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The development of biomass-based CQD is highly attentive to enhancing photocatalytic performance, especially in secondary or ternary heterogeneous photocatalysts by allowing for smooth electron-hole separation and migration. In this study, kenaf-based carbon quantum dots (CQD) were prepared. The main objective of the current work was to investigate temperature, precursor mass and time in hydrothermal synthesis treatment to improve the CQD properties and methylene blue photocatalytic degradation. Optimization of kenaf-based CQD for inclusion in hydrothermal treatment was analyzed. The as-prepared CQDs have been characterized in detail by Fourier transform infrared (FTIR) spectroscopy, high-resolution transmission electron microscope (HRTEM), photoluminescence (PL) and ultraviolet–visible (UV–Vis) spectroscopy. It was found that C200-0.5-24 exhibits a higher photocatalytic activity of the methylene blue dye and optimized hydrothermal conditions of 200 °C, 0.5 g and 24 h. Therefore, novel kenaf-based CQD was synthesized for the first time and was successfully optimized in the as-mentioned conditions. During the hydrothermal treatment, precursor mass controls the size and the distribution of CQD nanoparticles formed. The C200-0.5-24 showed a clearly defined and well-distributed CQD with an optimized nanoparticle size of 8.1 ± 2.2 nm. Indeed, the C200-0.5-24 shows the removal rate of 90% of MB being removed within 120 min. [ABSTRACT FROM AUTHOR]

In the present study, the conversion performance of hydrogen sulfide (H2S) to elemental sulfur in ionic-liquid-incorporated transition metals (ILTMs) is predicted using a conductor-like screening model for realistic solvents (COSMO-RS). The predictions were made via the establishment of a correlation between the conversion performance and solubility of H2S in ionic liquids (ILs). All molecules involved were optimized at the DFT/TZVP/M06 computational level and imported on the COSMOtherm program at equimolar conditions. For validation purposes, the solubility of ILs was predicted at 1 bar pressure. Simple regression analysis was used to establish a relationship between the solubility and conversion performance of H2S. The results indicate that the solubility prediction of ILs is accurate (R2 = 93.40%) with a p-value of 0.0000000777. Additionally, the conversion performance is generally found to be dependent on the solubility value. Furthermore, 1-butyl-3-methylimidazolium chloride [bmim][Cl] was chosen as the base IL for incorporating the transition metal, owing to its solubility and selectivity to H2S. The solubility trend of ILTMs is found to follow the following order: [bmim][NiCl3] > [bmim][FeCl4] > [bmim][CoCl3] > [bmim][CuCl3]. According to the viscosity measurements of ILTMs, [bmim][NiCl3] and [bmim][FeCl4] exhibited the highest and lowest viscosity values, respectively. Therefore, [bmim][FeCl4] is a promising ILTM owing to its higher solubility and low viscosity for the application studied. [ABSTRACT FROM AUTHOR]

This document is a correction notice for an article titled "Effect of Hydrothermal Conditions on Kenaf-Based Carbon Quantum Dots Properties and Photocatalytic Degradation." The correction addresses a technical writing mistake regarding the TEM equipment used in the research paper. The corrections have been made to the abstract, materials and methods section, and results and discussion section. The authors apologize for any inconvenience caused and state that the scientific conclusions are unaffected. [Extracted from the article]

This study focuses on the effect of modified silica fillers by [EMIN][Tf2N] via physical adsorption on the CO2 separation performance of a mixed matrix membrane (MMM). The IL-modified silica was successfully synthesized as the presence of fluorine element was observed in both Fourier transform infrared spectroscopy (FTIR) and X-ray photoelectron spectrometer (XPS) analyses. The prepared MMMs with different loadings of the IL-modified silica were then compared with an unmodified silica counterpart and neat membrane. The morphology of IL-modified MMMs was observed to have insignificant changes, while polymer chains of were found to be slightly more flexible compared to their counterpart. At 2 bar of operating pressure, a significant increase in performance was observed with the incorporation of 3 wt% Sil-IL fillers compared to that of pure polycarbonate (PC). The permeability increased from 353 to 1151 Barrer while the CO2/CH4 selectivity increased from 20 to 76. The aforementioned increment also exceeded the Robeson upper bound. This indicates that the incorporation of fillers surface-modified with ionic liquid in an organic membrane is worth exploring for CO2 separation. [ABSTRACT FROM AUTHOR]

The textile industry provides for the needs of people especially in apparel and household items. The industry also discharges dye-containing wastewater that is typically challenging to treat. Despite the application of the biological and chemical treatments for the treatment of textile wastewater, these methods have their own drawbacks such as non-environment friendly, high cost and energy intensive. This research investigates the efficiency of the celestine blue dye removal from simulated textile wastewater by electrocoagulation (EC) method using iron (Fe) electrodes through an electrolytic cell, integrated with nylon 6,6 nanofiber (NF) membrane filtration for the separation of the flocculants from aqueous water. Based on the results, the integrated system achieves a high dye removal efficiency of 79.4%, by using 1000 ppm of sodium chloride as the electrolyte and 2 V of voltage at a constant pH of 7 and 10 ppm celestine blue dye solution, compared to the standalone EC method in which only 43.2% removal was achieved. Atomic absorption spectroscopy analysis was used to identify the traces of iron in the residual EC solution confirming the absence of iron. The EC-integrated membrane system thus shows superior performance compared to the conventional method whereby an additional 10–30% of dye was removed at 1 V and 2 V using similar energy consumptions. [ABSTRACT FROM AUTHOR]

This paper reports the fabrication of polyethersulfone membranes via in situ hydrogen peroxide-assisted polymerization of dopamine. The dopamine and hydrogen peroxide were introduced into the dope solution where the polymerization occurred, resulting in a single-step additive formation during membrane fabrication. The effectivity of modification was evaluated through characterizations of the resulting membranes in terms of chemical functional groups, surface morphology, porosity, contact angle, mechanical strength and filtration of humic acid solution. The results confirm that the polydopamine was formed during the dope solution mixing through peroxide-assisted polymerization as proven by the appearance of peaks associated OH and NH groups in the resulting membranes. The presence of polydopamine residual in the membrane matric enhances the pore properties in terms of size and porosity (by a factor of 10), and by lowering the hydrophilicity (from 69° to 53°) which leads to enhanced filtration flux of up to 217 L/m2 h. The presence of the residual polydopamine also enhances membrane surface hydrophilicity which improve the antifouling properties as shown from the flux recovery ratio of > 80%. [ABSTRACT FROM AUTHOR]

Empty fruit bunch (EFB) utilization to produce valuable bio-chemicals is seen as an economical and sustainable alternative to waste management in palm oil industries. This work proposed an integrated biorefinery configuration of EFB valorization considering sustainability pillars—namely, economic, environmental, and safety criteria. Techno-economic analysis, life cycle assessment, and hazard identification ranking methods were used to estimate annual profit, global warming potential (GWP), fire explosion damage index (FEDI), and toxicity damage index (TDI) of the proposed integrated biorefinery. A multi-objective optimization problem was then formulated and solved for simultaneous maximization of profit and minimization of GWP, FEDI and TDI. The resulting Pareto-optimal solutions convey the trade-off among the economic, environmental, and safety performances. To choose one of these optimal solutions for implementation, a combined approach of fuzzy analytical hierarchy process and a technique for order preference by similarity to ideal solution was applied. For this selection, the economic criterion was more preferred, followed by the safety and environmental criterion; thus, the optimal solution selected for integrated biorefinery configuration had the highest annual profit, which was at the maximum capacity of 100 ton/h of EFB. It can fulfill the global demand of xylitol (by 55%), levulinic acid (by 98%), succinic acid (by 25%), guaiacol (by 90%), and vanillin (by 12%), and has annual profit, GWP, FEDI, and TDI of 932 M USD/year, 284 tonCO2-eq, 595, and 957, respectively. [ABSTRACT FROM AUTHOR]

A petroleum refinery heavily depends on crude oil as its main feedstock to produce liquid fuels and chemicals. In the long term, this unyielding dependency is threatened by the depletion of the crude oil reserve. However, in the short term, its price highly fluctuates due to various factors, such as regional and global security instability causing additional complexity on refinery production planning. The petroleum refining industries are also drawing criticism and pressure due to their direct and indirect impacts on the environment. The exhaust gas emission of automobiles apart from the industrial and power plant emission has been viewed as the cause of global warming. In this sense, there is a need for a feasible, sustainable, and environmentally friendly generation process of fuels and chemicals. The attention turns to the utilization of biomass as a potential feedstock to produce substitutes for petroleum-derived fuels and building blocks for biochemicals. Biomass is abundant and currently is still low in utilization. The biorefinery, a facility to convert biomass into biofuels and biochemicals, is still lacking in competitiveness to a petroleum refinery. An attractive solution that addresses both is by the integration of bio- and petroleum refineries. In this context, the right decision making in the process selection and technologies can lower the investment and operational costs and assure optimum yield. Process optimization based on mathematical programming has been extensively used to conduct techno-economic and sustainability analysis for bio-, petroleum, and the integration of both refineries. This paper provides insights into the context of crude oil and biomass as potential refinery feedstocks. The current optimization status of either bio- or petroleum refineries and their integration is reviewed with the focus on the methods to solve the multi-objective optimization problems. Internal and external uncertain parameters are important aspects in process optimization. The nature of these uncertain parameters and their representation methods in process optimization are also discussed. [ABSTRACT FROM AUTHOR]

The removal of H2S and CH4 from natural gas is crucial as H2S causes environmental contamination, corrodes the gas stream pipelines, and decreases the feedstock for industrial productions. Many scientific researches have shown that the metal-organic framework (MOF)/ionic liquids (ILs) have great potential as alternative adsorbents to capture H2S. In this work, molecular dynamics (MD) simulation was carried out to determine the stability of ILs/IRMOF-1 as well as to study the solubility of H2S and CH4 gases in this ILs/IRMOF-1 hybrid material. Three choline-based ILs were incorporated into IRMOF-1 with different ratios of 0.4, 0.8, and 1.2% w/w, respectively, in which the most stable choline-based ILs/IRMOF-1 composite was analysed for H2S/CH4 solubility selectivity. Among the three choline-based ILs/IRMOF-1, [Chl] [SCN]/IRMOF-1 shows the most stable incorporation. However, the increment of ILs loaded in the IRMOF-1 significantly reduced the stability of the hybrid due to the crowding effect. Solvation free energy was then computed to determine the solubility of H2S and CH4 in the [Chl] [SCN]/IRMOF-1. H2S showed higher solubility compared to CH4, where its solubility declined with the increase of choline-based IL loading. [ABSTRACT FROM AUTHOR]

The competitiveness of algae as biofuel feedstock leads to the growth of membrane filtration as one of promising technologies for algae harvesting. Nanofiber membrane (NFM) was found to be efficient for microalgae harvesting via membrane filtration, but it is highly limited by its weak mechanical strength. The main objective of this study is to enhance the applicability of nylon 6,6 NFM for microalgae filtration by optimizing the operational parameters and applying solvent vapor treatment to improve its mechanical strength. The relaxation period and filtration cycle could be optimized to improve the hydraulic performance. For a cycle of 5 min., relaxation period of ≤2 min shows the highest steady-state permeability of 365 ± 14.14 L m−2 h−1 bar−1, while for 10 min cycle, 3 min. of relaxation period was found optimum that yields permeability of 402 ± 34.47 L m−2 h−1 bar−1. The treated nylon 6,6 NFM was also used to study the effect of aeration rate. It is confirmed that the aeration rate enhances the steady-state performance for both intermittent and continuous mode of aeration. Remarkably, intermittent aeration shows 7% better permeability than the full aeration for all tested condition, which is beneficial for reducing the total energy consumption. [ABSTRACT FROM AUTHOR]

In this study, a series of TiO2 nanotubes (NTs) were synthesized employing electrochemical anodization of titanium foil in an ionic liquid solution containing a mixture of glycerol and choline chloride, acting as electrolyte. The as-synthesized TiO2 NTs were calcined at 350, 450, or 550 °C for a 2 h duration to investigate the influence of calcination temperature on NTs formation, morphology, surface properties, crystallinity, and subsequent photocatalytic activity for visible light photodegradation of gaseous formaldehyde (HCHO). Results showed that the calcination temperature has a significant effect on the structure and coverage of TiO2 NTs on the surface. Freshly synthesized TiO2 NTs showed better-ordered structure compared to calcined samples. There was significant pore rupture with increasing calcination temperature. The transformation from anatase to rutile phase appeared after calcination at 450 °C and the weight fraction of the rutile phase increased from 19% to 36% upon increasing the calcination temperature to 550 °C. The band gaps of the TiO2 NTs were in the range from 2.80 to 2.74 eV, shifting the active region of the materials to visible light. The presence of mixed anatase–rutile TiO2 phases in the sample calcined at 450 °C showed enhanced photoactivity, which was confirmed by the 21.56 mg∙L−1∙g−1 removal of gaseous formaldehyde under 120 min of visible light irradiation and displayed enhanced quantum yield, ∅HCHO of 17%. [ABSTRACT FROM AUTHOR]

This study develops electrospun nylon 6,6 nanofiber membrane (NFM), incorporating zeolitic imidazolate framework-8 (ZIF-8) as the additive for produced water (PW) filtration. Electrospun NFM is suitable to be used as a filter, especially for water treatment, since it has a huge surface area to volume ratio, high porosity, and great permeability compared to the conventional membranes. These properties also enhance its competitiveness to be used as reverse osmosis pre-treatment, as the final stage of PW treatment water reuse purpose. However, the fouling issue and low mechanical strength of NFM reduces hydraulic performance over time. Therefore, this study employs ZIF-8 as an additive to improve nylon 6,6 NFM properties to reduce fouling and increase membrane tensile strength. Results show that the optimum loading of ZIF-8 was at 0.2%. This loading gives the highest oil rejection (89%), highest steady-state pure water permeability (1967 L/(m2·h·bar)), 2× higher than untreated nylon 6,6 NFM with tensile strength 5× greater (3743 MPa), and a steady-state permeability of 1667 L/(m2·h·bar) for filtration of real produced water. [ABSTRACT FROM AUTHOR]

Electrospun nanofiber membrane (NFM) has a high potential to be applied as a filter for produced water treatment due to its highly porous structure and great permeability. However, it faces fouling issues and has low mechanical properties, which reduces the performance and lifespan of the membrane. NFM has a low integrity and the fine mat easily detaches from the sheet. In this study, nylon 6,6 was selected as the polymer since it offers great hydrophilicity. In order to increase mechanical strength and separation performance of NFM, solvent vapor treatment was implemented where the vapor induces the fusion of fibers. The fabricated nylon 6,6 NFMs were treated with different exposure times of formic acid vapor. Results show that solvent vapor treatment helps to induce the fusion of overlapping fibers. The optimum exposure time for solvent vapor is 5 h to offer full retention of dispersed oil (100% of oil rejection), has 62% higher in tensile strength (1950 MPa) compared to untreated nylon 6,6 NFM (738 MPa), and has the final permeability closest to the untreated nylon 6,6 NFM (733 L/m 2 .h.bar). It also took more time to get fouled (220 min) compared to untreated NFM (160 min).