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Compared with traditional hot mix asphalt (HMA), wax based warm mix asphalt (WWMA) can be mixed with the aggregate at a lower temperature and achieve the desired compaction. However, the adhesion performance of WWMA on aggregate is uncertain. To evaluate the adhesion performance of asphalt and aggregate, researchers used contact angle test, pull-off test, and ultrasonic washing experiments. However, these tests cannot adequately explain the microscopic mechanism of the interface between asphalt and aggregate. Molecular dynamics (MD) can better explain the adhesion mechanism of asphalt aggregates because they can be simulated at the molecular scale. So, the purpose of this research is to use the MD method to study the adhesion performance between WWMA and aggregate. Two aggregate oxides (CaCO3 and SiO2) models, the matrix asphalt model and WWMA models, were built in Materials Studio (MS) software. The adhesion work of asphalt and aggregate oxides was calculated. With the increase of wax modifier content, the adhesion work of asphalt and aggregate oxides (CaCO3 and SiO2) first increases and then decreases. When the wax modifier is increased to 3 wt%, the adhesion works of the WWMA-SiO2 and WWMA-CaCO3 increase by 31.2% and 14.0%, compared with that of matrix asphalt. In this study, the accuracy of the MD calculation result was verified by the pull-off experiments and the contact angle experiments. WWMA was prepared by a high-shear mixer emulsifier. In the pull-off experiments and the contact angle experiments, the tensile strength and the adhesion work between the aggregate and the asphalt containing 3% wax modifier reaches peak values. These values are 140.7% and 124.9%, compared with those between the aggregate and the matrix asphalt. In addition, the results of the pull-off experiments and the contact angle experiments are in good agreement with that of the MD simulation. Finally, Fourier transform infrared spectroscopy (FTIR) shows that the carbonyl content of WWMA is greater than that of matrix asphalt. It explains well that the wax modifier promotes the adhesion between asphalt and aggregate. This paper provides an important theoretical basis to understand the adhesion performance of WWMA and aggregate. [ABSTRACT FROM AUTHOR]

In order to explore the moduli decay patterns of asphalt mixtures under different loading conditions, the nonlinear fatigue damage model was implemented in order to simulate the moduli decay patterns. Then, the direct tensile, indirect tensile, and uniaxial compression fatigue tests were employed under four kinds of stress levels with four parallel tests. The specimens of AC-13C Styrene-butadiene-styrene (SBS) modified mixtures were manufactured. Based on the test results, the decay patterns of the moduli during fatigue tests under different stress states were revealed, and the parameters of the damage model under different test conditions were obtained. By changing the values of the model parameters under a certain loading condition, fatigue curves were obtained. Then, the fatigue properties of asphalt mixtures under different stress states could be compared and analyzed directly. The result indicated that the evolution curves of fatigue damage for the direct tensile test, the indirect tensile test, and the uniaxial compression test all experienced three stages, which indicates that the fatigue damage characteristic of asphalt mixtures is non-linear. The decay patterns of the direct tensile moduli and the tensile moduli measured by the indirect tensile test are similar. The decay patterns of the uniaxial compression and the compression moduli measured by indirect tensile test are similar. The decay patterns of tensile and compressive moduli are obviously different. At the same cycle ratio state, the position of the decay curve for the compression moduli is higher than that of the tensile moduli. It indicates that the tensile failure is the main reason of the fatigue damage for asphalt mixture. The new analysis method of fatigue damage was proposed, which provides a possibility to compare the fatigue results that were obtained from different loading conditions and different specimen sizes. [ABSTRACT FROM AUTHOR]

Strength and fatigue life are essential parameters of pavement structure design. To accurately determine the pavement structure resistance of rubber asphalt mixture, the strength tests at various temperatures, loading rate, and fatigue tests at different stress levels were conducted in this research. Based on the proposed experiments, the change law of rubber asphalt mixture strength with different temperatures and loading rates was revealed. The phenomenological fatigue equation of rubber asphalt mixture was established. The genetic algorithm optimized backpropagation neural network (GA-BPNN) is highly reliable for optimizing production processes in civil engineering, and it has a remarkable application effect. A GA-BPNN strength and fatigue life prediction model was created in this study. The reliability of the prediction model was verified through experiments. The results showed that the rubber asphalt mixture strength decreases and increases with the increase of temperature and loading rate, respectively. The goodness of fit of the rubber asphalt mixture strength and fatigue life prediction model based on the GA-BPNN could reach 0.989 and 0.998, respectively. The indicators of the fatigue life prediction model are superior to the conventional phenomenological fatigue equation model. The GA-BPNN provides an effective method for predicting the rubber asphalt mixture strength and fatigue life, which significantly improves the accuracy of the resistance design of the rubber asphalt pavement structure. [ABSTRACT FROM AUTHOR]

Waste engine oil (WEO) and waste polyethylene (WPE) are two common wastes, which are easy to pollute the environment. As the primary material in road construction, natural asphalt is a non-renewable energy source and asphalt is vulnerable to ultraviolet (UV) radiation during the service life. It results in degradation of asphalt pavement performance. In this paper, 2 wt % to 8 wt % of WEO and WPE were used to modify asphalts and the UV aging simulation experiment was carried out. The physical parameters of asphalts before the UV aging experiment show that the asphalt containing 4 wt % WPE and 6 wt % WEO mixture (4 wt % WPE + 6 wt % WEO) has similar physical properties with that of the matrix asphalt. Besides, gel permeation chromatography (GPC) verifies that the molecular weight distribution of the asphalt containing 4 wt % WPE + 6 wt % WEO is close to that of the matrix asphalt. The storage stability test shows that 4 wt % WPE + 6 wt % WEO has good compatibility with the matrix asphalt. The functional groups and micro-morphology of asphalts before and after the UV aging experiment were investigated by Fourier transform infrared spectroscopy (FTIR) and atomic force microscopy (AFM). FTIR results display that 4 wt % WPE + 6 wt % WEO can effectively reduce the formation of carbonyl and sulfoxide functional groups. AFM shows that 4 wt % WPE + 6 wt % WEO can also retard the formation of a "bee-like" structure in asphalt after the UV aging experiment. Based on the above results, it can be concluded that WEO and WPE mixture can replace part of asphalt and improve the UV aging resistance of asphalt. [ABSTRACT FROM AUTHOR]

The objectives of this study are to evaluate the high-temperature performance of polymer-modified asphalt and asphalt mixtures, and to investigate if the standard technical indexes are useful in the performance evaluation of the polymer-modified asphalt. There are four typically used polymer-modified asphalt types employed in the study. The standard high-temperature rheological test, such as the temperature sweep test, was used to express the high-temperature performance of the polymer-modified asphalt. Also, considering the non-Newtonian fluid properties of the polymer-modified asphalt, the multiple stress creep recovery (MSCR) and zero-shear viscosity (ZSV) tests were employed for the characterizations. Besides, based on the mixture design of SMA-13, the high temperature of the polymer-modified asphalt mixture was evaluated via Marshall stability and rutting tests. The test results concluded that the ranking of the four kinds of polymer-modified asphalt was different in various laboratory tests. The TB-APAO has the best technical indexes in MSCR and ZSV tests, while the WTR-APAO performed best in the temperature sweep test. In addition, the correlation between the polymer-modified asphalt and the asphalt mixture was very poor. Thus, the present standard technical indexes for the profoundly polymer-modified asphalt mixtures are no longer suitable. [ABSTRACT FROM AUTHOR]

Although the rutting resistance, fatigue cracking, and the resistance to water and frost are important for the asphalt pavement, the strength of asphalt mixture is also an important factor for the asphalt mixture design. The strength of asphalt mixture is directly associated with the overall performance of asphalt mixture. As a top layer material of asphalt pavement, the strength of asphalt mixture plays an indispensable role in the top structural bearing layer. In the present design system, the strength of asphalt pavement is usually achieved via the laboratory tests. The stress states are usually different for the different laboratory approaches. Even at the same stress level, the laboratory strengths of asphalt mixture obtained are significantly different, which leads to misunderstanding of the asphalt mixtures used in asphalt pavement structure design. The arbitrariness of strength determinations affects the effectiveness of the asphalt pavement structure design in civil engineering. Therefore, in order to overcome the design deviation caused by the randomness of the laboratory strength of asphalt mixtures, in this study, the direct tension, indirect tension, and unconfined compression tests were implemented on the specimens under different loading rates. The strength model of asphalt mixture under different loading modes was established. The relationship between the strength ratio and loading rate of direct tension, indirect tension, and unconfined compression tests was adopted separately. Then, one unified strength model of asphalt mixture with different loading modes was established. The preliminary results show that the proposed unified strength model could be applied to improve the accurate degree of laboratory strength. The effectiveness of laboratory-based asphalt pavement structure design can therefore be promoted. [ABSTRACT FROM AUTHOR]