynthesis salvage pathway. The presence of human cholesterol biosynthesis gene homologs in F. keratoplasticum (ebp1, dhcr7 and dhcr24_1, dhcr24_2 and dhcr24_3) suggests that additional sterol biosynthesis pathways may be induced in fusaria under other growth conditions or during host invasion. Voriconazole also induced the expression of a number of ABC efflux pumps. Further investigations suggested that the highly conserved master regulator of ergosterol biosynthesis, FkSR, and the pleiotropic drug resistance network that induces zinc-cluster transcription factor FkAtrR coordinate the response of FSSC species to azole antifungal exposure. In-depth genome mining also helped clarify the ergosterol biosynthesis pathways of moulds and provided a better understanding of antifungal drug resistance mechanisms in fusaria.

The transition metal-based catalysts for the elimination of greenhouse gases via methane reforming using carbon dioxide are directly or indirectly associated with their distinguishing characteristics such as well-dispersed metal nanoparticles, a higher number of reducible species, suitable metal–support interaction, and high specific surface area. This work presents the insight into catalytic performance as well as catalyst stability of CexSr1−xNiO3 (x = 0.6–1) nanocrystalline perovskites for the production of hydrogen via methane reforming using carbon dioxide. Strontium incorporation enhances specific surface area, the number of reducible species, and nickel dispersion. The catalytic performance results show that CeNiO3 demonstrated higher initial CH4 (54.3%) and CO2 (64.8%) conversions, which dropped down to 13.1 and 19.2% (CH4 conversions) and 26.3 and 32.5% (CO2 conversions) for Ce0.8Sr0.2NiO3 and Ce0.6Sr0.4NiO3, respectively. This drop in catalytic conversions post strontium addition is concomitant with strontium carbonate covering nickel active sites. Moreover, from the durability results, it is obvious that CeNiO3 exhibited deactivation, whereas no deactivation was observed for Ce0.8Sr0.2NiO3 and Ce0.6Sr0.4NiO3. Carbon deposition during the reaction is mainly responsible for catalyst deactivation, and this is further established by characterizing spent catalysts.

Higher spatial resolution imaging data are considered desirable in many Earth observation applications. In this work, we propose and demonstrate the TARSGAN (learning Terrestrial image deblurring using Adaptive weighted dense Residual Super-resolution Generative Adversarial Network) system for Super-resolution Restoration (SRR) of 10 m/pixel Sentinel-2 “true” colour images as well as all the other multispectral bands. In parallel, the ELF (automated image Edge detection and measurements of edge spread function, Line spread function, and Full width at half maximum) system is proposed to achieve automated and precise assessments of the effective resolutions of the input and SRR images. Subsequent ELF measurements of the TARSGAN SRR results suggest an averaged effective resolution enhancement factor of about 2.91 times (equivalent to ~3.44 m/pixel for the 10 m/pixel bands) given a nominal SRR upscaling factor of 4 times. Several examples are provided for different types of scenes from urban landscapes to agricultural scenes and sea-ice floes.

The occurrence of bone disorders is steadily increasing worldwide. Bone tissue engineering (BTE) has emerged as a promising alternative to conventional treatments of bone defects, developing bone scaffolds capable of promoting bone regeneration. In this research, biomimetic scaffolds based on ion-substituted calcium phosphates, derived from cuttlefish bone, were prepared using a hydrothermal method. To synthesize Mn 2+ -substituted scaffolds, three different manganese concentrations (corresponding to 1, 2.5, and 5 mol% Mn substitutions for Ca into hydroxyapatite) were used. Also, syntheses with the simultaneous addition of an equimolar amount (1 mol%) of two (Mg 2+ and Sr 2+ ) or three ions (Mn 2+ , Mg 2+ , and Sr 2+ ) were performed. A chemical, structural, and morphological characterization was carried out using X-ray diffraction, Fourier transform infrared spectroscopy, and scanning electron microscopy. The effects of the ion substitutions on the lattice parameters, crystallite sizes, and fractions of the detected phases were discussed. Multi-substituted (Mn 2+ , Mg 2+ , and Sr 2+ ) scaffolds were coated with polycaprolactone (PCL) using simple vacuum impregnation. The differentiation of human mesenchymal stem cells (hMSCs), cultured on the PCL-coated scaffold, was evaluated using histology, immunohistochemistry, and reverse transcription-quantitative polymerase chain reaction analyses. The expression of collagen I, alkaline phosphatase, and dentin matrix protein 1 was detected. The influence of PCL coating on hMSCs behavior is discussed.

This paper investigates the influence of the spectral irradiance variation and the spectral response (SR) on the production of energy by photovoltaic cells. To determine the impact of SR and spectral irradiance on m-Si and perovskite cells, experimental tests were conducted outdoors, used optical filters to select different zones of the spectrum. For the computational simulations of the different photovoltaic modules, when subjected to a certain spectral irradiance, a model with spectral factor (SF) was implemented. The SF model accurately simulated the experiments performed for the high-pass filters. The highest relative errors for certain irradiation bands occurred due to the input variables used in the model, which did not fully describe the reality of the experiments performed. The effect of the SR and the spectral irradiance for each of them were observed through the simulations for the m-Si, a-Si, CdTe, and copper indium selenide (CIS) modules. The CIS technology presented a better overall result in the near infrared zone, producing about half of the energy produced by the CdTe technology in the visible zone. The SF, spectral incompatibility factor (MM), and spectral effective responsivity (SEF) parameters were verified to be important for studying the photovoltaic energy production.

Electrical discharge machining (EDM) is an advanced machining method which removes metal by a series of recurring electrical discharges between an electrode and a conductive workpiece, submerged in a dielectric fluid. Even though EDM techniques are widely used to cut hard materials, low efficiency and high tool wear remain remarkable challenges in this process. Various studies, such as mixing different powders to dielectric fluids, are progressing to improve their efficiency. This paper reviews advances in the powder-mixed EDM process. Furthermore, studies about various powders used for the process and its comparison are carried out. This review looks at the objectives of achieving a more efficient metal removal rate, reduction in tool wear, and improved surface quality of the powder-mixed EDM process. Moreover, this paper helps researchers select suitable powders which are exhibiting better results and identifying different aspects of powder-mixed dielectric fluid of EDM.

The depth distribution of soil organic carbon (SOC) in a soil profile is important to examine the effects of different treatments on SOC sequestration. This study was conducted to determine the effects of different vegetation types on the concentration, storage, and stratification ratio (SR) of SOC in northeastern China. Five vegetation types, Leymus chinensis (LEY), Puccinellia tenuiflora (PUC), Echinochloa phyllopogon (ECH), saline seepweed (SUA), and Chloris virgata Swartz (CHL), were selected as treatments. Soil bulk density and SOC concentration were measured at 0 to 50 cm depth, and SOC storage and four SRs (SR1 [0−10:10−20 cm], SR2 [0−10:20−30 cm], SR3 [0−10:30−40 cm], and SR4 [0−10:40−50 cm]) were calculated under the five vegetation types. Results showed a pronounced reduction in SOC concentration with increasing soil depth. Vegetation types had significant effects on SOC concentration and storage. Under PUC, ECH, SUA, and CHL treatments, SOC concentrations (2.150, 1.068, 4.110, and 2.542 g kg−1, respectively) and storages (15.075, 7.273, 30.024, and 18.078 Mg ha−1, respectively) at 0−50 cm depth were lower than those under the LEY treatment. SR1 values were all < 2, while SR2, SR3, and SR4 values were all > 2 except for SR2 under ECH and SUA treatments. Vegetation types had significant effects on SR3 (p < 0.001) and SR4 (p = 0.040), while no significant differences were found for SR1 and SR2 due to the narrow range, with values of 0.248 and 0.553 for SR1 and SR2, respectively, among the vegetation types. These results indicated that the degraded soils have great potential to sequester organic carbon in northeastern China, and SR3 could be used as an effective index to show the changes in SOC concentration and soil quality in northeastern China.

Strontium is a common radionuclide in radioactive waste, and its release into the environment can cause enormous damage to the ecosystem environment. In this study, the natural mineral allophane was selected as the substrate to prepare solidified ceramic products by cold pressing/sintering to solve the problem of the final disposal of radioactive strontium. Ceramic solidified products with various crystal structures were successfully prepared, and the microscopic morphology and energy-dispersive spectroscopy images of the samples showed a uniform distribution of Sr in the solidified products. Sr 2 Al 2 SiO 7 and SrAl 2 Si 2 O 8 , which can stably solidify strontium, were formed in the solidified products, and the structural characteristics and stability of the above-mentioned substances were analyzed from the perspective of quantum chemical calculations using density functional theory. The calculation results showed that the overall deformation resistance of Sr 2 Al 2 SiO 7 was higher than that of SrAl 2 Si 2 O 8 . Considering the isomorphic substitution effect of CaO impurities, we inferred that a mixed-crystalline structure of Ca 2-x Sr x Al 2 SiO 7 may be present in the solidified products.

Hyperspectral remote sensing (RS) provides unique possibilities to monitor peatland vegetation traits and their temporal dynamics at a fine spatial scale. Peatlands provide a vital contribution to ecosystem services by their massive carbon storage and wide heterogeneity. However, monitoring, understanding, and disentangling the diverse vegetation traits from a heterogeneous landscape using complex RS signal is challenging, due to its wide biodiversity and distinctive plant species composition. In this work, we aim to demonstrate, for the first time, the large heterogeneity of peatland vegetation traits using well-established vegetation indices (VIs) and Sun-Induced Fluorescence (SIF) for describing the spatial heterogeneity of the signals which may correspond to spatial diversity of biochemical and structural traits. SIF originates from the initial reactions in photosystems and is emitted at wavelengths between 650−780 nm, with the first peak at around 687 nm and the second peak around 760 nm. We used the first HyPlant airborne data set recorded over a heterogeneous peatland area and its surrounding ecosystems (i.e., forest, grassland) in Poland. We deployed a comparative analysis of SIF and VIs obtained from differently managed and natural vegetation ecosystems, as well as from diverse small-scale peatland plant communities. Furthermore, spatial relationships between SIF and VIs from large-scale vegetation ecosystems to small-scale peatland plant communities were examined. Apart from signal variations, we observed a positive correlation between SIF and greenness-sensitive VIs, whereas a negative correlation between SIF and a VI sensitive to photosynthesis was observed for large-scale vegetation ecosystems. In general, higher values of SIF were associated with higher biomass of vascular plants (associated with higher Leaf Area Index (LAI)). SIF signals, especially SIF760, were strongly associated with the functional diversity of the peatland vegetation. At the peatland area, higher values of SIF760 were associated with plant communities of high perennials, whereas, lower values of SIF760 indicated peatland patches dominated by Sphagnum. In general, SIF760 reflected the productivity gradient on the fen peatland, from Sphagnum-dominated patches with the lowest SIF and fAPAR values indicating lowest productivity to the Carex-dominated patches with the highest SIF and fAPAR values indicating highest productivity.

Fusarium keratoplasticum is the Fusarium species most commonly associated with human infections (fusariosis). Antifungal treatment of fusariosis is often hampered by limited treatment options due to resistance towards azole antifungals. The mechanisms of antifungal resistance and sterol biosynthesis in fusaria are poorly understood. Therefore, in this study we assessed the transcriptional response of F. keratoplasticum when exposed to voriconazole. Our results revealed a group of dramatically upregulated ergosterol biosynthesis gene duplicates, most notably erg6A (912-fold), cyp51A (52-fold) and ebp1 (20-fold), which are likely part of an alternative ergosterol biosynthesis salvage pathway. The presence of human cholesterol biosynthesis gene homologs in F. keratoplasticum ( ebp1 , dhcr7 and dhcr24&#95;1 , dhcr24&#95;2 and dhcr24&#95;3 ) suggests that additional sterol biosynthesis pathways may be induced in fusaria under other growth conditions or during host invasion. Voriconazole also induced the expression of a number of ABC efflux pumps. Further investigations suggested that the highly conserved master regulator of ergosterol biosynthesis, FkSR, and the pleiotropic drug resistance network that induces zinc-cluster transcription factor FkAtrR coordinate the response of FSSC species to azole antifungal exposure. In-depth genome mining also helped clarify the ergosterol biosynthesis pathways of moulds and provided a better understanding of antifungal drug resistance mechanisms in fusaria.