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After discussing the characteristics of ammonia and comparing hydrogen storage methods, they investigated ammonia production technologies, including the Haber-Bosch process, electrochemical processing, and thermochemical cycle. It is crucial that green hydrogen production, which involves electrolyzing water using electricity from renewable energy sources (called power-to-gas systems), surpasses conventional hydrogen production. The prepared Ni/MgAl SB 2 sb O SB 4 sb catalyst could achieve a methane conversion of up to 80% with >75% hydrogen selectivity, which is better than that observed in the plasma only methane cracking method (hydrogen selectivity of 62%). Steel alloys, which are common storage materials, are unsuitable for storing liquid hydrogen; thus, systematic research on storage materials suitable for cryogenic hydrogen storage is needed. [Extracted from the article]

Turning carbon dioxide (CO2) into fuels and chemicals using chemical, photochemical, electrochemical, and enzymatic methods could be used to recycle large quantities of carbon. The enzymatic method, which is inspired by cellular CO2 metabolism, has attracted considerable attention for efficient CO2 conversion due to improved selectivity and yields under mild reaction conditions. In this review, the research progress of green and potent enzymatic conversion of CO2 into useful fuels and chemicals was discussed. Furthermore, applications of the enzymatic conversion of CO2 to assist in CO2 capture and sequestration were highlighted. A summary including the industrial applications, barriers, and some perspectives on the research and development of the enzymatic approach to convert CO2 were introduced. [ABSTRACT FROM AUTHOR]

Cellulosic ethanol (CE) can not only be produced from a nonedible, cheap, and abundant lignocellulose feedstock but also can reduce carbon footprint significantly compared to starch ethanol. Despite great stimulation worldwide, CE production has not yet commercialized because of the complexity of lignocellulose. Therefore, intensive research and development are needed to improve CE technologies. In this study, a cost-efficient and sustainable design was proposed for the coproduction of CE, heat, and electricity from the actual lignocellulosic fermentation broth. First, a conventional coproduction process of CE, heat, and electricity based on hybrid distillation and adsorption (HDA) was simulated and optimized. Subsequently, various heat integrated (HI) techniques such as heat pump (HP), multi-effect distillation (MED), and combined HP-MED were evaluated to improve the CE process. The combined heat and power (CHP) process that utilized the combustible solids of the beer stillage was designed and integrated with the CE process. Structural alternatives were assessed for both economic and environmental impacts. The results show that the proposed HI-HDA process can save 36.9% and 33.6% of total annual costs and carbon footprint, respectively, compared to the conventional CE process. In the proposed HI-HDA coproduction process, the CE recovery process can be self-efficient in energy and the CHP can generate 12.0% more electricity than that in the conventional coproduction process. [ABSTRACT FROM AUTHOR]