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This article will focus on the alkaline leaching of gold-bearing tetrahedrite concentrate in a solution containing sodium sulfide and sodium hydroxide. This selective leaching is followed by the leaching of heavy and waste metals into the solution, which may influence the physical properties and quality of the desired product, possibly causing environmental toxicity. At the same time, the amount of gold was observed during the leaching process to increase its content in the solid phase for the possibility of recovery and subsequent extraction of the precious metal. Sodium sulfide works very effectively on sulfide minerals which include tetrahedrite, and sodium hydroxide eliminates the hydrolysis of sulfur which slows leaching. The leaching kinetics were carried out with a duration of five hours, and based on volume sampling at certain time intervals from three samples, with the characteristic NaOH concentration, the leaching efficiency was observed from the results with atomic absorption spectrometry. The solid residue containing the tetrahedrite concentrate was analyzed through X-ray photoelectron analysis spectrometry, from which the % solids content was determined, and it is also known to deduce the leached amount of metals for each sample.

Karst dolines, as geomorphologically diverse natural landforms, usually exhibit more or less steep microclimatic gradients that provide a mosaic of diverse microhabitat conditions, resulting in a high diversity of soil biota with numerous rare endemic and/or relict species occupying these habitats. In this study, we investigated the spatial patterns of Collembola abundance, species richness, community structure and distribution of functional groups at topographically and microclimatically different sites across three open (unforested) karst dolines in a north-south direction in the Slovak Karst, Slovakia. We also assessed the refugial capacity of dolines for collembolan communities. The Friedman ANOVA test confirmed the significant differences in soil mean temperatures between the sites of all the dolines selected. The diverse soil microclimatic conditions within the dolines supported higher Collembola diversity (species numbers, diversity indices) compared with sites on the karst plateau and showed a potential to facilitate the persistence of some species that are absent or very rare in the surrounding landscape. In dolines with circular morphology and comparable size, the topography and soil microclimate had a stronger effect on community composition and structure than soil organic carbon. Shallow solution dolines provided microhabitats for various functional groups of soil Collembola in relation to the microclimatic character of the individual sites. It was observed that such landforms can also function as microclimatic refugia for cold-adapted species through the accumulation of colder air and the buffering of the local microclimate against the ambient mesoclimate, thus underlying the necessity of adequate attention in terms of the conservation of the karst natural phenomena.

Geopolymers can improve environmental protection and are therefore considered a 21st-century material that requires special attention. The main objective of this study was to examine the utilization of fly ash deposited on a heap as a potential raw material for the geopolymerization process. In this work, flexural and compressive strengths, as well as water absorption of geopolymers, were evaluated based on alkaline activator properties. Na2O content, SiO2/Na2O molar ratio and fly ash-to-water ratio were key observed factors. Mechanical strengths tests were conducted after 7, 28, 90, 180, and 360 days. The research findings showed that geopolymer cured at appropriate conditions and with a suitable alkaline activator can reach a compressive strength of more than 55 MPa. The presented study highlighted the possibility of the efficient use of fly ash to produce useful materials, i.e., geopolymers, which contribute to environmentally friendly solutions. This approach is fully in line with the principles of sustainable development.

The purpose of this work is to test the effectiveness of strengthening timber structures by means of composite bars. This article presents the results of preliminary tests carried out on solid beams made of fir wood. The test specimens, which are classified as strength class C24, had dimensions of 7 × 17 × 330 cm. Beams were reinforced with 8 mm diameter basalt fiber-reinforced polymer (BFRP) bars. The bars were glued into grooved channels along the bottom surface. Epoxy resin was used as an adhesive. The strength tests were conducted in accordance with the requirements of EN 408+A1:2012. The four-point bending scheme was adopted. The tests were conducted in the following two series: unreinforced beams (A) and beams reinforced with composites (B). Five elements were tested in each series. The reinforcement resulted in an average increase in the bending moment value of 8.41%. The deflection value at failure increased by 19.77%. The work also includes an analysis of the failure mode and a ductility analysis. Further tests should be carried out using a higher reinforcement ratio. A higher reinforcement ratio should make the presented reinforcement configuration more effective.

This study outlines a method of utilizing the finite element method and a simple mathematical model to predict the behavior of laminated veneer lumber (LVL) beams strengthened with composite sheets. The numerical models were created using the Abaqus 2017 software. The LVL was considered as a linearly elastic or elastic–plastic material, factoring in Hill’s yield criterion. The composites were simulated as linearly elastic–ideally plastic materials. The mathematical models were predicated on the methodology of transformed cross-section. The theoretical and numerical outcomes were juxtaposed with previous empirical investigations. The comparison encompassed load-bearing capacity, stiffness, and deformation under peak force. Furthermore, presentations of normal stress maps in the LVL and composite have been illustrated. The derived maps were juxtaposed with the delineations of failure modes. An adequate correlation was identified between the theoretical, numerical, and empirical values in the case of beams reinforced with aramid, glass, and carbon sheets. The relative deviation varied from several to multiple percentages. This technique is not applicable for evaluating load-bearing capacity and deformation when only dealing with sheets with low elongation of rupture. This is a consequence of their premature failure. The proposed models may be utilized by researchers and engineers in the design of reinforcements for timber structures.

Analyzing the feasibility of reinforcing new and existing wooden structures is a valid problem, being the subject of numerous scientific papers. The paper presents the preliminary results of a study on reinforcing Laminated Veneer Lumber (LVL) panels with composite materials bonded to exterior surfaces using epoxy resin. Glass-Fiber-Reinforced Polymer (GFRP) sheets, Carbon-Fiber-Reinforced Polymer (CFRP) sheets, and Ultra-High-Modulus (UHM) CFRP sheets were used as reinforcement. The variables in the analysis were the type of reinforcement and the number of reinforcement layers. The tests were carried out on small samples (45 × 45 × 900 mm) subjected to the so-called four-point bending test. Reinforcement positively affected the mechanical properties of composite section. The highest increases in load bearing were 37 and 48% for two layers of GFRP and CFRP, respectively. The bending stiffness increased up to 53 and 62% for two layers of CFRP and UHM CFRP, respectively. There was a change in failure mode from cracking in the tension zone for unreinforced beams to veneer shear in the support zone (for CFRP and GFRP sheets) and sheet rupture (UHM CFRP). Good agreement was obtained for estimating bending stiffness with the presented numerical and mathematical model; the relative error was up to 6% for CFRP and GFRP and up to 20% for UHM CFRP. This preliminary study proved the effectiveness of combining LVL with FRP sheets and indicated their weak spots, which should be further analyzed to improve their competitiveness against the traditional structures. The key limitation was the shear strength of LVL.

Due to the high cost of laboratory testing, many researchers are considering developing methods to predict the behavior of unreinforced and reinforced wood beams. This work aims to create either numerical or analytical models useful for extrapolating already conducted tests to other schemes/materials used as reinforcement. In the case of timber structures, due to the complexity of timber, this task is difficult. The first part of the article presents an analysis of the suitability of using a simplified mathematical model based on the equivalent cross-section method to describe the behavior of unreinforced and reinforced with carbon-fibre-reinforced polymer (CFRP) composite full-size laminated veneer lumber (LVL) beams. The theoretical results were compared with the results of conducted experimental tests. The scope of the analysis includes the estimation of modulus of rupture, bending stiffness, and determination of the neutral axis position. The equivalent cross-section method showed good agreement in determining the bending stiffness and neutral axis position of the strengthened sections. However, the suitability of using the equivalent cross-section method to estimate the load-carrying capacity of a cross-section reinforced with fiber composites still needs to be confirmed, which, according to the authors, is due to the differences between the assumed (linear) and actual (nonlinear) strain distribution in the compression zone. The second part uses the equivalent cross-section method to estimate the predicted bending stiffness of LVL beams strengthened with aramid-fibre-reinforced polymer (AFRP), glass-fibre-reinforced polymer (GFRP), and ultra-high modulus carbon-fibre-reinforced polymer (CFRP UHM) sheets. The proposed method can be used for preliminary evaluation of strengthening effectiveness of LVL beams.

The paper presents the results of experimental research on unstrengthened and strengthened laminated veneer beams subjected to 4-point bending. Aramid, glass and carbon sheets with high tensile strength (HS) and ultra-high modulus of elasticity (UHM) glued to external surfaces with an epoxy resin adhesive were used as reinforcement. Two reinforcement layouts were used: (1) sheets glued along the bottom surface and (2) sheets glued to the bottom and side surfaces. Based on the test results, the flexural strength, flexural ductility and stiffness were estimated. Compared to the reference beams, the maximum bending moment was higher by 15%, 20%, 30% and by 16%, 22% and 35% for the Aramid Fiber Reinforced Polymers (AFRP), Glass Fiber Reinforced Polymers (GFRP) and Carbon Fiber Reinforced Polymers (CFRP) HS sheets, respectively. There was no significant increase in the flexural bending capacity for beams reinforced with UHM CFRP sheets. Similar values of bending ductility indices based on deflection and energy absorption were obtained. Higher increases in ductility were observed for AFRP, GFRP and CFRP HS sheets in “U” reinforcement layout. The average increase in bending stiffness coefficient ranged from 8% for AFRP sheets to 33% for UHM CFRP sheets compared to the reference beams.

We report on the comparison between temperature-dependent magneto-absorption and magnetotransport spectroscopy of HgTe/CdHgTe quantum wells in terms of the detection of the phase transition between the topological insulator and band insulator states. Our results demonstrate that temperature-dependent magnetospectroscopy is a powerful tool to discriminate trivial and topological insulator phases, yet the magnetotransport method is shown to have advantages for the clear manifestation of the phase transition with accurate quantitative values of the transition parameter (i.e., critical magnetic field Bc).