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This paper demonstrates a method for the development of stepped-metal coating on optical fiber Bragg grating. The paper also analyzes the dual-peak resonance restructured by the nickel/copper stepped-metal coating. According to the coefficients of linear thermal expansion of the coatings, the modeling and experimental analysis is categorized into three types: Type A, Type B, and Type C. We denote the temperature sensitivity difference between the two peaks as ΔKT for Type A, ΔK′T for Type B, and ΔK″T for Type C. The experimental results show that ΔKT, ΔK′T, and ΔK″T are 2.1 pm/°C, 6.5 pm/°C, and 0.8 pm/°C, respectively. The model analysis and the experimental results all show the Type B stepped-metal coating causes the most obvious temperature sensitivity difference between the two resonance peaks. The stepped-metal coating on the same one Bragg grating can restructure the single resonance into dual-peak resonance with different temperature sensing, and Type B can be used to develop a dual-parameter optical fiber Bragg grating sensor at one location which can measure two physical parameters simultaneously. [ABSTRACT FROM AUTHOR]