1. Free-standing Reduced Graphene Oxide/Carbon Nanotube Paper for Flexible Sodium-ion Battery Applications
- Author
-
Yong Hao and Chunlei Wang
- Subjects
Paper ,Materials science ,anode ,Oxide ,Pharmaceutical Science ,chemistry.chemical_element ,Electrons ,02 engineering and technology ,Carbon nanotube ,010402 general chemistry ,Electrochemistry ,7. Clean energy ,01 natural sciences ,Energy storage ,Article ,Analytical Chemistry ,law.invention ,lcsh:QD241-441 ,chemistry.chemical_compound ,Electric Power Supplies ,Electricity ,lcsh:Organic chemistry ,law ,Drug Discovery ,Humans ,Physical and Theoretical Chemistry ,Electrodes ,reduced graphene oxide/carbon nanotube (rgo/cnt) ,free-standing ,Graphene ,Nanotubes, Carbon ,Organic Chemistry ,Sodium ,Sodium-ion battery ,Electrochemical Techniques ,Cations, Monovalent ,021001 nanoscience & nanotechnology ,0104 chemical sciences ,Anode ,chemistry ,Chemical engineering ,Chemistry (miscellaneous) ,Molecular Medicine ,sodium-ion batteries ,Graphite ,flexible ,0210 nano-technology ,Carbon - Abstract
We propose a flexible, binder-free and free-standing carbonaceous paper fabricated via electrostatic spray deposition using reduced graphene oxide/carbon nanotube (rGO/CNT) as a promising electrode material for flexible sodium-ion batteries (NIBs). The as-prepared rGO/CNT paper exhibits a three-dimensional (3D) layered structure by employing rGO as conductive frameworks to provide sodium-storage active sites and CNT as spacer to increase rGO interlayer distance and benefit the diffusion kinetics of sodium ions. Consequently, the rGO/CNT paper delivers an enhanced sodium ion storage capacity of 166.8 mAh g&minus, 1 at 50 mA g-1, retaining an average capacity of 101.4 mAh g&minus, 1 when current density sets back 100 mA g&minus, 1 after cycling at various current rates. An average capacity of 50 mAh g&minus, 1 at 200 mA g&minus, 1 was stabilized when cycling up to 300 cycles. The well-maintained electrochemical performance of free-standing rGO/CNT paper is due to the well-established hybrid 3D nanostructures, which demonstrates our carbon based material fabricated by a facile approach can be applied as one of the high-performance and low-cost electrode materials for applications in flexible energy storage devices.
- Published
- 2020