1. Mussel-Inspired Fabrication of Konjac Glucomannan/Poly (Lactic Acid) Cryogels with Enhanced Thermal and Mechanical Properties
- Author
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Hong Xin, Ni Yongsheng, Chunhua Wu, Ruo-Jun Mu, Gong Jingni, Jie Pang, Wang Lin, and Yuan Yi
- Subjects
Thermogravimetric analysis ,Indoles ,Materials science ,Polymers ,Polyesters ,nanofibers cryogels ,02 engineering and technology ,mechanical properties ,010402 general chemistry ,01 natural sciences ,konjac glucomannan ,Article ,Catalysis ,Mannans ,Inorganic Chemistry ,lcsh:Chemistry ,chemistry.chemical_compound ,Differential scanning calorimetry ,Animals ,Physical and Theoretical Chemistry ,Fourier transform infrared spectroscopy ,Molecular Biology ,lcsh:QH301-705.5 ,Spectroscopy ,polydopamine ,Thermostability ,Hydrogen bond ,poly (lactic acid) ,Organic Chemistry ,Hydrogen Bonding ,General Medicine ,021001 nanoscience & nanotechnology ,Electrospinning ,Bivalvia ,0104 chemical sciences ,Computer Science Applications ,Lactic acid ,chemistry ,Chemical engineering ,lcsh:Biology (General) ,lcsh:QD1-999 ,Nanofiber ,0210 nano-technology ,Cryogels - Abstract
Three-dimensional nanofibers cryogels (NFCs) with both thermally-tolerant and mechanically-robust properties have potential for wide application in biomedical or food areas; however, creating such NFCs has proven to be extremely challenging. In this study, konjac glucomannan (KGM)/poly (lactic acid) (PLA)-based novel NFCs were prepared by the incorporation of the mussel-inspired protein polydopamine (PDA) via a facile and environmentally-friendly electrospinning and freeze-shaping technique. The obtained KGM/PLA/PDA (KPP) NFCs were characterized by field emission scanning electron microscopy (FE-SEM), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and compressive and tensile test. The results showed that the hierarchical cellular structure and physicochemical properties of KPP NFCs were dependent on the incorporation of PDA content. Moreover, the strong intermolecular hydrogen bond interactions among KGM, PLA and PDA also gave KPP NFCs high thermostability and mechanically-robust properties. Thus, this study developed a simple approach to fabricate multifunctional NFCs with significant potential for biomedical or food application.
- Published
- 2017