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In this work, polyethyleneimine-grafted graphene oxide (PEI/GO) is synthesized using graphene, polyethyleneimine, and trimesoyl chloride. Both graphene oxide and PEI/GO are characterized by a Fourier-transform infrared (FTIR) spectrometer, a scanning electron microscope (SEM), and energy-dispersive X-ray (EDX) spectroscopy. Characterization results confirm that polyethyleneimine is uniformly grafted on the graphene oxide nanosheets and, thus, also confirm the successful synthesis of PEI/GO. PEI/GO adsorbent is then evaluated for the removal of lead (Pb2+) from aqueous solutions, and the optimum adsorption is attained at pH 6, contact time of 120 min, and PEI/GO dose of 0.1 g. While chemosorption is dominating at low Pb2+ concentrations, physisorption is dominating at high concentrations and the adsorption rate is controlled by the boundary-layer diffusion step. In addition, the isotherm study confirms the strong interaction between Pb2+ ions and PEI/GO and reveals that the adsorption process obeys well the Freundlich isotherm model (R2 = 0.9932) and the maximum adsorption capacity (qm) is 64.94 mg/g, which is quite high compared to some of the reported adsorbents. Furthermore, the thermodynamic study confirms the spontaneity (negative ΔG° and positive ΔS°) and the endothermic nature (ΔH° = 19.73 kJ/mol) of the adsorption process. The prepared adsorbent (PEI/GO) offers a potential promise for wastewater treatment because of its fast and high uptake removal capacity and could be used as an effective adsorbent for the removal of Pb2+-ions and other heavy metals from industrial wastewater.

Nanofluids and nanotechnology are very important in enhancing heat transfer due to the thermal conductivity of their nanoparticles, which play a vital role in heat transfer applications. Researchers have used cavities filled with nanofluids for two decades to increase the heat-transfer rate. This review also highlights a variety of theoretical and experimentally measured cavities by exploring the following parameters: the significance of cavities in nanofluids, the effects of nanoparticle concentration and nanoparticle material, the influence of the inclination angle of cavities, heater and cooler effects, and magnetic field effects in cavities. The different shapes of the cavities have several advantages in multiple applications, e.g., L-shaped cavities used in the cooling systems of nuclear and chemical reactors and electronic components. Open cavities such as ellipsoidal, triangular, trapezoidal, and hexagonal are applied in electronic equipment cooling, building heating and cooling, and automotive applications. Appropriate cavity design conserves energy and produces attractive heat-transfer rates. Circular microchannel heat exchangers perform best. Despite the high performance of circular cavities in micro heat exchangers, square cavities have more applications. The use of nanofluids has been found to improve thermal performance in all the cavities studied. According to the experimental data, nanofluid use has been proven to be a dependable solution for enhancing thermal efficiency. To improve performance, it is suggested that research focus on different shapes of nanoparticles less than 10 nm with the same design of the cavities in microchannel heat exchangers and solar collectors.

The analysis of air pollution behavior is becoming crucial, where information on air pollution behavior is vital for managing air quality events. Many studies have described the stochastic behavior of air pollution based on the Markov chain (MC) models. Fitting the optimum order of MC models is essential for describing the stochastic process. However, uncertainty remains concerning the optimum order of such models for representing and characterizing air pollution index (API) data. In this study, the optimum order of the MC models for hourly and daily API sequences from seven stations in the central region of Peninsular Malaysia is identified, based on the Bayesian information criteria (BIC), contributing to exploring an adequate explanation of the probabilistic dependence of air pollution. A summary of the statistics for the API was calculated prior to the analysis. The Markov property and the divergence for the empirically estimated transition matrix of an MC sequence are also investigated. It is found from the analysis that the optimum order varies from one station to another. At most stations, for both observed and simulated API data, the second and third orders of the MC models are found to be optimum for hourly API occurrences, while the first-order MC is found to be most fitting for describing the dynamics of the daily API. Overall, fitting the optimum order of the MC model for the API data sequence captured the delay effect of air pollution. Accordingly, we concluded that the air quality standard lies within controllable limits, except for some infrequent occurrences of API values exceeding the unhealthy level.

It is necessary to sustain energy from an external reservoir or employ advanced technologies to enhance oil recovery. A greater volume of oil may be recovered by employing nanofluid flooding. In this study, we investigated oil extraction in a two-phase incompressible fluid in a two-dimensional rectangular porous homogenous area filled with oil and having no capillary pressure. The governing equations that were derived from Darcy’s law and the mass conservation law were solved using the finite element method. Compared to earlier research, a more efficient numerical model is proposed here. The proposed model allows for the cost-effective study of heating-based inlet fluid in enhanced oil recovery (EOR) and uses the empirical correlations of the nanofluid thermophysical properties on the relative permeability equations of the nanofluid and oil, so it is more accurate than other models to determine the higher recovery factor of one nanoparticle compared to other nanoparticles. Next, the effect of nanoparticle volume fraction on flooding was evaluated. EOR via nanofluid flooding processes and the effect of the intake temperatures (300 and 350 K) were also simulated by comparing three nanoparticles: SiO2, Al2O3, and CuO. The results show that adding nanoparticles (

Arsenic is a deleterious heavy metal that is usually removed from polluted water based on adsorption processes. The latest mode of modeling such a process is to implement artificial intelligence (AI). In the current work, a new artificial neural network (ANN) model was developed to predict the adsorption efficiency of arsenate (As(III)) from contaminated water by analyzing different architectures of an adaptive network-based fuzzy inference system (ANFIS). The database for the current study consisted of the experimental data of the adsorption of As(III) by different adsorbents/biosorbents. The data were randomly divided into two sets: 70% for the training phase and 30% for the testing phase. Four statistical evaluation metrics, namely, mean square error (MSE), root-mean-square error (RMSE), Pearson’s correlation coefficient (R%), and the determination coefficient (R2) were used for the analysis. The best performing ANFIS model was characterized with the average values of 97.72%, 0.9333, 0.137, and 0.274 of R%, R2, MSE, and RMSE, respectively. In addition, a parametric investigation revealed that the most dominating parameters on the adsorption process efficiency were in the following order: pH, As initial concentration, contact time, adsorbent dosage, inoculum size, and temperature. The results of the current study would be useful in the adsorption process scale-up and optimization.

In this work, an artificial neural network (ANN) model was efficiently developed to predict the pyrolysis of mixed plastics, including pure polystyrene (PS), polypropylene (PP), low-density polyethylene (LDPE), and high-density polyethylene (HDPE), at a heating rate of 60 K/min using thermogravimetric analysis (TGA) data. The data of seventeen experimental tests of polymer mixtures with different compositions were used. A feed-forward back-propagation model, with 15 and 10 neurons in two hidden layers and TANSIG-TANSIG transfer functions, was constructed to predict the weight left percent during the pyrolysis of the mixed polymer samples. The model input variables include the composition of each polymer (PS, PP, LDPE, and HDPE), and temperature. The results showed an excellent agreement between the experimental and the predicted weight left percent values, where the correlation coefficient (R) is greater than 0.9999. In addition, to validate the proposed model, a highly efficient performance was found when the proposed model was simulated using new input data. Furthermore, a sensitivity analysis was performed using Pearson correlation to find the uncertainties associated with the relationship between the output and the input parameters. Temperature was found to be the most sensitive input parameter.

Agricultural droughts impose many economic and social losses on various communities. Most of the effective tools developed for agricultural drought assessment are based on vegetation indices (VIs). The aim of this study is to compare the response of two commonly used VIs to meteorological droughts—Moderate Resolution Imaging Spectroradiometer (MODIS) normalized difference vegetation index (NDVI) and Soil Moisture and Ocean Salinity (SMOS) vegetation optical depth (VOD). For this purpose, meteorological droughts are calculated by using a standardized precipitation index over more than 24,000 pixels at 0.25° × 0.25° spatial resolution located in central Europe. Then, to evaluate the capability of VIs in the detection of agricultural droughts, the average values of VIs anomalies during dry and wet periods obtained from meteorological droughts are statistically compared to each other. Additionally, to assess the response time of VIs to meteorological droughts, a time lag of one to six months is applied to the anomaly time series of VIs during their comparison. Results show that over 35% of the considered pixels NDVI, over 22% of VOD, and over 8% of both VIs anomalies have a significant response to drought events, while the significance level of these differences and the response time of VIs vary with different land use and climate conditions.

In this work, the treatment of oily wastewater was investigated using developed cellulose acetate (CA) membranes blended with Nylon 66. Membrane characterization and permeation results in terms of oil rejection and flux were compared with a commercial CA membrane. The solution casting method was used to fabricate membranes composed of CA and Nylon 66. Scanning Electron Microscopy (SEM) analysis was done to examine the surface morphology of the membrane as well as the influence of solvent on the overall structure of the developed membranes. Mechanical and thermal properties of developed blended membranes and a commercial membrane were examined by thermogravimetric analysis (TGA) and universal (tensile) testing machine (UTM). Membrane characterizations revealed that the thermal and mechanical properties of the fabricated blended membranes better than those of the commercial membrane. Membrane fluxes and rejection of oil as a function of Nylon 66 compositions and transmembrane pressure were measured. Experimental results revealed that the synthetic membrane (composed of 2% Nylon 66 and Dimethyl Sulfoxide (DMSO) as a solvent) gave a permeate flux of 33 L/m2h and an oil rejection of around 90%, whereas the commercial membrane showed a permeate flux of 22 L/m2h and an oil rejection of 70%.

Vegetation is a key element in the energy, water and carbon balances over the land surfaces and is strongly impacted by climate change and anthropogenic effects. Remotely sensed observations are commonly used for the monitoring of vegetation dynamics and its temporal changes from regional to global scales. Among the different indices derived from Earth observation satellites to study the vegetation, the vegetation optical depth (VOD), which is related to the intensity of extinction effects within the vegetation canopy layer in the microwave domain and which can be derived from both passive and active microwave observations, is increasingly used for monitoring a wide range of ecological vegetation variables. Based on different frequency bands used to derive VOD, from L- to Ka-bands, these variables include, among others, the vegetation water content/status and the above ground biomass. In this review, the theoretical bases of VOD estimates for both the passive and active microwave domains are presented and the global long-term VOD products computed from various groups in the world are described. Then, major findings obtained using VOD are reviewed and the perspectives offered by methodological improvements and by new sensors onboard satellite missions recently launched or to be launched in a close future are presented.

Development of optical materials has attracted strong attention from scientists across the world to obtain low band gap energy and become active in field of solar energy. This challenge, which cannot be accomplished by the usual techniques, has overcome through the current study using non-conventional techniques. This study has used explosive reactions to convert non-optical alumina to series of new optical nanocomposites with very low band gap energy for the first time. In this trend, alumina nanoparticles were prepared and modified by explosive reactions using ammonium nitrate as a solid fuel. By using methanol or ethanol as a source of carbon species, three nanocomposites were produced indicating a gradual reduction of the band gap energy of alumina from 4.34 eV to 1.60 eV. These nanocomposites were obtained by modifying alumina via two different carbon species; core-shell structure and carbon nanotubes. This modification led to sharp reduction for the band gap energy to become very sensitive in sunlight. Therefore, these nanocomposites caused fast decolorization and mineralization of green dyes after illuminating in sunlight for ten minutes. Finally, it can be concluded that reduction of the band gap energy introduces new optical materials for developing optical nano-devices and solar cells.

Quantifying roughness effects on ground surface emissivity is an important step in obtaining high-quality soil moisture products from large-scale passive microwave sensors. In this study, we used a semi-empirical method to evaluate roughness effects (parameterized here by the parameter) on a global scale from AMSR-E (Advanced Microwave Scanning Radiometer for EOS) observations. AMSR-E brightness temperatures at 6.9 GHz obtained from January 2009 to September 2011, together with estimations of soil moisture from the SMOS (Soil Moisture and Ocean Salinity) L3 products and of soil temperature from ECMWF’s (European Centre for Medium-range Weather Forecasting) were used as inputs in a retrieval process. In the first step, we retrieved a parameter (referred to as the parameter) accounting for the combined effects of roughness and vegetation. Then, global MODIS NDVI data were used to decouple the effects of vegetation from those of surface roughness. Finally, global maps of the Hr parameters were produced and discussed. Initial results showed that some spatial patterns in the values could be associated with the main vegetation types (higher values of were retrieved generally in forested regions, intermediate values were obtained over crops and grasslands, and lower values were obtained over shrubs and desert) and topography. For instance, over the USA, lower values of were retrieved in relatively flat regions while relatively higher values were retrieved in hilly regions.

Hydro-agricultural applications often require surface soil moisture (SM) information at high spatial resolutions. In this study, daily spatial patterns of SM at a spatial resolution of 1 km over the Babao River Basin in northwestern China were mapped using a Bayesian-based upscaling algorithm, which upscaled point-scale measurements to the grid-scale (1 km) by retrieving SM information using Moderate Resolution Imaging Spectroradiometer (MODIS)-derived land surface temperature (LST) and topography data (including aspect and elevation data) and in situ measurements from a wireless sensor network (WSN). First, the time series of pixel-scale (1 km) representative SM information was retrieved from in situ measurements of SM, topography data, and LST. Second, Bayesian linear regression was used to calibrate the relationship between the representative SM and the WSN measurements. Last, the calibrated relationship was used to upscale a network of in situ measured SM to map spatially continuous SM at a high resolution. The upscaled SM data were evaluated against ground-based SM measurements with satisfactory accuracy—the overall correlation coefficient (r), slope, and unbiased root mean square difference (ubRMSD) values were 0.82, 0.61, and 0.025 m3/m3, respectively. Moreover, when accounting for topography, the proposed upscaling algorithm outperformed the algorithm based only on SM derived from LST (r = 0.80, slope = 0.31, and ubRMSD = 0.033 m3/m3). Notably, the proposed upscaling algorithm was able to capture the dynamics of SM under extreme dry and wet conditions. In conclusion, the proposed upscaled method can provide accurate high-resolution SM estimates for hydro-agricultural applications.

Global soil moisture (SM) products are currently available thanks to microwave remote sensing techniques. Validation of these satellite-based SM products over different vegetation and climate conditions is a crucial step. INRA (National Institute of Agricultural Research) has set up the AQUI SM and soil temperature in situ network (composed of three main sites Bouron, Bilos, and Hermitage), over a flat area of dense pine forests, in South-Western France (the Bordeaux⁻Aquitaine region) to validate the Soil Moisture and Ocean salinity (SMOS) satellite SM products. SMOS was launched in 2009 by the European Space Agency (ESA). The aims of this study are to present the AQUI network and to evaluate the SMOS SM product (in the new SMOS-IC version) along with other microwave SM products such as the active ASCAT (Advanced Scatterometer) and the ESA combined (passive and active) CCI (Climate Change Initiative) SM retrievals. A first comparison, using Pearson correlation, Bias, RMSE (Root Mean Square Error), and Un biased RMSE (ubRMSE) scores, between the 0⁻5 cm AQUI network and ASCAT, CCI, and SMOS SM products was conducted. In general all the three products were able to reproduce the annual cycle of the AQUI in situ observations. CCI and ASCAT had best and similar correlations (R~0.72) over the Bouron and Bilos sites. All had comparable correlations over the Hermitage sites with overall average values of 0.74, 0.68, and 0.69 for CCI, SMOS-IC, and ASCAT, respectively. Considering anomalies, correlation values decreased for all products with best ability to capture day to day variations obtained by ASCAT. CCI (followed by SMOS-IC) had the best ubRMSE values (mostly < 0.04 m3/m3) over most of the stations. Although the region is highly impacted by radio frequency interferences, SMOS-IC followed correctly the in situ SM dynamics. All the three remotely-sensed SM products (except SMOS-IC over some stations) overestimated the AQUI in situ SM observations. These results demonstrate that the AQUI network is likely to be well-suited for satellite microwave remote sensing evaluations/validations.

This study evaluates the accuracy of several recent remote sensing Surface Soil Moisture (SSM) products at sites in southwestern France. The products used are Soil Moisture Active Passive “SMAP” (level 3: 36 km × 36 km, level 3 enhanced: 9 km × 9 km, and Level 2 SMAP/Sentinel-1: 1 km × 1km), Advanced Scatterometer “ASCAT” (level 2 with three spatial resolution 25 km × 25 km, 12.5 km × 12.5 km, and 1 km × 1 km), Soil Moisture and Ocean Salinity “SMOS” (SMOS INRA-CESBIO “SMOS-IC”, SMOS Near-Real-Time “SMOS-NRT”, SMOS Centre Aval de Traitement des Données SMOS level 3 “SMOS-CATDS”, 25 km × 25 km) and Sentinel-1(S1) (25 km × 25 km, 9 km × 9 km, and 1 km × 1 km). The accuracy of SSM products was computed using in situ measurements of SSM observed at a depth of 5 cm. In situ measurements were obtained from the SMOSMANIA ThetaProbe (Time Domaine reflectometry) network (7 stations between 1 January 2016 and 30 June 2017) and additional field campaigns (near Montpellier city in France, between 1 January 2017 and 31 May 2017) in southwestern France. For our study sites, results showed that (i) the accuracy of the Level 2 SMAP/Sentinel-1 was lower than that of SMAP-36 km and SMAP-9 km; (ii) the SMAP-36 km and SMAP-9 km products provide more precise SSM estimates than SMOS products (SMOS-IC, SMOS-NRT, and SMOS-CATDS), mainly due to higher sensitivity of SMOS to RFI (Radio Frequency Interference) noise; and (iii) the accuracy of SMAP-36 km and SMAP-9 km products was similar to that of ASCAT (ASCAT-25 km, ASCAT-12.5 km and ASCAT-1 km) and S1 (S1-25 km, S1-9 km, and S1-1 km) products. The accuracy of SMAP, Sentinel-1 and ASCAT SSM products calculated using the average of statistics obtained on each site is defined by a bias of about −3.2 vol. %, RMSD (Root Mean Square Difference) about 7.6 vol. %, ubRMSD (unbiased Root Mean Square Difference)about 5.6 vol. %, and R coefficient about 0.57. For SMOS products, the station average bias, RMSD, ubRMSD, and R coefficient were about −10.6 vol. %, 12.7 vol. %, 5.9 vol. %, and 0.49, respectively.

Long-term climate records of soil moisture are of increased importance to climate researchers. In this study, we aim to evaluate the quality of three different fusion approaches that combine soil moisture retrieval from multiple satellite sensors. The arrival of L-band missions has led to an increased focus on the integration of L-band-based soil moisture retrievals in climate records, emphasizing the need to improve our understanding based on its added value within a multi-sensor framework. The three evaluated approaches were developed on 10-year passive microwave data (2003–2013) from two different satellite sensors, i.e., SMOS (2010–2013) and AMSR-E (2003–2011), and are based on a neural network (NN), regressions (REG), and the Land Parameter Retrieval Model (LPRM). The ability of the different approaches to best match AMSR-E and SMOS in their overlapping period was tested using an inter-comparison exercise between the SMOS and AMSR-E datasets, while the skill of the individual soil moisture products, based on anomalies, was evaluated using two verification techniques; first, a data assimilation technique that links precipitation information to the quality of soil moisture (expressed as the Rvalue), and secondly the triple collocation analysis (TCA). ASCAT soil moisture was included in the skill evaluation, representing the active microwave-based counterpart of soil moisture retrievals. Besides a semi-global analysis, explicit focus was placed on two regions that have strong land–atmosphere coupling, the Sahel (SA) and the central Great Plains (CGP) of North America. The NN approach gives the highest correlation coefficient between SMOS and AMSR-E, closely followed by LPRM and REG, while the absolute error is approximately the same for all three approaches. The Rvalue and TCA show the strength of using different satellite sources and the impact of different merging approaches on the skill to correctly capture soil moisture anomalies. The highest performance is found for AMSR-E over sparse vegetation, for SMOS over moderate vegetation, and for ASCAT over dense vegetation cover. While the two SMOS datasets (L3 and LPRM) show a similar performance, the three AMSR-E datasets do not. The good performance for AMSR-E over spare vegetation is mainly perceived for AMSR-E LPRM, benefiting from the physically based model, while AMSR-E NN shows improved skill in densely vegetated areas, making optimal use of the SMOS L3 training dataset. AMSR-E REG has a reasonable performance over sparsely vegetated areas; however, it quickly loses skill with increasing vegetation density. The findings over the SA and CGP mainly reflect results that are found in earlier sections. This confirms that historical soil moisture datasets based on a combination of these sources are a valuable source of information for climate research.

After publication of the research paper [1], the authors wish to make the following correction to this paper. In the fourth line from the bottom in abstract, due to a typing error, “RMSE = 0.84 m3/m3” should be replaced with “RMSE = 0.084 m3/m3”.[...]

The main goal of the Soil Moisture and Ocean Salinity (SMOS) mission over land surfaces is the production of global maps of soil moisture (SM) and vegetation optical depth (τ) based on multi-angular brightness temperature (TB) measurements at L-band. The operational SMOS Level 2 and Level 3 soil moisture algorithms account for different surface effects, such as vegetation opacity and soil roughness at 4 km resolution, in order to produce global retrievals of SM and τ. In this study, we present an alternative SMOS product that was developed by INRA (Institut National de la Recherche Agronomique) and CESBIO (Centre d’Etudes Spatiales de la BIOsphère). One of the main goals of this SMOS-INRA-CESBIO (SMOS-IC) product is to be as independent as possible from auxiliary data. The SMOS-IC product provides daily SM and τ at the global scale and differs from the operational SMOS Level 3 (SMOSL3) product in the treatment of retrievals over heterogeneous pixels. Specifically, SMOS-IC is much simpler and does not account for corrections associated with the antenna pattern and the complex SMOS viewing angle geometry. It considers pixels as homogeneous to avoid uncertainties and errors linked to inconsistent auxiliary datasets which are used to characterize the pixel heterogeneity in the SMOS L3 algorithm. SMOS-IC also differs from the current SMOSL3 product (Version 300, V300) in the values of the effective vegetation scattering albedo (ω) and soil roughness parameters. An inter-comparison is presented in this study based on the use of ECMWF (European Center for Medium range Weather Forecasting) SM outputs and NDVI (Normalized Difference Vegetation Index) from MODIS (Moderate-Resolution Imaging Spectroradiometer). A six-year (2010–2015) inter-comparison of the SMOS products SMOS-IC and SMOSL3 SM (V300) with ECMWF SM yielded higher correlations and lower ubRMSD (unbiased root mean square difference) for SMOS-IC over most of the pixels. In terms of τ, SMOS-IC τ was found to be better correlated to MODIS NDVI in most regions of the globe, with the exception of the Amazonian basin and the northern mid-latitudes.

This study presents a back propagation neural network (BPNN) method to rebuild a global and long-term soil moisture (SM) series, adopting the microwave vegetation index (MVI). The data used in our study include Soil Moisture and Ocean Salinity (SMOS) Level 3 soil moisture (SMOSL3sm) data, the Advanced Microwave Scanning Radiometer-Earth Observing System (AMSR-E), and Advanced Microwave Scanning Radiometer 2 (AMSR2) Level 3 brightness temperature (TB) data and L3 SM products. The BPNNs on each grid were trained over July 2010–June 2011, and the entire year of 2013, with SMOSL3sm as a training target, and taking the reflectivities (Rs) of the C/X/Ku/Ka/Q bands, and the MVI from AMSR-E/AMSR2 TB data, as input, in which the MVI is used to correct for vegetation effects. The training accuracy of networks was evaluated by comparing soil moisture products produced using BPNNs (NNsm hereafter) with SMOSL3sm during the BPNN training period, in terms of correlation coefficient (CC), bias (Bias), and the root mean square error (RMSE). Good global results were obtained with CC = 0.67, RMSE = 0.055 m3/m3 and Bias = −0.0005 m3/m3, particularly over Australia, Central USA, and Central Asia. With these trained networks over each pixel, a global and long-term soil moisture time series, i.e., 2003–2015, was built using AMSR-E TB from 2003 to 2011 and AMSR2 TB from 2012 to 2015. Then, NNsm products were evaluated against in situ SM observations from all SCAN (Soil Climate Analysis Network) sites (SCANsm). The results show that NNsm has a good agreement with in situ data, and can capture the temporal dynamics of in situ SM, with CC = 0.52, RMSE = 0.84 m3/m3 and Bias = −0.002 m3/m3. We also evaluate the accuracy of NNsm by comparing with AMSR-E/AMSR2 SM products, with results of a regression method. As a conclusion, this study provides a promising BPNN method adopting MVI to rebuild a long-term SM time series, and this could provide useful insights for the future Water Cycle Observation Mission (WCOM).

A method to retrieve soil moisture (SM) from Advanced Scanning Microwave Radiometer—Earth Observing System Sensor (AMSR-E) observations using Soil Moisture and Ocean Salinity (SMOS) Level 3 SM as a reference is discussed. The goal is to obtain longer time series of SM with no significant bias and with a similar dynamical range to that of the SMOS SM dataset. This method consists of training a neural network (NN) to obtain a global non-linear relationship linking AMSR-E brightness temperatures ( T b ) to the SMOS L3 SM dataset on the concurrent mission period of 1.5 years. Then, the NN model is used to derive soil moisture from past AMSR-E observations. It is shown that in spite of the different frequencies and sensing depths of AMSR-E and SMOS, it is possible to find such a global relationship. The sensitivity of AMSR-E T b ’s to soil temperature ( T s o i l ) was also evaluated using European Centre for Medium-Range Weather Forecast Interim/Land re-analysis (ERA-Land) and Modern-Era Retrospective analysis for Research and Applications-Land (MERRA-Land) model data. The best combination of AMSR-E T b ’s to retrieve T s o i l is H polarization at 23 and 36 GHz plus V polarization at 36 GHz. Regarding SM, several combinations of input data show a similar performance in retrieving SM. One NN that uses C and X bands and T s o i l information was chosen to obtain SM in the 2003–2011 period. The new dataset shows a low bias (

Global Navigation Satellite System-Reflectometry (GNSS-R) has emerged as a remote sensing tool, which is complementary to traditional monostatic radars, for the retrieval of geophysical parameters related to surface properties. In the present paper, we describe a new polarimetric GNSS-R system, referred to as the GLObal navigation satellite system Reflectometry Instrument (GLORI), dedicated to the study of land surfaces (soil moisture, vegetation water content, forest biomass) and inland water bodies. This system was installed as a permanent payload on a French ATR42 research aircraft, from which simultaneous measurements can be carried out using other instruments, when required. Following initial laboratory qualifications, two airborne campaigns involving nine flights were performed in 2014 and 2015 in the Southwest of France, over various types of land cover, including agricultural fields and forests. Some of these flights were made concurrently with in situ ground truth campaigns. Various preliminary applications for the characterisation of agricultural and forest areas are presented. Initial analysis of the data shows that the performance of the GLORI instrument is well within specifications, with a cross-polarization isolation better than −15 dB at all elevations above 45°, a relative polarimetric calibration accuracy better than 0.5 dB, and an apparent reflectivity sensitivity better than −30 dB, thus demonstrating its strong potential for the retrieval of land surface characteristics.