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The Ring of Cenotes (RC) extends along the edge of the Chicxulub crater, in the limestone platform of the Yucatan Peninsula (YP), where groundwater shows two preferential flow paths toward the coast near Celestun and Dzilam Bravo towns. The objectives of this study were to describe the regional hydrogeochemical evolution of the groundwater in the RC, and its association with the dissolution/precipitation of the minerals present along its pathway to the ocean. These objectives results were obtained by: a) characterizing groundwater hydrogeochemistry, b) calculating calcite, dolomite, and gypsum saturation indexes in the study area, and c) developing a hydrogeochemical model using PHREEQC (U. S. Geological Survey) inverse modelling approach. The model predictions confirmed that there are two evolution pathways of the groundwater consistent with the preferential flow paths suggested in a previous regionalization of the RC. On the western path, where groundwater flows towards Celestun, marine intrusion influences the hydrogeochemical processes and represents a risk for the freshwater. On the eastern path, where groundwater flows toward Dzilam Bravo, rainfall has an important effect on the hydrogeochemical processes, evidenced by a higher concentration in sulfates during droughts than during rainy periods. Then, monitoring of marine intrusion and phases dissolution in the RC is highly recommended

Karst aquifers show dissolution/precipitation processes of the minerals present in the carbonate rocks. The Ring of Cenotes (RC) extends along the edge of the Chicxulub crater, in the limestone platform of the Yucatan Peninsula (YP), where groundwater shows preferential flow paths toward the coast near Celestun and Dzilam Bravo towns. This study aimed to describe the regional hydrogeochemical evolution of groundwater of the RC, and its association with the dissolution/precipitation of the minerals present along its path to the ocean. To achieve this aim, we: a) characterized groundwater's hydrogeochemistry; b) determined the calcite, dolomite, and gypsum saturation indexes (reaction phases with the groundwater) in the study area; c) proposed a hydrogeochemical model developed through PHREEQC using an inverse modelling approach. The model predictions confirmed that there are two evolution pathways of the groundwater consistent with the preferential flow paths suggested in a previous regionalization of the RC. On the western path, where groundwater flows towards Celestun, an important marine intrusion influences the hydrogeochemical processes and represents a risk for the prevalence of freshwater. On the eastern path, where groundwater flows toward Dzilam Bravo, the hydrogeochemistry in the sinkholes correlates well with rainfall, suggesting a higher vulnerability during droughts than during rainy periods.

Springs are common features on the Yucatán coast. They can discharge either under the sea (submarine) or inland in coastal lagoons and wetlands. Previous observations of a coastal lagoon located on the northern Yucatán Peninsula (La Carbonera) reported sea water intrusion on a spring that discharge on a coastal lagoon (lagoon tidal spring). The saltwater intrusion occurs when the tide is at its lower level, which is the opposite to what has been reported for submarine springs in the Yucatán Peninsula. In this study, the hydrodynamics of the spring is analyzed and the driving forces controlling the seawater intrusion are identified and discussed. Time series of water levels, salinity, and velocity measurements in the lagoon, the aquifer, and the spring are analyzed by means of tide component decomposition and cross-correlations analysis of the tide signals. Results show that the main driving forces causing the intrusion are the density differences and pressure head gradients, and the mechanisms influencing the driving forces driving those differences are the tides, the friction in the lagoon, and the confinement of the aquifer; other mechanisms are discussed to present a complete idea of the complexity of the interactions between the coastal aquifer, the coastal lagoons, and the sea.