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1. Palladium(II) Catalyzed Cyclization-Carbonylation-Cyclization Coupling Reaction of (ortho-Alkynyl Phenyl) (Methoxymethyl) Sulfides Using Molecular Oxygen as the Terminal Oxidant.

Author

Rong Shen, Taichi Kusakabe, Tomofumi Yatsu, Yuichiro Kanno, Keisuke Takahashi, Kiyomitsu Nemoto, and Keisuke Kato

Subjects
BENZOQUINONES, HYDROQUINONE, CATALYSTS, CARBONYLATION, SULFIDES
Abstract

An efficient PdII/Pd0-p-benzoquinone/hydroquinone-CuCl2/CuCl catalyst system was developed that uses environmentally friendly molecular oxygen as the terminal oxidant to catalyze the cyclization-carbonylation-cyclization coupling reaction (CCC-coupling reaction) of (o-alkynyl phenyl) (methoxymethyl) sulfides. [ABSTRACT FROM AUTHOR]

Published
2016
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