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The more economically viable and environmentally sustainable approach for treating the by-products of coal combustion from thermal power plants entails their collective disposal as opposed to individual disposal methods. This aligns with pertinent EU directives and domestic regulations, ensuring compliance with established standards while optimizing resource utilization and minimizing environmental impact. This study evaluated the resistance to wind erosion of the binding properties of a mixture (fly ash (FA), bottom ash (BA), and additives) using an indoor wind tunnel under simulated ambient conditions. Investigations of the mutual impact of ash, bottom ash, and additives (CaO and Ca(OH)2) with a certain percentage of water were carried out with eighteen samples. The samples consisted of the water at six addition rates 5, 8, 10, 15, 20, and 25% (w/w), and additive at three addition rates (1, 2, and 3% (w/w). Based on the obtained results, the optimal ratios of additives (3% (w/w)) and water (15% (w/w)) were determined. Prior to the wind tunnel experiments, and according to the different addition rates of additives and water, eight samples were prepared with different addition rates of ash. The mass concentrations of suspended particles (PM10) and total suspended particles (TSPs) in these samples were measured at three distinct wind velocities: 1 m/s, 3 m/s, and 5 m/s, respectively. The results indicate that the samples containing the optimal content of additives and water demonstrate a maximum increase in PM10 emission zero values of no more than 1.9 times. This finding can be considered satisfactory from the standpoint of environmental protection. [ABSTRACT FROM AUTHOR]

Spent adsorbents used in As removal treatment may re-leach As. In this study, the effects of soil on spent Mg-based and Ca-based adsorbents were investigated. The spent adsorbents containing arsenite (As(III)) were prepared by adsorbing As(III) on MgO, Mg(OH)2, CaO, and Ca(OH)2 powder reagents. Kuroboku soil (Ku), yellow-brown forest soil (YF), Kanuma soil (Ka), river sand (RS), and mountain sand (MS) were used as soil samples. The As leaching ratio was examined in coexistence with soil via shaking tests, and the results were compared with those of a previous study on adsorbents containing arsenate (As(V)). The environmental stability of the spent adsorbents was found to vary greatly depending on the combination of the As valence, adsorbent type, and soil type. However, regardless of the adsorbent or soil type, the spent adsorbents containing As(III) were more likely to leach As than those containing As(V). Additionally, the As leaching ratio was generally lower in Ku and YF and higher in Ka, RS, and MS. For environmentally friendly and sustainable As removal treatment, disposal, and management, the selection of MgO as the adsorbent and treatment involving the oxidation treatment of As(III) to As(V) before adsorbing As onto adsorbents are recommended. [ABSTRACT FROM AUTHOR]

Germany is obliged to report emissions of fluorinated greenhouse gases annually under the UNFCCC. This includes emissions of fluorinated refrigerants when decommissioning RAC equipment. To obtain this information, data on the recovery, recycling, and disposal of fluorinated greenhouse gases is necessary, but such data are scarce. The VDKF-LEC database contains information on the recovery of fluorinated refrigerants from decommissioned RAC equipment in Germany and an extracted dataset was used to obtain real-world information for the years 2017 to 2021. Recovery rates for different fluorinated refrigerants from decommissioned commercial and industrial refrigeration as well as stationary air-conditioning equipment were derived. Furthermore, average lifetimes of equipment for the different sectors were calculated. In the analysis, a dependency of charged refrigerant and age of the unit at decommissioning could be observed. Results from the analysis of the VDKF-LEC dataset were compared with reported data under the UNFCCC for Germany and other available data sources. [ABSTRACT FROM AUTHOR]

Agricultural plastic mulching is an important horticultural process for increasing crop yields because it preserves soil moisture, soil temperature, and nutrients, and avoids the need for weed herbicides. However, there are risks to using plastic mulch, since residual macroplastic (MaP), microplastic (MP), and nanoplastic (NP) in fields have a significant negative impact on the environment, causing damage to soil properties, harming microorganisms in the soil, and entering the human body via the food chain. Plastic mulch is often disposed of in landfills or used in techniques like the thermal process to gain energy or recycling to generate plastic granules for the plastic industry. Pretreatments are occasionally required before recycling, such as cleaning the mulch from the soil to fit the recycling process. This review provides an overview of the quantities and negative impacts of plastic, especially plastic mulch films after use, as well as their decomposition products, on the environment, soil, and human health, and presents alternatives. The possibilities and problems of collecting and recycling films are discussed in addition to the alternatives, for example, the use of biodegradable films. Overall, agricultural advancements to reduce plastic waste in the environment by using thicker films, collection after use, and recycling in developed countries are on a good path. However, NP poses a risk, as it is still completely unclear how it affects human health. Alternatives to plastic mulch have found little acceptance so far due to the significantly higher material costs. [ABSTRACT FROM AUTHOR]

The structural and chemical properties of zirconolite (ideally CaZrTi2O7) as a host phase for separated REE–actinide-rich wastes are considered. Detailed analysis of both natural and synthetic zirconolite-structured phases confirms that a selection of zirconolite polytype structures may be obtained, determined by the provenance, crystal chemistry, and/or synthesis route. The production of zirconolite ceramic and glass–ceramic composites at an industrial scale appears most feasible by cold pressing and sintering (CPS), pressure-assisted sintering techniques such as hot isostatic pressing (HIP), or a melt crystallization route. Moreover, we discuss the synthesis of zirconolite glass ceramics by the crystallization of B–Si–Ca–Zr–Ti glasses containing actinides in conditions of increased temperatures relevant to deep borehole disposal (DBD). [ABSTRACT FROM AUTHOR]

The per capita municipal solid waste (MSW) generation per day in Ghana is estimated to be 0.47 kg/person/day, which translates to over 14,000 tonnes of solid waste generation daily. The disposal and management of this amount of solid waste has been challenging worldwide, and in Ghana, this is evident with the creation of unsanitary dumping sites scattered across most communities in the country, especially urban communities. The indiscriminate disposal of solid waste in Ghana is known to cause flooding, the pollution of water bodies, and the spread of diseases. The purpose of this review is to highlight the prospects of waste incineration with energy recovery as a waste-to-energy (WtE) technology which has contributed immensely to the disposal and management of MSW in nations worldwide (especially developed ones). The review indicates that waste incineration with energy recovery is a matured waste-to-energy technology in developed nations, and there are currently about 492 waste incineration plants in operation in the EU, over 77 in operation in about 25 states in the USA, and about 1900 in operation in Japan. Waste incineration with energy recovery is also gradually gaining prominence in developing nations like China, Brazil, Bangladesh, Nigeria, Indonesia, and Pakistan. The adoption of waste incineration with energy technology can reduce Ghana's overdependence on fossil fuels as primary sources of energy. It is, however, recommended that a techno-economic assessment of proposed waste incineration facilities is performed considering the MSW generated in Ghana. Additionally, it is also recommended that the possibility of incorporating the use of artificial intelligence technology into the management of MSW in Ghana be investigated. [ABSTRACT FROM AUTHOR]

Municipal solid waste collection must reach the recycling rates required by new regulations, like with the introduction of new bins to collect the organic fraction. The filling pattern of those bins is unknown, and the collection frequency and collection routes can change. Sensors can help to identify the filling degree and to reorganize the waste collection routes. Yet, equipping all the bins with new technologies can represent a significant amount of money for enterprises and public authorities. The aim of this work is to analyze the use of sensors in waste collection systems where the collection frequency is high. Bins from two zones of a town (a residential and a commercial zone) were selected, and a volumetric sensor was installed to study the filling pattern. In the first scenario, the organic fraction and the mixed waste bin were monitored. In the second experiment, data from mixed waste bins were recorded during two days of the week. Results show that the filling degree pattern is similar in all the cases and that citizens do not respect the recommended times for taking their waste out. Additionally, the cost of the sensors represents a significant amount for a medium-sized town. Although sensors can provide a great amount of information, it is not necessary to install them in all the bins but only at the points to be analyzed. This work proposes a new way to use sensors to validate and calibrate the containerization network of a town with a high collection frequency. [ABSTRACT FROM AUTHOR]

The activity and disposal options for irradiated Be12Ti were assessed for the HCPB DEMO blankets making use of a code system that enables performing 3D activation calculations by linking the Monte Carlo transport code MCNP and the fusion inventory code FISPACT through an appropriate interface. The dedicated full-scale geometry MCNP model of the 11.25 degree HCPB DEMO torus was adapted to the requirements for the coupled 3D neutron transport and activation calculations. Special attention was paid to the use in the activation calculations of the commercial materials containing technological impurities. This has a crucial effect on the results and the impurities must be accounted for in any nuclear safety analyses. The short-term activity is formed by the radionuclides produced through the activation of Be and Ti nuclei and the long-term activity is formed by the products of the neutron irradiation taking place on the impurities. A prerequisite for the disposal or the recycling of the irradiated Be12Ti is its deep detritiation; otherwise, the very high-tritium activity would fully prevent any attempt for its treatment. The most preferable is the use of the Be12Ti with the composition including less material impurities, especially uranium. There could be the option to dispose the Be12Ti intermediate-level wastes in the French repository after 1 year of cooling, assuming the detailed control of the impurities that fulfil the French authority requirements. The USA near-ground repositories could be an alternative to the European sites. The recycling of the irradiated Be12Ti must first be elaborated and approved to ensure its treatment in a safe and efficient way. The remote handling technique must be developed for the re-fabrication of the Be12Ti blocks. [ABSTRACT FROM AUTHOR]

Definition: Nuclear waste (like radioactive waste) is waste that contains, or is contaminated with, radionuclides, at activity concentrations greater than clearance levels set by the regulators, beyond which no further use is foreseen. Disposal is the emplacement of waste in an appropriate facility without the intention to retrieve it. [ABSTRACT FROM AUTHOR]

The paper describes the results obtained from a large-scale trial designed to assess the impact of the backfilling of waste mine burden in an exhausted pit on the quality of lake water. The trial aimed at understanding the interaction between groundwater and clay and silty sand soils composing the overburden material. The two main environmental concerns related to the turbidity of the water and the concentration of sulphate ions. Tests were designed to (I) assess the interaction between soil and water; (II) measure the turbidity of water, related to the amount of solid particles in suspension; (III) observe the sedimentation of fine particles; (IV) measure the concentration of sulphate ions during backfilling and water pumping operations; and (V) validate an analytical model for the prediction of sulphate quantity in water. The main results indicated that the basin was capable to retain particles with sizes in the order of diameters that were nearly 10 microns. The water pumping was responsible for a relevant motion of fine particles (diameter less than 2 μm); this effect impacted on the turbidity level observed at the outflow in a relevant way. On the other hand, the test indicated that the estimation of the release of sulphate ions in the water was heavily affected by a proper assumption of the average background values of the concentration of sulphate ions in the water before the dumping activity. [ABSTRACT FROM AUTHOR]

Featured Application: This work provides fundamental information regarding the technical, environmental, and economic viability of granite sludge valorisation as a substitute for feldspar in a ceramic paste and as a substitute for fine–medium inert in structural concrete. The granite sludge (GS) produced during block sawing can be exploited as alternative raw material in ceramic and concrete industries. Based on the case study of a Portuguese granite processing plant, this work analysed, by experimental tests and Environmental and Cost Life Cycle analyses, the feasibility of GS valorisation as a substitute (i) for feldspar in a ceramic paste and (ii) fine–medium inert filler in structural concrete. The results demonstrated that both the valorisation pathways are more advantageous than GS landfilling. Due to granulometric, mineralogical composition and shrinkage, GS can substitute feldspar in sandstone tiles or tableware products, although its tinting effect can limit noble whitish ceramic applications. In structural concrete mixes, 5% w/w GS instead of fine inert filler reduces the compressive strength and increases the water:cement ratio. The GS generates lower environmental impacts as a substitute for inert filler than as a substitute for feldspar in most of the impact categories analysed, even though the latter valorisation pathway provides higher benefits in Climate Change and the Depletion of Fossil resources, Water, and Ozone. If no monetary value is recognised for GS valorisation by the market, the sustainability of GS life cycle cost decreases when compared to its landfilling. [ABSTRACT FROM AUTHOR]

Green roofs are increasingly being used in urban settings because of the many benefits they are capable of providing. Because of their widespread use, the issue of how to conduct proper disposal of green roofs once they have reached their end of life is beginning to be raised. The present study is a review of the scientific literature published between 2007 and 2022. Specifically, the contribution of this review study is to clarify whether a waste scenario exists and if so, identify the methodological frameworks and/or criteria used in green roof-related studies to establish the end-of-life scenario of a given green roof, which will then be used to analyze its environmental and economic performance. The literature analysis indicated that a standardized method, widely adopted, which allows identifying recovery and/or disposal treatments to be assigned to waste from the disposal of a green roof, is missing. In general, the feeling one gets from reading all these articles is that when it comes to the end of life of green roofs, everything is rather vague, and that one proceeds in no particular order. The main results of the study are a collection of the criteria currently proposed in the literature to identify the end-of-life scenario of green roofs. These essentially include predominant waste management practices in place in the country where the green roof is located, safety sheets of products constituting single layers of the green roof, and statistical data on the management of specific types of waste. The results also include an overview of the current body of knowledge related to the management of the end-of-life of these building components. This study also intends to serve as a starting point for opening a debate on the disposal of green roofs, a current hot topic and still open as it has not yet been codified. Finally, some recommendations for future research work in this field are proposed. [ABSTRACT FROM AUTHOR]

Bauxite residue (BR), also known as red mud, is a byproduct of the alumina production using the Bayer process. This material is not used to make iron or other iron-containing products worldwide, owing to its high content of sodium oxide and other impurities. In this study, we investigated the hydrochemical conversion of goethite (FeOOH) to magnetite (Fe3O4) in high-iron BR from the Friguia alumina refinery (Guinea) by Fe2+ ions in highly concentrated alkaline media. The simultaneous extraction of Al and Na made it possible to obtain a product containing more than 96% Fe3O4. The results show that the magnetization of Al-goethite and Al-hematite accelerates the dissolution of the Al from the iron mineral solid matrix and from the desilication product (DSP). After ferrous sulfate (FeSO4·7H2O) was added directly at an FeO:Fe2O3 molar ratio of 1:1 at 120 °C for 150 min in solution with the 360 g L−1 Na2O concentration, the alumina extraction ratio reached 96.27% for the coarse bauxite residue size fraction (Sands) and 87.06% for fine BR obtained from red mud. The grade of iron (total iron in the form of iron elements) in the residue can be increased to 69.55% for sands and 58.31% for BR. The solid residues obtained after leaching were studied by XRD, XRF, TG-DTA, VSM, Mössbauer spectroscopy, and SEM to evaluate the conversion and leaching mechanisms, as well as the recovery ratio of Al from various minerals. The iron-rich residues can be used in the steel industry or as a pigment. [ABSTRACT FROM AUTHOR]

This descriptive cross-sectional study aimed to assess the knowledge and practices of pharmacy and nursing students at a medical college in Kosovo concerning unused and expired medications. A self-administered questionnaire was distributed to 500 randomly selected students of pharmacy (200 questionnaires) and nursing students (300 questionnaires). Overall, 336 returned the filled forms and the response rate was 67.2. SPSS version 26.0 was utilized for statistical analysis. The results showed that 89.2% of pharmacy students and 82.2% of nursing students check the expiration date of medications before purchasing them and a considerable number of students stated that they possess unused medicines at home (78.4% of pharmacy and 74% of nursing students). Regarding disposal practice, over 50% of both nursing and pharmacy students dispose of unused and expired medications in the trash. A small proportion of students returned unused or expired medicines to the pharmacy (11.4% of pharmacy students and 10.7% of nursing students return unused medications, whereas 14.4% of pharmacy respondents and 10.1% of nursing respondents reported returning expired medicines). There was a statistically significant difference in the ways pharmacy and nursing students purchase pharmaceuticals and in their opinions regarding institutions in charge of disposing of unused and expired medicines (p = 0.000). Students are aware of the detrimental effects improper disposal of unused and expired medicines has on the environment and public health, but lack information regarding the return of unused and expired medicines to the pharmacy. To change the existing practice the most appropriate method would be to add additional lectures on safe disposal practices into existing modules. It is recommended for involved stakeholders in Kosovo to organize training, seminars, and workshops for health professionals especially pharmacists and nurses, since they pass the information to patients/consumers as well as the government to make amendments to current legislation to ameliorate the returning procedures for patients/consumers in pharmacies. [ABSTRACT FROM AUTHOR]

The scientific community has revealed the environmental benefits of recycling construction waste (CW) versus its disposal, and its contribution to circularity. The Life Cycle Assessment (LCA) method enables the environmental impact of CW management to be quantified and facilitates the comparison of recycling versus alternative disposal scenarios. However, due to its complexity, LCA is seldom used by technicians during the design phase, which constitutes a crucial stage in the prevention of environmental impacts. This paper therefore proposes an LCA-based tool, integrated into the Building Information Modelling (BIM) methodology, that helps designers to automate the environmental assessment of recycling versus disposal. The CW-LCA-BIM tool uses impact factors obtained from an LCA model applied to CW and was applied to the structural system of a building in Spain. Up to 99% of the non-hazardous waste was recyclable or reusable. The management of three types of recyclable waste was assessed: concrete (27.2 t), plastics (4.2 t), and steel (1.5 t). Recycling is shown to be the best option since it prevents 1.4 times (14.6 t) the emissions of the disposal scenario and saves 85 times (148.5 GJ) its energy consumption. This tool can be developed in other waste management systems and infrastructures. It can be useful both for designers for the reduction of the environmental impact of their buildings, and for policy managers for waste-prevention policies. [ABSTRACT FROM AUTHOR]

We present a concise mini overview on the approaches to the disposal of nuclear waste currently used or deployed. The disposal of nuclear waste is the end point of nuclear waste management (NWM) activities and is the emplacement of waste in an appropriate facility without the intention to retrieve it. The IAEA has developed an internationally accepted classification scheme based on the end points of NWM, which is used as guidance. Retention times needed for safe isolation of waste radionuclides are estimated based on the radiotoxicity of nuclear waste. Disposal facilities usually rely on a multi-barrier defence system to isolate the waste from the biosphere, which comprises the natural geological barrier and the engineered barrier system. Disposal facilities could be of a trench type, vaults, tunnels, shafts, boreholes, or mined repositories. A graded approach relates the depth of the disposal facilities' location with the level of hazard. Disposal practices demonstrate the reliability of nuclear waste disposal with minimal expected impacts on the environment and humans. [ABSTRACT FROM AUTHOR]

This article presents a study on hazardous waste management in the Malopolskie region of Poland. The study was based on the information obtained during three years from 2016 to 2018, and following analysis, it was found that in 2016 there was the highest amount of 24,872.13 tons of hazardous waste produced, of which only a three-fold lower amount was disposed of. In this study, various types of hazardous waste were analyzed, including the waste from construction materials and asbestos. The predominant share of 50% of the mass of analyzed hazardous waste was felt on the generated one. Waste recovered in installations had a lower share of 43%, with a significant and favorable increase of over 5000.00 tons. In the context of the correctness of environmental aspects, it was considered an advisable solution that would optimize treatment conditions, and at the same time minimize the costs of hazardous waste management. [ABSTRACT FROM AUTHOR]

The disposal of high-level radioactive waste (HLW) in deep stable geological formations is accepted at an international level to be the most promising option for its long-term management. The supercontainer concept is currently being considered as the Belgian reference design, wherein the waste will be stored in geological stable clay formations. The outer barrier of the supercontainer is the envelope, which should be made of a corrosion-resistant material as it will be in contact with the aggressive species leaching from the host rock (i.e., chloride) and diffusing through the cementitious barriers of the disposal system. Polarization measurements are carried out to study the pitting susceptibility and the uniform corrosion of possible candidate materials in chloride-rich concrete pore solutions, aerated by high-purity oxygen. The tests are carried out at a deep soil-representative temperature of 60 °C. All materials showed high pitting resistance in aerated concrete pore solutions and can withstand chloride concentrations up to 1 M. Regular 316L and LDX2304 stainless steel also showed good corrosion resistance and can serve as a more economical alternative. The pH of the used pore solutions did affect the measured corrosion rate irrespective of the alloying elements inside the steel grades. [ABSTRACT FROM AUTHOR]

Liquid fuel can be an alternative to solid fuel in non-gasified locations. The mazout for municipal-energy boiler plants is much cheaper than fuel oil. However, this relates to the problem of wastewater disposal from such a boiler plant. A proprietary system for the disposal of bottom water and other sewage-containing mazout has been developed. The solution depends on the proper preparation and burning of a water–mazout emulsion (WME). The emulsion is prepared in a specially designed and developed dosing ejector. By burning the emulsion using the developed system, an efficiency increase of 2–3% was achieved for boilers operating on the mazout fuel. Such a result was achieved due to a reduction in the excess air factor. Moreover, emissions of nitrogen oxides and carbon monoxide were reduced by 30–35% and 70–80%, respectively. In addition due to cleaning the heat-exchange surfaces obtained when working on the WME, the amount of time for productive and more efficient use of the equipment has increased. [ABSTRACT FROM AUTHOR]

Despite being considered a consumption behaviour, disposal is still treated in an incipient way in the consumer literature. In addition, little is known about the entire journey of those who practice sustainable consumption disposal. In order to fill this gap, this exploratory, qualitative study used semi-structed interviews with 15 consumers who already discarded items through return programmes for recycling purposes of two products: slow fashion wallets and coffee capsules. The products are from two companies in Brazil, Dobra and Terra Cycle, whose managers were also interviewed. Records of photos and videos made by these consumers were also part of the research material, in addition to the analysis of brands' social media. Content analysis with deductive coding was used to analyse the data. The results allow for the proposition of a disposal journey framework and the understanding of this journey and its touchpoints for the products as a different trajectory. Still, it was found that detachment, emotional and mental separation from the product, only happens in some circumstances. The theoretical, managerial, and social implications of this journey of sustainable consumption disposal are discussed. [ABSTRACT FROM AUTHOR]

The spent adsorbents left after treating arsenic-contaminated water contain large amounts of arsenic. These spent adsorbents may come into contact with silicic acid leached from soil or cementitious solidification materials in the disposal environment. Thus, it is important to evaluate the effects of silicic acid on spent adsorbents containing arsenic. In this study, the effects of silicic acid on spent Mg-based adsorbents (magnesium oxide (MgO) and magnesium hydroxide (Mg(OH)2)) containing arsenite were investigated. The arsenic leaching ratios of both spent adsorbents decreased slightly with an increase in the initial silicic acid concentration of the eluent. The arsenic leaching ratio decreased from 1.24% to 0.69% for MgO and from 5.97% to 4.71% for Mg(OH)2 at an initial Si-normalized concentration of 100 mg/L. The primary mechanism behind the inhibition of arsenic leaching by silicic acid was determined to be the difficulty of arsenic desorption due to the coating effect following the adsorption of silicic acid species. The results indicate that the arsenic leaching related to the ion exchange reaction with silicic acid hardly occurred for the spent Mg-based adsorbents. Compared with various spent Mg-based and Ca-based adsorbents, the spent MgO adsorbent exhibited the highest environmental stability and best performance. [ABSTRACT FROM AUTHOR]

This study performed a Life Cycle Assessment of the collection, transport, treatment and disposal of source-separated municipal waste (MW) in Baronissi, a town of 17,000 inhabitants in the Campania region of Italy. Baronissi is a high-performing town in a region with scarcity of MW facilities. The environmental impacts were assessed with three different methods--IPCC 2007, Ecological Footprint and ReCiPe 2008--in order to evaluate how they influence the results as well as how the global warming affects the results, since it is one of the major environmental concerns of people. The obtained results showed how the presence of facilities in the area is fundamental. Their lack means high environmental loads due to the transportation of materials for long distances, particularly for the organic fraction. The presence of a composting plant at 10 km from the municipality would result in a decrease of 65% of the impacts due to the external transport, regardless of the evaluation method. The results obtained with ReCiPe 2008 and Ecological Footprint agreed, while those obtained with IPCC 2007 were very different since global warming is strongly affected by the transport phase. IPCC 2007 does not allow to take into account the advantages obtainable with a good level of separate collection. Considering a single impact evaluation method, there is a high risk of coming to misleading conclusions. [ABSTRACT FROM AUTHOR]

Pharmaceutical wastes are expected to increase given the increasing population growth rates and rapidly rising economic burden of human diseases. This challenge calls for appropriate measures for the management of such hazardous wastes. The purpose of this survey was to document and investigate existing practices for the handling, storage, and disposal of household pharmaceutical wastes (HPWs) in the Johannesburg area. Primary data were collected via online surveys with self-administered questionnaires completed by respondents. The research found that 77% ( n = 286) of respondents claimed some knowledge about HPWs. Types of medicines that contributed to HPWs included painkillers or analgesics (73%, n = 270) and drugs for treating colds and flu-related illnesses (52%; n = 193). Although there were a few exceptions, the respondents generally exhibited strong disagreements with environmentally unfriendly and health-threatening disposal practices. Moreover, most participants were willing to return expired medicines to pharmacies (40.7%, n = 151), whereas only 8.6% ( n = 32) opposed this solution. Awareness levels tended to vary with employment status, educational qualifications, and place of residence. However, place of residence and household size did not correlate with types of pharmaceutical waste. Additionally, the study found that education attainments significantly influenced the willingness of respondents to return pharmaceutical wastes. Finally, there were no significant differences amongst respondents in terms of waste disposal practices. Altogether, the findings suggest the need for targeted efforts to bring about sustainable waste management at a household level.

In light of the increasing demand for energy sources in the world and the need to meet climate goals set by countries, there is growing global interest in high temperature gas cooled reactors (HTGRs), especially as they are known to be inherently safe nuclear reactors. The safety of HTGRs results, among other, from the nature of the nuclear fuel used in them in the form of coated TRISO particles (tri-structural-isotropic) and the reduction of the total amount of radioactive waste generated. This paper reviews numerous methods used to ensure the sustainable, feasible management and long-term storage of HTGR nuclear waste for the protection of the environment and society. The types of waste generated in the HTGR cycle are presented as well as the methods of their characterization, which are important for long-time storage and final disposal. Two leading nuclear fuel cycle strategies, the once-through cycle (direct disposal or open cycle) and the twice-through cycle (recycling or partially closed cycle), are discussed also in relation to TRISO spent fuel. A short review of the possibilities of treatment of TRISO spent nuclear fuel from HTGR reactors is made. [ABSTRACT FROM AUTHOR]

The discovery of an innovative class of inorganic polymers has brought forth a revolution in the history of construction technology. Now, no energy-intensive reactions at elevated temperatures are essential, as found in the case of contemporary cement production. In addition to their attributes of low energy and a mitigated carbon footprint, geopolymeric composites can incorporate diversely originated and profound wastes in their manufacturing. As of today, profoundly accessible landfills of rubber tyre waste negatively impact the environment, water, and soil, with many health hazards. Their nonbiodegradable complex chemical structure supports recycling, and toxic gases are emitted by burning them, leading to aesthetic issues. These, altogether, create great concern for well-thought-out disposal methods. One of the achievable solutions is processing this waste into alternative aggregates to thus generate increased economic value whilst reducing primary aggregate consumption through the incorporation of these vast automobile solid wastes in the manufacturing of geopolymer construction composites, e.g., binders, mortar, concrete, etc., produced through the process of geopolymerization as a replacement for natural aggregates, providing relief to the crisis of the degradation of restricted natural aggregate resources. Currently, tyre rubber is one of the most outstanding materials, extensively employed in scores of engineering applications. This manuscript presents a state-of-the-art review of value-added applications in the context of rubberized geopolymer building composites and a review of past investigations. More significantly, this paper reviews rubberized geopolymer composites for their value-added applications. [ABSTRACT FROM AUTHOR]

The concept of sustainable development was introduced in Europe by the Treaty of Amsterdam (1997) and was extended to waste management in the Waste Framework Directive. In order to achieve sustainable development, hazardous waste (HW) must be managed safely and in accordance with regulations. This also applies to worldwide HW transport, especially when HW is shipped for disposal. The United Nations, through the Basel Convention, aims to prevent the export of HW from developed countries to developing countries for disposal. In Europe, HW shipments are regulated by Regulation (EC) No. 1013/2006 of the European Parliament and by the Council of 14 June 2006 on shipments of waste. Additionally, all HW shipments must be in accordance with two principles contained in the Waste Framework Directive: proximity and self-sufficiency. Using data from 2014 and network analysis methodology, this paper fills the gaps in the scientific literature by looking at how shipments of HW travel for disposal in Europe, how the regulations affect these shipments and how GDP per capita influences the shipment of waste. The results show that countries with a high GDP per capita play an important role in the network (having the highest in-degree) and that the absence of landfill taxes for HW does not influence HW shipments for disposal. Therefore, countries in the EU act in accordance with the proximity and self-sufficiency principles. [ABSTRACT FROM AUTHOR]

In this study we investigate how consumers in The Netherlands can be persuaded to adopt sustainable practices when purchasing, using and disposing of clothes. This study investigates the attitude-behavior gap for the sustainable choices for purchase, use and disposing of clothes. For each consumption phase we ran a two-step multiple regression. The findings showed that the importance of the factors vary in the three consumption phases. For purchasing and disposal decisions, the core motivator social motivation predicts sustainable practices best, while it has no role in the usage phase. The factor ability appeared to have a significant role in the disposal phase, but not in the other phases. Finally, the trigger appears to lower the consumers' ability in the purchasing phase, while it enhances the core motivator social evaluation in the disposal phase. [ABSTRACT FROM AUTHOR]

The environmental impacts of five waste management scenarios for polylactic acid (PLA)-based bioplastics and food waste were quantified using life cycle assessment. Laboratory experiments have demonstrated the potential for a pretreatment process to accelerate the degradation of bioplastics and were modeled in two of the five scenarios assessed. The five scenarios analyzed in this study were: (1a) Anaerobic digestion (1b) Anaerobic digestion with pretreatment; (2a) Compost; (2a) Compost with pretreatment; (3) Landfill. Results suggested that food waste and pretreated bioplastics disposed of with an anaerobic digester offers life cycle and environmental net total benefits (environmental advantages/offsets) in several areas: ecotoxicity (−81.38 CTUe), eutrophication (0 kg N eq), cumulative energy demand (−1.79 MJ), global warming potential (0.19 kg CO2), and human health non-carcinogenic (−2.52 CTuh). Normalized results across all impact categories show that anaerobically digesting food waste and bioplastics offer the most offsets for ecotoxicity, eutrophication, cumulative energy demand and non-carcinogenic. Implications from this study can lead to nutrient and energy recovery from an anaerobic digester that can diversify the types of fertilizers and decrease landfill waste while decreasing dependency on non-renewable technologies. Thus, using anaerobic digestion to manage bioplastics and food waste should be further explored as a viable and sustainable solution for waste management. [ABSTRACT FROM AUTHOR]

In developing countries, landfills of urban solid waste (USW) are a major source of contamination. One reason is the common practice of the illegal confinement of hazardous waste (HW). The contamination is mainly due to deficitary design location, operation and lack of liner, which enables the dispersion of pollutants. The aim of our work is to demonstrate the presence of heavy metals (HM) and arsenic (As) in USW of the closed dump of Morelia, which clandestinely confined HW for 20 years. Solid samples of USW were collected from eight opencast wells with different age of confinement. Composition, degradation status, physical-chemical characterization and analysis of HM and As were carried out. The results showed the presence of Pb, Cu, Ni, Zn, Cr, Fe and high concentrations of As. This study provides evidence about the usual and illegal practice of landfill HW together with USW; the hazard due to the presence of HM and As; the deficiency in the operation and closure; and, the lack of competent legislation on the subject. This information is essential to establish background information for improving laws and help decision makers in territorial planning to improve public and environment health. [ABSTRACT FROM AUTHOR]

Simple Summary: Companion animals are increasingly seen as a valued member of the family unit, and when disaster strikes their guardians often act protectively of them even at the risk to human safety. This behaviour has been observed in numerous disasters and as a result of Hurricane Katrina in 2005, the United States passed specific federal law to protect companion and service animals in a bid to acknowledge that in doing so it would also benefit the wellbeing and safety of its citizens. This article explores the effectiveness of current legislative arrangements in New Zealand with a focus on powers to seize and dispose of companion animals during and following an emergency, as well as other legal considerations for public safety. Though specific to New Zealand, the recommendations provide generic considerations that may enhance the legislative frameworks in other countries to improve both animal and human safety and wellbeing. With the increasing societal expectation that animals are afforded greater protection in emergencies, the legal process from entering a property to rescuing a companion animal, through to how to dispose of such animals if they remain unclaimed has not been well examined in New Zealand. It is hypothesised that the legal framework for such a response is flawed. In this study, each phase of animal disaster rescue is evaluated against four key statutes that may apply in each phase, in that does any statute provide clear end-to-end provisions with clear legal authority to do so? The study found that all statutes evaluated contained flaws and that the current legal provisions are insufficient to provide clear authority for the sequential process of undertaking the rescue of animals during emergencies. A major flaw was discovered in the Civil Defence Emergency Management Act 2002, a key statute, that provided for the seizure of property and animals but omitted a procedure for the disposal of such seized things leaving them all in legal limbo. It is recommended that animal disaster laws be updated to be more animal inclusive. The method also may be applicable to assist evaluating animal disaster management legal frameworks in other countries. [ABSTRACT FROM AUTHOR]

This work studies a hybrid manufacturing–remanufacturing system with a sorting line and disposal. In particular, it models a company that collects used product, remanufactures returned products that have been evaluated as suitable to be recovered, and manufactures new products to satisfy customer demand. Specifically, the system is modeled as a multilevel inventory system, with three types of stock (used products inventory, recoverable inventory, and serviceable inventory), each characterized by an inventory holding cost, and three limited capacity resources: a sorting line, which enables the company to distinguish those returns that are remanufacturable from those that are not; a remanufacturing line to carry out operations on sorted remanufacturable returns; and a manufacturing line to produce new products in order to satisfy customer demand. Each resource is characterized by a setup cost, as well as a constant production rate, while each type of stock is associated with an inventory holding cost. The aim of the paper is to develop a model for the considered production system in order to minimize the setup and inventory holding costs. In particular, the objective is to evaluate the behavior of a controllable disposal rate with the minimization of the total cost function, by considering the effect on the remanufacturing and manufacturing lines. [ABSTRACT FROM AUTHOR]

Cultivation of olive trees and olive oil production have been considered as a legacy for the Mediterranean region. This custom represents a very important benefit for many nations in terms of wealth and health. However, huge amounts of by-products and waste are generated during olive oil production. This represents a serious environmental impact on land and water bodies if not properly handled. Olive oil extraction generates two waste streams, a solid waste called pomace and olive mill wastewater (OMWW), which has been considered as highly pollutant and phytotoxic waste. These wastes have high disposal costs and predominantly generated from small-scale enterprises that have limited financial resources to treat them properly before discharge to the environment. Besides being a serious environmental problem, OMWW has potential economic value that remains to be utilized such as: fertilizers, valuable antioxidants agents and fatty acids needed in human diet. Also, Olive pomace is a valuable renewable energy source with an energy density of 23 MJ/kg and has become an inexpensive alternative for fossil fuels. Aiming at adding value to the olive production sectors and potential valorization options for byproducts in the MENA region, international practices applied in olive mills wastes management's and treatment methods used in major oil producing countries are presented. [ABSTRACT FROM AUTHOR]

As a result of agri-food production large amounts of organic waste are created in the form of press cakes. Until now, they were mainly used as animal fodder and also utilized for biofuels production. No other way usage has been found yet. A large quantity of these by-products is usually discarded in open areas, which leads to potentially serious environmental problems. The rich chemical composition of these waste products makes it possible to use them for producing other food products valuable for consumers. Based on the test results obtained, it can be stated that moisture content of press cakes is varied and depends on the input material. However, appropriately composed mixtures of various waste products and a properly conducted compaction process allows for obtaining a new product with functional properties. In addition, application of honey powder and starch tablet coating creates a product of resistant to compression and cutting. Results seem to have commercial importance, as they demonstrate that properly processed by-products can be used in food preparations as dietary supplements. [ABSTRACT FROM AUTHOR]

Nearly 290,000 tons of electronic waste was generated in Nigeria during the year 2017, which is likely to increase further due to high population growth rates, accelerated urbanization, high demand for electronic products, as well as disposal at their end-of-life. At the same time, e-waste is associated with negative human health impacts, as well as environmental pollution. Therefore, environmental awareness on this waste stream is crucial in its management and possible minimization. In this paper, we report on a survey which investigated awareness levels and knowledge amongst households in the Jos metropolis, Plateau State (Nigeria). We interviewed 228 respondents by means of close-ended questionnaires. The results indicated that cell phones (93%) and television sets (82%) were mentioned by most respondents. The main reasons for acquiring these electronic devices entailed the replacement of damaged ones (49.6%), frequent product upgrades (37.7%), as well as theft (35.55%), amongst others. The most predominant method of disposing e-waste included illegal dumping in open spaces along with other household wastes (25%), storing it at home indefinitely (27.6%), and selling it to others for possible reuse (17.5%). Although the handling and storage of this waste is currently inappropriate, most respondents (84.2%) were willing to participate in its management provided they are given appropriate knowledge (89.9%) on its safe disposal and recycling. Lastly, we found no significant correlation between existing awareness levels on e-waste and willingness to participate in its management based on the socio-demographical profile of respondents. Thus, we recommend educational interventions on sound e-waste management in the Jos metropolis, along with a systematic analysis of how policy interventions such as the extended producer responsibility schemes can be designed for effective e-waste management and recycling amongst all stakeholders. [ABSTRACT FROM AUTHOR]

The environmental conditions for the planned geological disposal of radioactive waste —including hyper-alkaline pH, radiation or anoxia—are expected to be extremely harsh for microbial activity. However, it is thought that microbial communities will develop in these repositories, and this would have implications for geodisposal integrity and the control of radionuclide migration through the surrounding environment. Nuclear waste contains radioactive isotopes of selenium (Se) such as 79Se, which has been identified as one of the main radionuclides in a geodisposal system. Here, we use the bacterial species Stenotrophomonas bentonitica, isolated from bentonites serving as an artificial barrier reference material in repositories, to study the reduction of selenite (SeIV) under simulated geodisposal conditions. This bacterium is able to reduce toxic SeIV anaerobically from a neutral to alkaline initial pH (up to pH 10), thereby producing elemental selenium (Se0) nanospheres and nanowires. A transformation process from amorphous Se (a-Se) nanospheres to trigonal Se (t-Se) nanowires, through the formation of monoclinic Se (m-Se) aggregates as an intermediate step, is proposed. The lesser solubility of Se0 and t-Se makes S. bentonitica a potential candidate to positively influence the security of a geodisposal system, most probably with lower efficiency rates than those obtained aerobically. [ABSTRACT FROM AUTHOR]

The prevalence of unused medications in homes has dramatically increased in recent decades, which has resulted in medication wastage. The aim of this study is to review the prevalence of unused medications in homes and to determine the reasons behind this disuse, so as to help reduce such wastage. The review also sheds light on current methods of disposal of unwanted medications. Here, using a narrative review, we provide an overview of the issues of unused medications, medication wastage, and methods of disposal. We conducted an extensive literature search focusing on subject-related keywords, as given in the methods section below. A search was undertaken through indexing services available in the library of the authors' institution. Full-text papers concerned with the prevalence of unused medications in homes, written in English language between 1992 and 2018, were retrieved and reviewed. Twenty-five related studies performed in different world regions were reviewed and included. The public, healthcare providers, and governments are all accused of promoting medication wastage in different ways, and thus, they need to be targeted to solve the problem. It was also noticed that the prevalence of unused medications is high in many countries. Non-steroidal anti-inflammatory drugs are among the most frequently wasted medications, and most of the public just dispose of their expired medications in the trash or toilet. Non-adherence, death, and medication change are among the main causes of medication accumulation and consequent wastage. A lack of policies to return unwanted medications in some countries, as well as public unawareness, carelessness, or illiteracy, are reasons for improper disposal of unused medications that may lead to adverse economic and environmental impacts. Various mitigation strategies (e.g., smart medicine cabinet) have emerged to reduce medication wastage. Joint work among the public, healthcare providers, and various governmental and private organizations is needed to adequately address the issue of medication wastage. [ABSTRACT FROM AUTHOR]

Introduction: Pharmacist roles promoting safe opioid use are recognized in literature and practice. Pharmacists can offer services such as counseling on opioid risks, naloxone dispensing, education on opioid storage and disposal, prescription drug monitoring program (PDMP) utilization, opioid deprescribing, and providing resources for addiction treatment to help mitigate the opioid crisis. Objective: This commentary seeks to describe current and potential roles for pharmacists to combat the United States opioid crisis and identify key factors affecting service provision. Methods: The paper summarizes evidence-based studies describing current pharmacist roles and services, factors affecting service implementation, and strategies to further improve pharmacist roles and services related to promoting safe opioid use for patients. Results: Pharmacists recognize their roles and responsibilities to counsel patients on opioid risks, dispense naloxone, educate on opioid storage and disposal, utilize prescription drug monitoring programs (PDMPs), offer opioid deprescribing, and provide resources for addiction treatment. However, pharmacists express low confidence, time, and training as barriers to service provision. This suggests a need for structured training, resources, and organizational support for pharmacists to improve confidence and participation in such services. Conclusions: Although pharmacists are aware of roles and responsibilities to help reduce the opioid crisis, more training, education, organizational support and resources are needed to increase their ability to embody these roles. [ABSTRACT FROM AUTHOR]

Background: The aim of this study was to determine the type, quantity, and cost of medications being disposed of by clients in a specifically-set pharmaceutical disposal bin at a village community pharmacy. Methods: Medicines placed in a medication disposal bin by clients were examined during a nine-month period from April to December 2018. The data recorded included the active ingredient, trade name, dose, dosage form, disposed quantity, and the actual expiry date on the pack. The medications were classified according to ATC (Anatomical Therapeutic Chemical Classification System) code, and the cost of the amount wasted was calculated using the pharmacy's price list. Descriptive statistics were used to analyze the data. Results: A total of 411 medications were collected, amounting to a total cost of approximately €2600. The largest group of medications belonged to the alimentary group, and this also represented the group with the highest monetary value. The number of months that medicinal products were retained by patients beyond the expiry date ranged from 1 to 232. Conclusion: This small study provides a glimpse of what clients dispose of in a medication bin when this is readily available in their community pharmacy, a simple measure which, if adopted on a national level, could aid in ensuring the appropriate disposal of wasted medication. [ABSTRACT FROM AUTHOR]

Environmental contamination due to the disposal of expired or obsolete drugs is a concern, since there is no specific Brazilian legislation, regarding disposal by the final consumer, thus reflecting the need for reverse logistics of medicines, after their consumption. The objective of this study was to survey the knowledge of pharmacists regarding their role in the reverse logistics of medicines and to understand the contribution of reverse logistics, aimed at the appropriate disposal of Group B waste, on a voluntary basis, by the population, in the municipality of São Paulo. A survey conducted through interviews with a hundred and sixty-one pharmacists demonstrated that 35% have partial knowledge of the postconsumer reverse logistics of their place of work and 16.8% have complete knowledge of the environmental harm resulting from the contamination of medicinal waste. The pharmacists also reported (10%) that there should be an educational plan for clients, and 50% of them agreed that incentives and disclosure, regarding the importance of reverse logistics for medicines, should be provided to consumers. [ABSTRACT FROM AUTHOR]