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A deep eutectic solvent (DES) with the ability to change from hydrophilic to hydrophobic was designed and synthesized and applied to the determination of organophosphorus (OPP) pesticides in honeysuckle dew samples. Choline chloride, phenol, and tetrahydrofuran (THF) were used as the hydrogen bond acceptor, hydrogen bond donor, and demulsifier, respectively. Eight OPP pesticides were extracted by DES coupled with ultrasonic-assisted extraction (UA) and then chromatographed by GC-MS. DES used as an extract solvent has the advantages of high extraction efficiency, low cost, and environmental protection. Furthermore, DES is compatible with GC-MS. The single factor experiment design and Box–Behnken design (BBD) were applied to the optimization of experimental factors, including the type and composition of extraction solvent, type of demulsifier solvent, the volume of DES and THF, pH of sample solution, and ultrasonic time. Under the optimum experimental conditions, the high degree of linearity from 0.1 to 20.0 ng mL−1 (R2 ≥ 0.9989), the limits of detection from 0.014 to 0.051 ng mL−1 (S/N = 3), and the recoveries of analytes from 81.4 to 104.4% with relative standard deviation below 8.6%. In addition, the adsorption mechanism of OPPs on DES was explored by adsorption kinetic studies. These results have demonstrated that the present method has offered an effective, accurate, and sensitive methodology for OPP pesticides in honeysuckle dew samples, and this method provides a reference for the detection of pesticide residues in traditional Chinese medicine. [ABSTRACT FROM AUTHOR]

The synthesis of primary amines via the reductive amination of alcohols involves a hydrogen-borrowing or hydrogen-transfer mechanism, which consists of three main steps: alcohol hydroxyl dehydrogenation, carbonyl imidization, and imine hydrogenation. Heterogeneous catalysts are widely used for this reaction because of their high performance and amenability to separation and reuse. However, the efficiency of reductive amination is limited by the dehydrogenation step, which is severely affected by the competitive adsorption of NH3. We hope to improve the efficiency of reductive amination by increasing dehydrogenation efficiency. Therefore, in this overview, we introduce the research progress of alcohol reductive amination reaction catalyzed by heterogeneous metal catalysts, focusing on methods of enhancing dehydrogenation efficiency by screening the metal component and the acidity/alkalinity of the support. Finally, we propose some new strategies for the preparation of catalysts from the perspective of overcoming the competitive adsorption of NH3 and speculate on the design and synthesis of novel catalysts with high performance in the future. [ABSTRACT FROM AUTHOR]

The hollow metal waveguides are attractive components for millimeter-wave circuits owing to low loss. To integrate with the front-end circuit, a transition from microstrip line to waveguide is required. In this article, a microstrip-to-waveguide transition is presented in the W-band by using an E-plane probe with a parasitic patch. The probe is embedded into the waveguide along the center of the broad wall to excite the TE10 mode. A backshort-circuited waveguide with a quarter wavelength is used to obtain sufficient energy coupling and achieve good impedance matching. The additional parasitic patch can introduce a new resonance at a low frequency to enhance the working bandwidth. Hence, the proposed transition achieves wide working bandwidth and low insertion loss. For verification, a back-to-back transition is constructed and measured. The measured results indicate that the proposed transition has a wide working bandwidth covering the entire W-band. The measured reflection coefficient is below −13 dB from 70 to 110 GHz and the average insert loss is 1.1 dB. Attributed to wide working bandwidth and simple structure, the proposed transition is attractive for W-band circuit systems. [ABSTRACT FROM AUTHOR]

After a large number of electric vehicles (EVs) are connected to the integrated energy system, disorderly charging and discharging of EVs will have a negative impact on the safe and stable operation of the system. In addition, EVs' uncertain travel plans and the stochastic fluctuation of renewable energy output and load power will bring risks and challenges. In view of the above problems, this paper establishes a hierarchical stochastic optimal scheduling model of an electric thermal hydrogen integrated energy system (ETH-IES) considering the EVs vehicle-to-grid (V2G) mechanism. The EVs charging and discharging management layer aims to minimize the variance of the load curve and minimize the dissatisfaction of EV owners participating in V2G. The multi-objective sand cat swarm optimization (MSCSO) algorithm is used to solve the proposed model. On this basis, the daily stochastic economic scheduling of ETH-IES is carried out with the goal of minimizing the operation cost. The simulation results show that the proposed strategy can better achieve a win-win situation between EV owners and microgrid operators, and the operation cost of the proposed strategy is reduced by 16.55% compared with that under the disorderly charging and discharging strategy, which verifies the effectiveness of the proposed model and algorithm. [ABSTRACT FROM AUTHOR]