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The chemical evolution of galaxies is governed by the chemical yields from stars, and here we focus on the important contributions from asymptotic giant branch (AGB) stars. AGB nucleosynthesis is, however, still riddled with complexities. Observations from post-asymptotic giant branch (post-AGB) stars serve as exquisite tools to quantify and understand AGB nucleosynthesis. In this contribution, we review the invaluable constraints provided by post-AGB stars with which to study AGB nucleosynthesis, especially the slow neutron capture nucleosynthesis (i.e., the s-process).

Cool stars with convective envelopes of spectral types F and later tend to exhibit magnetic activity throughout their atmospheres. The presence of strong and variable magnetic fields is evidenced by photospheric starspots, chromospheric plages and coronal flares, as well as by strong Ca ii H+K and Hα emission, combined with the presence of ultraviolet resonance lines. We review the drivers of stellar chromospheric activity and the resulting physical parameters implied by the observational diagnostics. At a basic level, we explore the importance of stellar dynamos and their activity cycles for a range of stellar types across the Hertzsprung–Russell diagram. We focus, in particular, on recent developments pertaining to stellar rotation properties, including the putative Vaughan–Preston gap. We also pay specific attention to magnetic variability associated with close binary systems, including RS Canum Venaticorum, BY Draconis, W Ursae Majoris and Algol binaries. At the present time, large-scale photometric and spectroscopic surveys are becoming generally available, thus leading to a resurgence of research into chromospheric activity. This opens up promising prospects to gain a much improved understanding of chromospheric physics and its wide-ranging impact.

Lead (Pb) is predicted to have large over-abundances with respect to other s-process elements in Asymptotic Giant Branch (AGB) stars, especially of low metallicities. However, our previous abundance studies of s-process enriched post-Asymptotic Giant Branch (post-AGB) stars in the Galaxy and the Magellanic Clouds show a discrepancy between observed and predicted Pb abundances. For the subset of post-AGB stars with low metallicities the determined upper limits based on detailed chemical abundance studies are much lower than what is predicted. Recent theoretical studies have pointed to the occurrence of the i-process to explain the observed chemical patterns, especially of Pb. A major development, in the observational context, is the release of the GAIA EDR3 parallaxes of the post-AGBs in the Galaxy, which has opened the gateway to systematically studying the sample of stars as a function of current luminosities (which can be linked to their initial masses). In this paper, we succinctly review the Pb discrepancy in post-AGB stars and present the latest observational and theoretical developments in this research landscape.