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The paper discusses the results of the concentrations of atmospheric particulate matter, in the PM2.5 and PM10 fractions, acquired by two low-cost sensors. The research was carried out from 1 July 2023 to 30 June 2024, in Palermo, Sicily. The results obtained from two systems equipped with the same sensor model were compared. Excellent linear correlation was observed between the results, with differences in measurements falling within instrumental accuracy. Two instruments equipped with different sensors, models Novasense SDS011 and Plantower PMSA003, were placed at the same site. These were complemented by a weather station to measure meteorological parameters. Upon comparing the atmospheric particulate matter concentrations measured by the two instruments, it was observed that there was a good linear correlation for PM2.5 and a poor linear correlation for PM10. Additionally, the PMSA003 sensor appeared to consistently record higher concentrations than the SDS011 sensor. During periods influenced by natural sources and/or anthropogenic activities at the regional and/or local scale, i.e., the dispersal of Saharan sands, forest fires, and local events using fireworks, abnormal concentrations of atmospheric particulate matter were detected. Despite the inherent limitations in precision and accuracy, both low-cost instruments were able to identify periods with abnormal concentrations of atmospheric particulate matter, regardless of their source or type.

The concentrations of trace elements in atmospheric bulk depositions (wet plus dry) were investigated from two highly industrialised areas of Sicily (southern Italy) from June 2018 to July 2019, in order to recognise the main natural and anthropogenic sources. A side objective of this study was to improve the common sampling procedures and analytical methods used for monitoring trace elements in atmospheric deposition. The trace element VWM (Volume-Weighted Mean) concentrations ranged from less than 0.01 μg L−1 for trace elements such as Cs, Tl, and U, up to 24 μg L−1 for minor elements (Al, Zn, Sr), in the filtered aliquot, while they reached concentrations up to 144 μg L−1 for the same elements, in the unfiltered aliquot. Therefore, significant differences in concentrations between these two aliquots were found, particularly for Al, Fe, Ti, Zn, Cr, Pb, Se, Cs, and U. This implies that filtering operations may produce a consistent underestimation of concentrations of certain ‘constituents’ of the atmospheric deposition. Natural (marine spray, local and regional geogenic input, volcanic emanations) and anthropogenic sources (industrial emissions, auto vehicular traffic, and diffuse background pollution) which influence rainwater chemistry were identified. Enrichment factors (EFs), with respect to the upper crust composition, provided clear evidence of the different sources above mentioned: Ti, Fe, Al, Cs, Cr, Rb, and Co have low EFs (10), highlight the influence of marine and/or industrial sources. The study produced a novel dataset on the atmospheric deposition rate of several trace elements, which had never been studied in the investigated areas. Finally, a comparison of trace element deposition rates in the studied areas with the atmospheric deposition reported for 53 different sites, belonging to 20 different European nations, was made. The comparison showed that some elements, such as Al, V, Zn, and Mo had higher median deposition fluxes in the Sicilian sites than in European monitoring sites.