1. Efficient CO2 Electrocarboxylation Using Dye-Sensitized Photovoltaics
- Author
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Yingtian Zhang, Huaiyan Ren, Huawei Zhou, Peipei Luo, Qi Wan, Xianxi Zhang, Bo Wang, Baoli Chen, and Bo Zhang
- Subjects
electrochemical carboxylation ,electrocarboxylation ,CO2 fixation ,CO2 electrocatalytic carboxylation ,electrosynthesis ,dye-sensitized solar cells ,Organic chemistry ,QD241-441 - Abstract
This paper presents the solar-driven electrocarboxylation of 2-bromopyridine (2-BP) with CO2 into high-value-added chemicals 2-picolinic acid (2-PA) using dye-sensitized photovoltaics under simulated sunlight. Using three series-connected photovoltaic modules and an Ag electrode with excellent catalytic performance, a Faraday efficiency (FE) of 33.3% is obtained for 2-PA under mild conditions. The experimental results show that photovoltaics-driven systems for electrocarboxylation conversion of CO2 with heterocyclic halide to afford value-added heterocyclic carboxylic acid are feasible and effective.
- Published
- 2024
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