Search

Compared to air, rail, and road transport, shipping is a more energy-efficient and environmentally friendly way to transport goods over a long distance. However, the unprecedented growth of global seaborne trade has had a significant impact on the environment. The process of shipping transportation, through exhaust gas, wastewater discharge, fuel leakage, etc., has caused very serious environmental pollution. In response to this issue, the International Maritime Organization introduced the International Convention for the Prevention of Pollution from Ships (MARPOL) Convention to regulate the discharge of pollution from ships. Given that there are few studies discussing policy effectiveness, this study comprehensively considers and reviews the implementation effectiveness of all annexed policies under the MARPOL Convention. After discussing the differences between these policies based on the implementation conditions, requirements, strictness, and scope of adoption, the empirical analysis method of time-varying differences-in-differences model is adopted to analyze the policy effectiveness of each annex. It further puts forward suggestions and references for the formulation of effective maritime policies in the future that should be targeted, comprehensive, contingency-based, and proactive. This will help design or revise policies in the shipping industry, thereby promoting the early achievement of shipping emission reduction targets and contributing to the sustainability of the shipping industry. [ABSTRACT FROM AUTHOR]

Compared with isolated converters, transformerless converters are a preferred choice in low-voltage grids due to their efficiency and lower cost. However, leakage current and common mode (CM) voltage appear through the converter and ground in hybrid grids, which consist of AC and DC subgrids. The leakage current and CM voltage seriously influence operation and power quality in low-voltage distribution systems. This paper proposes a common-ground-type (CGT) converter equipped with a CM decoupling control strategy to eliminate the leakage current and CM voltage. A CM model is derived, and the leakage current and CM voltage are analyzed in detail. A CGT four-leg converter is constructed to eliminate the high frequency CM voltage. A dual DQ current control loop is developed to suppress the DC double-frequency ripple. Additionally, an active damping method is proposed, based on the neutral current feed-forward plus inductor current feedback, to attenuate the low frequency CM voltage. The proposed converter and control strategy guarantees excellent performance in suppressing leakage current and CM voltage. The DC voltage of the converter connected to the DC grid maintains stability and symmetry. The leakage current is significantly reduced, and the leakage current suppression performance is improved by 83%. The high frequency CM voltage is attenuated from 50%udc to 2%udc, and the low frequency CM voltage is suppressed from approximately 32%udc to 3%udc, which is a significant improvement compared with the traditional method. In addition, the proposed control strategy has good transient performance when the load changes abruptly. Finally, an experimental platform is established to validate the feasibility and performance. The experiment results showed that the proposed control strategy improves the system performance and power quality. [ABSTRACT FROM AUTHOR]

In the present study, the microstructure and mechanical properties of a new Mg-4Al-3.5Ca-2Gd (AXE432) alloy are investigated. The microstructure of the as-cast AXE432 alloy consists of α-Mg, C14 (Mg2Ca), and C36((Mg, Al)2Ca) phases. After the heat treatment at 480 °C for 8 h, the C14 with fine lamellar structure changes from narrow stripes to micro-scale particles, and part of the C36 and the C14 dissolve into the α-Mg matrix, with many short needle-shaped C15 (Al2Ca) phase precipitating in the primary a-Mg grains. The AXE432 alloy extruded at a temperature as high as 420 °C exhibits a refined dynamically recrystallized (DRXed) microstructure with grain sizes less than 1.5 ± 0.5 μm and a strong {0001}<10 1 ¯ 0> basal texture with a maximum intensity of 5.62. A complex combination of the effects from grain size, texture, second-phase particles, and strain hardening results in balanced mechanical properties, with the tensile yield strength (TYS), ultimate tensile strength (UTS), elongation (El), compressive yield strength (CYS), and ultimate compressive strength (UCS) of 331.4 ± 2.1 MPa, 336.9 ± 3.8 MPa, 16.1 ± 2.3%, 270.4 ± 1.6 MPa and 574.5 ± 12.4 MPa, respectively. [ABSTRACT FROM AUTHOR]

The effects of mold temperatures on the microstructures and mechanical properties of thixoforged Grp (graphite particles)/AZ91D composites have been investigated, followed by partial remelting and thixoforging technology. The results indicate that the best semi-solid microstructure could be obtained after being partially remelted at 600 °C and held for 60 min. Correspondingly, under a mold temperature of 300 °C, the best tensile properties were obtained by thixoforging. The UTS (ultimate tensile strength) and elongation of the thixoforged Grp/AZ91D were up to 304.1 MPa and 13.9%, respectively, which increased 11.3% and 43.1% in comparison with the thixoforged AZ91D, respectively. The variation of the tensile properties responded to the influences of mold temperatures on the amount of eutectic phase, the distribution of Grp, and the grain size of α-Mg. Meanwhile, HRTEM (High Resolution Transmission Electron Microscope) showed good bonding between Grp and AZ91D, and many edge dislocations were found in the inverse FFT (Fast Fourier Transform) image. And the result showed that the increase in tensile properties is attributed to the synergistic effect of load transfer, dislocation strengthening, and Orowan looping mechanisms from the Grp strengthening the matrix. [ABSTRACT FROM AUTHOR]

In contrast to practical hot compression processes, the testing of the hot workability of TiAl alloys is usually conducted under the conditions of constant strain rates and constant temperatures. This work aims at investigating the microstructural evolution of TiAl alloys on a Gleeble-3800 thermomechanical simulator under a variable strain rate (0.1, 0.01 and 0.001 s−1) at 1200 °C. The results show that, after a holding time of 30 s, the abrupt change in the strain rate at ε = 0.3 (engineering strain) has a remarkable influence on the flow stress and dynamic recrystallization (DRX) behavior of the β-γ Ti-44Al-6Nb-1Mo-0.3 (B, Y, La, Ce) (at.%) alloy. The flow stress demonstrates a rapid decrease with a sudden reduction in the strain rate. A duplex microstructure of γ + B2/β can be obtained under a high strain rate or continuous medium strain rate. During the two-step deformation, however, both γ→α phase transformation and DRX exist, and the content of the α phase demonstrates a significant increase when the strain rate becomes lower. Finally, a fine-grained structure of γ + B2/β + α2 phases with low residual stresses can be obtained via the two-step heat treatment processes. This provides a promising approach to significantly improve the hot workability of β-γ TiAl alloys. [ABSTRACT FROM AUTHOR]

The plate-like iron-rich intermetallic phases in recycled aluminum alloys significantly deteriorate the mechanical properties. In this paper, the effects of mechanical vibration on the microstructure and properties of the Al-7Si-3Fe alloy were systematically investigated. Simultaneously, the modification mechanism of the iron-rich phase was also discussed. The results indicated that the mechanical vibration was effective in refining the α-Al phase and modifying the iron-rich phase during solidification. The forcing convection and a high heat transfer inside the melt to the mold interface caused by mechanical vibration inhibited the quasi-peritectic reaction: L + α-Al8Fe2Si → (Al) + β-Al5FeSi and eutectic reaction: L → (Al) + β-Al5FeSi + Si. Thus, the plate-like β-Al5FeSi phases in traditional gravity-casting were replaced by the polygonal bulk-like α-Al8Fe2Si. As a result, the ultimate tensile strength and elongation were increased to 220 MPa and 2.6%, respectively. [ABSTRACT FROM AUTHOR]

In this work, a novel core-shell structure material, NiFe layered double hydroxide (NiFe LDH) loaded on SiO2 microspheres (SiO2@NiFe LDH), was synthesized by a one-step hydrothermal method, and the spontaneous electrostatic self-assembly process. The morphology, structure, and microwave absorption properties of SiO2@NiFe LDH nanocomposites with different NiFe element ratios were systematically investigated. The results show that the sample of SiO2@NiFe LDH-3 nanocomposite has excellent microwave absorption properties. It exhibits broadband effective absorption bandwidth (RL < −10 dB) of 8.24 GHz (from 9.76 GHz to 18.0 GHz) and the reflection loss is −53.78 dB at the matched thickness of 6.95 mm. It is expected that this SiO2@NiFe-LDH core-shell structural material can be used as a promising non-precious, metal-based material microwave absorber to eliminate electromagnetic wave contamination. [ABSTRACT FROM AUTHOR]

The effects of Grp (graphite particles) addition and holding time on the microstructure and mechanical properties of the Grp/AZ91D composite were investigated in this work. The results indicated that the distribution of Grp in the matrix was determined by the self-stabilizing mechanism and relationships between the solidifying interface and the particles. Due to the self-stabilizing mechanism, a small amount of Grp would uniformly distribute in the melt alloy, and as the amount of Grp increased, agglomeration would occur. Accordingly, the former would be engulfed by the solidifying interface and the latter would be pushed. With an increased holding time, Grp tended to agglomerate, due to the interfacial reaction that occurred, and as a result, the solidifying interface will push it. The Grp/AZ91D composite with the addition of 1.5 wt.% Grp and a holding time of 15 min obtained grains 30.2 μm in size with a hardness of 89.07 HV, which was a decrease of 83.04% and increase of 35.06% compared to AZ91D, respectively. [ABSTRACT FROM AUTHOR]

The dispersion of carbon nanotubes (CNTs) is the bottleneck in CNT-reinforced metal matrix composites. In this work, CNT/Mg composites were prepared by grinding Mg powder and then dispersing CNTs via ball milling and hot pressing. The uniform distribution of Ni-coated CNTs in the matrix was achieved by optimizing the content of CNTs. Scanning electron microscope, high-resolution transmission electron microscopy and X-ray diffraction, optical microscopy, and compression tests were employed. With the CNT content being less than 1%, the CNTs can be evenly distributed in CNT/Mg composites, resulting in a sharp increase in strength. However, with the higher CNT content, the CNTs gradually cluster, leading decreased fracture strain and strength. Furthermore, the coated Ni in the CNTs reacts with the magnesium matrix and completely transforms into Mg2Ni, significantly enhancing the interface bonding. This strong interface bonding and the diffusely distributed Mg2Ni in the matrix significantly strengthen the CNT/Mg composite. [ABSTRACT FROM AUTHOR]

In this paper, CNT/Mg composites with high compressive properties were prepared by using Ni-plated CNT and pure magnesium powder as raw materials through the grinding of magnesium powder, ball-milling mixing and hot-pressing sintering. The effect of grinding time for finer magnesium powder on the microstructure and properties of the final composites was studied mainly by SEM, XRD, HRTEM and compression tests. The results show that with the prolongation of milling time, the magnesium particle size decreases gradually and the CNT dispersion becomes more uniform. Moreover, the nickel layer on the surface of CNT reacts with highly active broken magnesium powder in the sintering process to generate MgNi2 intermediate alloy, which significantly improves interface bonding. The strength and fracture strain of composites are significantly increased by the combined action of the uniform distribution of CNTs and strong interface bonding from the MgNi2 phase. The compressive strength, yield strength and fracture strain of the composites, prepared with a 60 h grinding of magnesium powder, reached 268%, 272% and 279% of those in composites without the grinding of magnesium powder. [ABSTRACT FROM AUTHOR]

The rapid development of fusion-reactor technology calls for excellent anti-irradiation materials. Complex concentrated alloy (CCA) is a newly proposed alloy concept which is a promising candidate of nuclear fusion materials by virtue of its great phase stability under irradiation. This article summarizes anti-radiation mechanism and the microstructure evolution in HEAs. The effective factors on irradiation behavior of HEAs, including entropy, sample size and temperature, are discussed. Finally, the article introduces the potential ways to solve the economic and environmental problems which the HEAs faced for their applications in the future. In summary, the HEAs usually show better irradiation resistance than traditional alloys, such as less swelling, smaller size of defects, and more stable mechanical properties. One possible reason for the irradiation resistance of HEA is the self-healing effect induced by the high-entropy and atomic-level stress among the metal atoms. The activation of the principal element should be considered when selecting components of HEA, and the high throughput technique is a potential way to reduce the design and fabrication cost of HEAs. It is reasonable to expect that coming years will see the application of novel HEAs in fusion reactors. [ABSTRACT FROM AUTHOR]

A neoteric round sieve diatomite (De) decorated with sea-urchin-like alpha-type iron trioxide (α-Fe2O3) synthetics was prepared by the hydrothermal method and further calcination. The results of the electromagnetic (EM) parameters of α-Fe2O3-decorated De (α-Fe2O3@D) showed that the minimum reflection loss (RLmin) of α-Fe2O3@D could reach −54.2 dB at 11.52 GHz and the matched absorber thickness was 3 mm. The frequency bandwidth corresponding to the microwave RL value below −20 dB was up to 8.24 GHz (9.76–18 GHz). This indicates that α-Fe2O3@D composite can be a lightweight and stable material; because of the low density of De (1.9–2.3 g/cm3), the density of α-Fe2O3@D composite material is lower than that of α-Fe2O3 (5.18 g/cm3). We found that the combination of the magnetic loss of sea-urchin-like α-Fe2O3 and the dielectric loss of De has the most dominant role in electromagnetic wave absorption and loss. We focused on comparing the absorbing properties before and after the formation of sea-urchin-like α-Fe2O3 and explain in detail the effects of the structure and crystal shape of this novel composite on the absorbing properties. [ABSTRACT FROM AUTHOR]

There have been many studies on contaminant removal by fresh and aged nanoscale zero-valent iron (nZVI), but the effect of spatial distribution of nZVI on the corrosion behavior of the composite materials and its subsequent Cr(VI) removal remains unclear. In this study, four types of D201-nZVI composites with different nZVI distributions (named D1, D2, D3, and D4) were fabricated and pre-corroded in varying coexisting solutions. Their effectiveness in the removal of Cr(VI) were systematically investigated. The results showed acidic or alkaline conditions, and all coexisting ions studied except for H2PO4− and SiO32− enhanced the corrosion of nZVI. Additionally, the Cr(VI) removal efficiency was observed to decrease with increasing nZVI distribution uniformity. The corrosion products derived from nZVI, including magnetite, hematite, lepidocrcite, and goethite, were identified by XRD. The XPS results suggested that the Cr(VI) and Cr(III) species coexisted and the Cr(III) species gradually increased on the surface of the pre-corroded D201-nZVI with increasing iron distribution uniformity, proving Cr(VI) removal via a comprehensive process including adsorption/coprecipitation and reduction. The results will help to guide the selection for nZVI nanocomposites aged under different conditions for environmental decontamination. [ABSTRACT FROM AUTHOR]

Layered double hydroxides (LDHs) have been successfully applied in surface protection and functionalization of metal materials owing to their special structure, composition, controllability, anion exchange, and other excellent properties. Herein, this review focused on the most common LDH preparation methods on magnesium alloys in the past 10 years by summarizing about 70 research papers. At the same time, based on the corrosion protection mechanism of LDH materials, the performance of LDH films and LDH as filler on metal substrates was briefly introduced. The surface of LDH materials were chemically modified to enhance their compatibility with solvents, and their corrosion resistance function was developed as an additive. Finally, LDH-based composite coatings on Mg alloys by surface pretreatment and chemical modification were discussed. [ABSTRACT FROM AUTHOR]

It is of great significance to regulate the dielectric parameters and microstructure of carbon materials by elemental doping in pursuing microwave absorption (MA) materials of high performance. In this work, the surface electronic structure of N-doped CNTs was tuned by boron doping, in which the MA performance of CNTs was improved under the synergistic action of B and N atoms. The B,N-doped carbon nanotubes (B,N-CNTs) exhibited excellent MA performance, where the value of minimum reflection loss was −40.04 dB, and the efficient absorption bandwidth reached 4.9 GHz (10.5–15.4 GHz). Appropriate conductance loss and multi-polarization loss provide the main contribution to the MA of B,N-CNTs. This study provides a novel method for the design of CNTs related MA materials. [ABSTRACT FROM AUTHOR]

The surface-electrode ion trap is one of the most promising devices to realize large-scale and integrated quantum information processing. However, a series of problems are faced in the micro-nano fabrication of surface-electrode ion traps. A prominent one is the difficulty to control the thick film surface roughness. A rough electrode surface could produce excessive radio frequency (RF) loss and deteriorate trapping ability of the surface-electrode ion trap. In this paper, a thick film micro-nano fabrication technology to control the surface roughness is presented, which can reduce the roughness of thick film surface-electrode down to 6.2 nm , while being controllable between 6.2 nm and 45 nm . Therefore, it can also provide a basis for studying the influence of electrode surface roughness on trap performance. The micro-nano fabrication technology is not only suitable for surface-electrode ion traps with various configurations, but also be further applied to researches of MEMS, solar cells and surface science. [ABSTRACT FROM AUTHOR]

Recent studies indicated that contamination by adatoms on the surface ion trap can generate contact potential, leading to fluctuations in patch potential. By investigating contamination induced by surface adatoms during a loading process, a direct physical image of the contamination process and the relationship between the capacitance change and the contamination from surface adatoms is examined theoretically and experimentally. From the relationship, the contamination by surface adatoms and the effect of in situ treatment process can be monitored by the capacitance between electrodes in real time. This study is foundational to further research on anomalous heating with practical applications in quantum information processing from surface ion traps. [ABSTRACT FROM AUTHOR]

In this work, a novel core-shell structure material, NiFe layered double hydroxide (NiFe LDH) loaded on SiO2 microspheres (SiO2@NiFe LDH), was synthesized by a one-step hydrothermal method, and the spontaneous electrostatic self-assembly process. The morphology, structure, and microwave absorption properties of SiO2@NiFe LDH nanocomposites with different NiFe element ratios were systematically investigated. The results show that the sample of SiO2@NiFe LDH-3 nanocomposite has excellent microwave absorption properties. It exhibits broadband effective absorption bandwidth (RL < −10 dB) of 8.24 GHz (from 9.76 GHz to 18.0 GHz) and the reflection loss is −53.78 dB at the matched thickness of 6.95 mm. It is expected that this SiO2@NiFe-LDH core-shell structural material can be used as a promising non-precious, metal-based material microwave absorber to eliminate electromagnetic wave contamination.