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Fermentative hydrogen production from molasses—a renewable by-product of beet-sugar processing—was considered. Technical and economic evaluations were performed of a stand-alone production plant employing a two-step fermentation process (dark thermophilic fermentation and photofermentation) followed by an adsorption-based upgrading of the produced hydrogen gas. Using a state-of-the-art knowledge base and a mathematical model composed of mass and energy balances, as well as economic relationships, the process was simulated and equipment data were estimated, the hydrogen cost was calculated and a sensibility analysis was carried out. Due to high capital, operating and labor costs, hydrogen production cost was estimated at a rather high level of 32.68 EUR/kg, while the energy output in produced hydrogen was determined as 68% more than the combined input of the thermal and electric energy needed for plant operation. As the room for improvement of plant performance is limited, a perspective on the cost competitiveness of large-scale hydrogen production from fossil sources is unclear.

The present work is an extension of the authors&rsquo, previous research, where changes in the dynamic behavior of heat exchangers induced by fouling build-up were studied. In the present work, the authors used the previously elaborated and validated mathematical model of transient heat exchange with the influence of thermal resistance of fouling taken into account. The behavior of specific Heat Exchanger Networks (HENs) coupled with a Crude Distillation Unit together with their control loops is simulated using Simulink/MATLAB and the influence of fouling build-up on specific indices of quality of operation is investigated. According to the presented results, the higher the number of heat exchangers in the PID control loop and the greater the number of heat exchangers interacting in the network, the smaller the influence of fouling on the control quality indices, and in the extreme case, this influence may be negligible. This might be caused by the compensation of the negative effects of fouling build-up when the heat exchangers are interacting in the HEN. Nevertheless, potential adverse effects of fouling on HEN operation can be prevented by periodic adjustments of the optimal values of PID gains.