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Marine water quality significantly impacts human livelihoods and production such as fisheries, aquaculture, and tourism. Satellite remote sensing facilitates the predictions of large-area marine water quality without the need for frequent field work and sampling. Prediction of diffuse attenuation coefficient (Kd), which describes the speed at which light decays as it travels through water, obtained from satellite-derived ocean color products can reflect the overall water quality trends. However, current models inadequately explore the complex nonlinear features of Kd, and there are difficulties in achieving accurate long-term predictions and optimal computational efficiency. This study innovatively proposes a model called Remote Sensing-Informer-based Kd Prediction (RSIKP). The proposed RSIKP is characterized by a distinctive Multi-head ProbSparse self-attention mechanism and generative decoding structure. It is designed to comprehensively and accurately capture the long-term variation characteristics of Kd in complex water environments while avoiding error accumulation, which has a significant advantage in multi-dataset experiments due to its high efficiency in long-term prediction. A multi-dataset experiment is conducted at different prediction steps, using 70 datasets corresponding to 70 study areas in Hangzhou Bay and Beibu Gulf. The results show that RSIKP outperforms the five prediction models based on Artificial Neural Networks (ANN, Convolutional Neural Networks (CNN), Gated Recurrent Unit (GRU), Long Short-Term Memory Recurrent Neural Networks (LSTM-RNN), and Long Short-Term Memory Networks (LSTM)). RSIKP captures the complex influences on Kd more effectively to achieve higher prediction accuracy compared to other models. It shows a mean improvement of 20.6%, 31.1%, and 22.9% on Mean Absolute Error (MAE), Mean Square Error (MSE), and Mean Absolute Percentage Error (MAPE). Particularly notable is its outstanding performance in the long time-series predictions of 60 days. This study develops a cost-effective and accurate method of marine water quality prediction, providing an effective prediction tool for marine water quality management. [ABSTRACT FROM AUTHOR]

Diffuse attenuation coefficient of photosynthetically available radiation (PAR), KPAR, is a key product of ocean color remote sensing. Current ocean color algorithms generally detect only the average KPAR within one optical depth, K P A R R S . Due to the marked vertical variations of KPAR, knowledge of K P A R R S is insufficient to accurately evaluate the submarine light field. By using field in situ observations, a two-step approach, based on the development of an ocean color algorithm for K P A R R S and the relationships between K P A R R S and the average KPAR from the surface down to depth Z ( K ¯ P A R Z ), was developed to remotely estimate the vertical variations in K ¯ P A R Z in the North Pacific from the MODerate-resolution Imaging Spectrometer (MODIS) imagery. The root mean square difference of log( K ¯ P A R Z ) in depths within the euphotic zone was around ±0.059 (in unit of m−1 for K ¯ P A R Z ), which corresponded to a deviation of ±15% for the estimated K ¯ P A R Z and the penetration depths of PAR. Our study may provide a promising approach to detect the vertical variations of K ¯ P A R Z and underwater PAR distributions in the North Pacific Ocean. [ABSTRACT FROM AUTHOR]

The diffuse attenuation coefficient of photosynthetically active radiation is an important inherent optical property of the subaquatic light field. This parameter, as a measure of the transparency of the medium, is a good indicator of water quality. Degradation of the optical properties of water due to anthropogenic disturbances is a common phenomenon in freshwater ecosystems. In this study, we used four algorithm-based Landsat 8 OLI and Sentinel-2A/B MSI images to estimate the diffuse attenuation coefficient of photosynthetically active radiation in Lake Villarrica located in south-central Chile. The algorithms' estimated data from the ACOLITE module were validated with in situ measurements from six sampling stations. Seasonal and intralake variations of the light attenuation coefficient were studied. The relationship between the diffuse attenuation coefficient of photosynthetically active radiation, meteorological parameters, and an optical classification was also explored. The best results were obtained with QAA v6 KdPAR Nechad (R2 = 0.931, MBE = 0.023 m−1, RMSE = 0.088 m−1, and MAPE = 35.9%) for spring and QAA v5 Kd490 algorithms (R2 = 0.919, MBE = −0.064 m−1, RMSE = −0.09 m−1, and MAPE = 30.3%) for summer. High KdPAR values are associated with the strong wind and precipitation events suggest they are caused by sediment resuspension. Finally, an optical classification of freshwater ecosystems was proposed for this lake. The promising results of this study suggest that the combination of in situ data and observation satellites can be useful for assessing the bio-optical state of water and water quality dynamics in Chilean aquatic systems. [ABSTRACT FROM AUTHOR]

Estimates of the diffuse attenuation coefficient ( K d ) at two different wavelengths and band-integrated (PAR) were obtained using different published algorithms developed for open ocean waters spanning in type from explicit-empirical, semi-analytical and implicit-empirical and applied to data from spectral radiometers on board six different satellites (MODIS-Aqua, MODIS-Terra, VIIRS–SNPP, VIIRS-JPSS, OLCI-Sentinel 3A and OLCI-Sentinel 3B). The resultant K d s were compared to those inferred from measurements of radiometry from sensors on board autonomous profiling floats (BGC-Argo). Advantages of BGC-Argo measurements compared to ship-based ones include: 1. uniform sampling in time throughout the year, 2. large spatial coverage, and 3. lack of shading by platform. Over 5000 quality-controlled matchups between K d s derived from float and from satellite sensors were found with values ranging from 0.01 to 0.67 m − 1 . Our results show that although all three algorithm types provided similarly ranging values of K d to those of the floats, for most sensors, a given algorithm produced statistically different K d distributions from the two others. Algorithm results diverged the most for low K d (clearest waters). Algorithm biases were traced to the limitations of the datasets the algorithms were developed and trained with, as well as the neglect of sun angle in some algorithms. This study highlights: 1. the importance of using comprehensive field-based datasets (such as BGC-Argo) for algorithm development, 2. the limitation of using radiative-transfer model simulations only for algorithm development, and 3. the potential for improvement if sun angle is taken into account explicitly to improve empirical K d algorithms. Recent augmentation of profiling floats with hyper-spectral radiometers should be encouraged as they will provide additional constraints to develop algorithms for upcoming missions such as NASA's PACE and SBG and ESA's CHIME, all of which will include a hyper-spectral radiometer. [ABSTRACT FROM AUTHOR]

The Ocean and Land Color Imager (OLCI) on the Sentinel-3A satellite, which was launched by the European Space Agency in 2016, is a new-generation water color sensor with a spatial resolution of 300 m and 21 bands in the range of 400-1020 nm. The OLCI is important to the expansion of remote sensing monitoring of inland waters using water color satellite data. In this study, we developed a dual band ratio algorithm for the downwelling diffuse attenuation coefficient at 490 nm (Kd(490)) for the waters of Lake Taihu, a large shallow lake in China, based on data measured during seven surveys conducted between 2008 and 2017 in combination with Sentinel-3A-OLCI data. The results show that: (1) Compared to the available Kd(490) estimation algorithms, the dual band ratio (681 nm/560 nm and 754 nm/560 nm) algorithm developed in this study had a higher estimation accuracy (N = 26, coefficient of determination (R2) = 0.81, root-mean-square error (RMSE) = 0.99m-1 and mean absolute percentage error (MAPE) = 19.55%) and validation accuracy (N = 14, R2 = 0.83, RMSE = 1.06 m-1 and MAPE = 27.30%), making it more suitable for turbid inland waters; (2) A comparison of the OLCI Kd(490) product and a similar Moderate Resolution Imaging Spectroradiometer (MODIS) product reveals a high consistency between the OLCI and MODIS products in terms of the spatial distribution of Kd(490). However, the OLCI product has a smoother spatial distribution and finer textural characteristics than the MODIS product and contains notably higher-quality data; (3) The Kd(490) values for Lake Taihu exhibit notable spatial and temporal variations. Kd(490) is higher in seasons with relatively high wind speeds and in open waters that are prone to wind- and wave-induced sediment resuspension. Finally, the Sentinel-3A-OLCI has a higher spatial resolution and is equipped with a relatively wide dynamic range of spectral bands suitable for inland waters. The Sentinel-3B satellite will be launched soon and, together with the Sentinel-3A satellite, will form a two-satellite network with the ability to make observations twice every three days. This satellite network will have a wider range of application and play an important role in the monitoring of inland waters with complex optical properties. [ABSTRACT FROM AUTHOR]

A critical parameter to assess the environmental status of water bodies is the transparency of the water, as it is strongly affected by different water quality related components (such as the presence of phytoplankton, organic matter and sediment concentrations). One parameter to assess the water transparency is the diffuse attenuation coefficient. However, the number of subsurface irradiance measurements obtained with conventional instrumentation is relatively low, due to instrument costs and the logistic requirements to provide regular and autonomous observations. In recent years, the citizen science concept has increased the number of environmental observations, both in time and space. The recent technological advances in embedded systems and sensors also enable volunteers (citizens) to create their own devices (known as Do-It-Yourself or DIY technologies). In this paper, a DIY instrument to measure irradiance at different depths and automatically calculate the diffuse attenuation Kd coefficient is presented. The instrument, named KdUINO, is based on an encapsulated low-cost photonic sensor and Arduino (an open-hardware platform for the data acquisition). The whole instrument has been successfully operated and the data validated comparing the KdUINO measurements with the commercial instruments. Workshops have been organized with high school students to validate its feasibility. [ABSTRACT FROM AUTHOR]

The composition of phytoplankton and the concentration of pigments in their cells make their absorption and specific absorption coefficients key parameters for bio-optical modeling. This study investigated whether the multispectral vertical diffuse attenuation coefficient of downward irradiance (Kd) gradients could be a good framework for accessing phytoplankton genera. In situ measurements of remote sensing reflectance (Rrs), obtained in an Amazon Floodplain Lake (Lago Grande do Curuai), were used to invert Kd, focusing on Sentinel-3/Ocean and Land Color Instrument (OLCI) sensor bands. After that, an analysis based on the organization of three-way tables (STATICO) was applied to evaluate the relationships between phytoplankton genera and Kd at different OLCI bands. Our results indicate that phytoplankton genera are organized according to their ability to use light intensity and different spectral ranges of visible light (400 to 700 nm). As the light availability changes seasonally, the structure of phytoplankton changes as well. Some genera, such as Microcystis, are adapted to low light intensity at 550–650 nm, therefore high values of Kd in this range would indicate the dominance of Microcysts. Other genera, such as Aulacoseira, are highly adapted to harvesting blue-green light with higher intensity and probably grow in lakes with lower concentrations of colored dissolved organic matter that highly absorbs blue light (405–498). These findings are an important step to describing phytoplankton communities using orbital data in tropical freshwater floodplains. Furthermore, this approach can be used with biodiversity indexes to access phytoplankton diversity in these environments. [ABSTRACT FROM AUTHOR]

Measuring the diffuse attenuation coefficient ( K d ) allows for monitoring the water body's environmental status. This parameter is of particular interest in water quality monitoring programs because it quantifies the presence of light and the euphotic zone's depth. Citizen scientists can meaningfully contribute by monitoring water quality, complementing traditional methods by reducing monitoring costs and significantly improving data coverage, empowering and supporting decision-making. However, the quality of the acquisition of in situ underwater irradiance measurements has some limitations, especially in areas where stratification phenomena occur in the first meters of depth. This vertical layering introduces a gradient of properties in the vertical direction, affecting the associated K d . To detect and characterize these variations of K d in the water column, it needs a system of optical sensors, ideally placed in a range of a few cm, improving the low vertical accuracy. Despite that, the problem of self-shading on the instrumentation becomes critical. Here, we introduce a new concept that aims to improve the vertical accuracy of the irradiance measurements: the underwater annular irradiance ( E a ). This new concept consists of measuring the irradiance in an annular-shaped distribution. We first compute the optimal annular angle that avoids self-shading and maximizes the light captured by the sensors. Second, we use different scenarios of water types, solar zenith angle, and cloud coverage to assess the robustness of the corresponding diffuse attenuation coefficient, K a . Finally, we derive empirical functions for computing K d from K a . This new concept opens the possibility to a new generation of optical sensors in an annular-shaped distribution which is expected to (a) increase the vertical resolution of the irradiance measurements and (b) be easy to deploy and maintain and thus to be more suitable for citizen scientists. [ABSTRACT FROM AUTHOR]

The diffuse attenuation coefficient of downwelling irradiance ( K d ) is an essential parameter for inland waters research by remotely sensing the water transparency. Lately, K d semi-analytical algorithms substituted the empirical algorithms widely employed. The purpose of this research was to reparametrize a semi-analytical algorithm to estimate K d and then apply it to a Sentinel-2 MSI time-series (2017–2019) for the Três Marias reservoir, Brazil. The results for the K d semi-analytical reparametrization achieved good accuracies, reaching mean absolute percentage errors (MAPE) for bands B2, B3 and B4 (492, 560 and 665 nm), lower than 21% when derived from in-situ remote sensing reflectance ( R r s ), while for MSI Data, a derived MAPE of 12% and 38% for B2 and B3, respectively. After the application of the algorithm to Sentinel-2 images time-series, seasonal patterns were observed in the results, showing high K d values at 492 nm during the rainy periods, mainly in the tributary mouths, possibly due to an increase in the surface runoff and inflows and outflow rates in the reservoir watershed. [ABSTRACT FROM AUTHOR]

The vertical distribution of irradiance in the ocean is a key input to quantify processes spanning from radiative warming, photosynthesis to photo-oxidation. Here we use a novel dataset of thousands local-noon downwelling irradiance at 490 nm (Ed(490)) and photosynthetically available radiation (PAR) profiles captured by 103 BGC-Argo floats spanning three years (from October 2012 to January 2016) in the world's ocean, to evaluate several published algorithms and satellite products related to diffuse attenuation coefficient (Kd). Our results show: (1) MODIS-Aqua Kd(490) products derived from a blue-to-green algorithm and two semi-analytical algorithms show good consistency with the float-observed values, but the Chla-based one has overestimation in oligotrophic waters; (2) The Kd(PAR) model based on the Inherent Optical Properties (IOPs) performs well not only at sea-surface but also at depth, except for the oligotrophic waters where Kd(PAR) is underestimated below two penetration depth (2zpd), due to the model's assumption of a homogeneous distribution of IOPs in the water column which is not true in most oligotrophic waters with deep chlorophyll-a maxima; (3) In addition, published algorithms for the 1% euphotic-layer depth and the depth of 0.415 mol photons m−2 d−1 isolume are evaluated. Algorithms based on Chla generally work well while IOPs-based ones exhibit an overestimation issue in stratified and oligotrophic waters, due to the underestimation of Kd(PAR) at depth. [ABSTRACT FROM AUTHOR]

We evaluated six empirical and semianalytical models of the diffuse attenuation coefficient at 490 nm (Kd(490)) using an in situ dataset collected in the Pearl River estuary (PRE). A combined model with the most accurate performance (correlation coefficient, R2 = 0.92) was selected and applied for long-term estimation from 2003 to 2017. Physical and biological processes in the PRE over the 14-year period were investigated by applying satellite observations (MODIS/Aqua data) and season-reliant empirical orthogonal function analysis (S-EOF). In winter, the average Kd(490) was significantly higher than in the other three seasons. A slight increasing trend was observed in spring and summer, whereas a decreasing trend was observed in winter. In summer, a tongue with a relatively high Kd(490) was found in southeastern Lingdingyang Bay. In Eastern Guangdong province (GDP), the relatively higher Kd(490) value was found in autumn and winter. Based on the second mode of S-EOF, we found that the higher values in the eastern GDP extended westward and formed a distinguishable tongue in winter. The grey relational analysis revealed that chlorophyll-a concentration (Cchla) and total suspended sediment concentration (Ctsm) were two dominant contributors determining the magnitude of Kd(490) values. The Ctsm-dominated waters were generally located in coastal and estuarine turbid waters; the Cchla-dominated waters were observed in open clear ocean. The distribution of constituents-dominated area was different in the four seasons, which was affected by physical forces, including wind field, river runoff, and sea surface temperature. [ABSTRACT FROM AUTHOR]

Water transparency represented by the Secchi disk depth (Zsd) plays an important role in understanding water ecology environment variations, especially for optically complex and shallow lake waters. In this study, using in situ measured remote sensing reflectance (Rrs), diffuse attenuation coefficient (Kd), and Zsd data collected in Lake Taihu (China), a regional algorithm for estimating Kd from Rrs was designed, and the semi-analytical model proposed by Lee et al. (2015) (hereafter called Lee_2015 model) was refined using a linear scaling correction for remote sensing of Zsd. The results showed that a good agreement between the derived Kd and in situ measured data (mean absolute percentage error (MAPE) = 26% for Kd(490); MAPE < 5% for Kd at 443, 555, and 660 nm). The in situ Rrs-derived Zsd results using the refined Lee_2015 model compared well with the in situ measured Zsd (R2 = 0.72 and MAPE = 36%), which was an obvious improvement over the Lee_2015 model in our study region. Subsequently, the refined Lee_2015 model was applied to the geostationary ocean color imager (GOCI) observations between 2012 and 2018 to yield the spatial and temporal variations of water transparency in the Lake Taihu waters. The long-term mean distribution of Zsd revealed that water transparency values in the northeastern Lake Taihu were generally higher than those in the southwest part. Monthly climatological Zsd patterns suggested that the Zsd distributions had large temporal variability, and distinct monthly patterns of Zsd existed in different subregions of Lake Taihu. The significant interannual variations of Zsd in Lake Taihu are probably affected by a combination of the water column stability mainly caused by wind, water temperature, human activity, and riverine discharge. The present study can provide a new approach for quantifying water visibility and serve for water-color remote sensing of optically complex and highly turbid waters. [ABSTRACT FROM AUTHOR]