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Low-cost, high-performance coatings for hydrogen production via electrolytic water-splitting are of great importance for de-carbonising energy. In this study the Raney2.0 coating was analysed using various electrochemical techniques to assess its absolute performance, and it was confirmed to have an extremely low overpotential for hydrogen evolution of just 28 mV at 10 mA/cm2. It was also confirmed to be an acceptable catalyst for oxygen evolution, making it the highest performing simple bifunctional electrocatalyst known. The coating exhibits an extremely high capacitance of up to 1.7 F/cm2, as well as being able to store 0.61 J/cm2 in the form of temporary hydride deposits. A new technique is presented that performs a best-fit of a transient simulation of an equivalent circuit containing a constant phase element to cyclic voltammetry measurements. From this the roughness factor of the coating was calculated to be approximately 40,000, which is the highest figure ever reported for this type of material. The coating is therefore an extremely useful improved bifunctional coating for the continued roll-out of alkaline electrolysis for large-scale renewable energy capture via hydrogen production.

In this paper we summarize the research on Systems Thinking for business management and explore several examples of business failures due to a lack of application of Systems Thinking, with an ultimate goal of offering a Systems Thinking approach that is useful to all levels of management. Although there is significant literature aimed at facilitating Systems Thinking in organizational management, there remains a lack of adoption of Systems Thinking in mainstream business practice. This is perhaps because the literature does not reduce high-level Systems Thinking principles to hands-on, practical protocols that are accessible for typical managers, thus limiting the working application of Systems Thinking concepts to researchers and consultants who specialize in the field. The goal of this work is to not only elaborate on the high-level ideals of System Thinking, but also to articulate a more precise and practical hands-on approach that is useful to all levels of business managers.

Systems thinking is an approach to reasoning and treatment of real-world problems based on the fundamental notion of ‘system.’ System here refers to a purposeful assembly of components. Thus, systems thinking is aimed at understanding relationships between components and their overall impact on system outcomes (i.e., intended and unintended) and how a system similarly fits in the broader context of its environment. There are currently several distinct flavors of systems thinking, both in practice and scholarship; most notably in the disciplines of systems science, systems engineering, and systems dynamics. Each of these, while similar in purpose, has a distinct history and a rich set of methods and tools for various application contexts. The WPI Systems Thinking Colloquium held on 2 October 2019 was aimed at exploring the diversity of perspectives on systems thinking from these disciplines. The colloquium brought together world-renowned experts from both industry and academia to share insights from their research and practice. This paper offers a compilation of summaries of the presentations given.

The use of hydrogen gas as a means of decoupling supply from demand is crucial for the transition to carbon-neutral energy sources and a greener, more distributed energy landscape. This work shows how simple commercially available titanium nitride coatings can be used to extend the lifetime of 316 grade stainless-steel electrodes for use as the cathode in an alkaline electrolysis cell. The material was subjected to accelerated ageing, with the specific aim of assessing the coating&rsquo, s suitability for use with intermittent renewable energy sources. Over 2000 cycles lasting 5.5 days, an electrolytic cell featuring the coating outperformed a control cell by 250 mV, and a reduction of overpotential at the cathode of 400 mV was observed. This work also confirms that the coating is solely suitable for cathodic use and presents an analysis of the surface changes that occur if it is used anodically.