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Phosphorus (P) and TiO2 have been extensively studied as anode materials for lithium-ion batteries (LIBs) due to their high specific capacities. However, P is limited by low electrical conductivity and significant volume changes during charge and discharge cycles, while TiO2 is hindered by low electrical conductivity and slow Li-ion diffusion. To address these issues, we synthesized organic–inorganic hybrid anode materials of P–polypyrrole (PPy) and TiO2–PPy, through in situ polymerization of pyrrole monomer in the presence of the nanoscale inorganic materials. These hybrid anode materials showed higher cycling stability and capacity compared to pure P and TiO2. The enhancements are attributed to the electrical conductivity and flexibility of PPy polymers, which improve the conductivity of the anode materials and effectively buffer volume changes to sustain structural integrity during the charge and discharge processes. Additionally, PPy can undergo polymerization to form multi-component composites for anode materials. In this study, we successfully synthesized a ternary composite anode material, P–TiO2–PPy, achieving a capacity of up to 1763 mAh/g over 1000 cycles.

In this study, an omnidirectional and high-performance free-standing monopole patch radio-frequency antenna was fabricated using a urea-functionalized phosphorene/TiO2/polypyrrole (UTP) nanocomposite. The UTP nanocomposite antenna was fabricated via ball milling of urea-functionalized phosphorene, chemical oxidative polymerization of the UTP nanocomposite, and mechanical pelletizing of the composite. Based on experiments, the proposed UTP nanocomposite-based antenna exhibited long-term stability in terms of electrical conductivity. After 12 weeks, a slight change in surface resistance was observed. The proposed antenna exhibited high radiation efficiency (78.2%) and low return loss (−36.6 dB). The results of this study suggest the potential of UTP nanocomposite antennas for applications in 5G technology.

In this paper, we report a titanium dioxide/polypyrrole/phosphorene (TiO2/PPy/phosphorene) nanocomposite as an active material for supercapacitor electrodes. Black phosphorus (BP) was fabricated by ball milling to induce a phase transition from red phosphorus, and urea-functionalized phosphorene (urea-FP) was obtained by urea-assisted ball milling of BP, followed by sonication. TiO2/PPy/phosphorene nanocomposites can be prepared via chemical oxidative polymerization, which has the advantage of mass production for a one-pot synthesis. The specific capacitance of the ternary nanocomposite was 502.6 F g−1, which was higher than those of the phosphorene/PPy (286.25 F g−1) and TiO2/PPy (150 F g−1) nanocomposites. The PPy fully wrapped around the urea-FP substrate provides an electron transport pathway, resulting in the enhanced electrical conductivity of phosphorene. Furthermore, the assistance of anatase TiO2 nanoparticles enhanced the structural stability and also improved the specific capacitance of the phosphorene. To the best of our knowledge, this is the first report on the potential of phosphorene hybridized with conducting polymers and metal oxides for practical supercapacitor applications.