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Pump-turbines experience complex flow phenomena and fluid–structure interactions during transient operations, which can significantly impact their stability and performance. This paper presents a comprehensive field test study of the pump mode startup process for a 150 MW prototype pump-turbine. By analyzing pressure fluctuations, structural vibrations, and their short-time Fourier transform (STFT) results, multiple stages were identified, each exhibiting distinct characteristics. These characteristics were influenced by factors such as runner rotation, free surface sloshing in the draft tube, and rotor–stator interactions. The natural frequencies of the metallic components varied during the speed-up and water-filling stages, potentially due to gyroscopic effects or stress-stiffening phenomena. The opening of the guide vanes and dewatering valve inside the guide vanes significantly altered the amplitude of the rotor–stator interaction frequency, transitioning the vibration behavior from forced to self-excited regimes. Interestingly, the draft tube pressure fluctuations exhibited sloshing frequencies that deviated from existing prediction methods. The substantial phenomena observed in this study can help researchers in the field to deepen the understanding of the complex behavior of pump-turbines during transient operations and identify more meaningful research directions. [ABSTRACT FROM AUTHOR]

During the flood season, Francis turbines often operate under low-head and full-load conditions, frequently experiencing significant pressure pulsations, posing potential threats to the safe and stable operation of the units. However, the factors contributing to substantial pressure pulsations in Francis turbines are multifaceted. This paper focuses on a mixed-flow hydroelectric generating unit at a specific hydropower station. Field tests were conducted to investigate abnormal vibrations and hydraulic pressure pulsations under low-head and full-load conditions. Utilizing the Navier–Stokes equations and the RNG k-ε turbulence model, the unsteady flow field within the turbine under these conditions was calculated. The results indicate that the abnormal pressure pulsations detected in the bladeless zone between the wicket gates and the turbine inlet are due to operational points deviating from the normal operating range of the turbine. When water flows at a large inflow angle, striking the turbine blade heads, it leads to significant flow separation and vortex formation at the back of the blade inlet edges, causing severe vibrations in the hydroelectric generating unit. These findings provide a basis and assurance for the safe and stable operation of the power station. [ABSTRACT FROM AUTHOR]

Pulmonary drug transport has numerous benefits. Large surface areas for absorption and limited drug degradation of the gastrointestinal system are provided through the respiratory tract. The administration is painless and easy for the patient. Due to their better stability when compared to liquid formulations, powders have gained popularity among pulmonary formulations. In the pharmaceutical sector, quality assurance and product stability have drawn a lot of attention. Due to this, it was decided to perform a long-term stability study on a previously developed, nanosized dry powder inhaler (DPI) formulation that contained meloxicam. Wet milling was implemented to reduce the particle size, and nano spray-drying was used to produce the extra-fine inhalable particles. The particle diameter was determined using dynamic light scattering and laser diffraction. Scanning electron microscopy was utilized to describe the morphology. X-ray powder diffraction and differential scanning calorimetry were applied to determine the crystallinity. In an artificial lung medium, the in vitro dissolution was studied. The Andersen Cascade Impactor was used to investigate the in vitro aerodynamic characteristics. The stability test results demonstrated that the DPI formulation maintained its essential qualities after 6 and 12 months of storage. Consequently, the product might be promising for further studies and development. [ABSTRACT FROM AUTHOR]

This paper analytically derives a stability test for the probability distribution of a random variable that follows the Edgeworth–Sargan density, also called Gram–Charlier. The distribution of the test is a weighted sum of Chi-squared densities of increasing degrees of freedom, starting with the standard equivalent Chi-squared under the same conditions. The weights turn out to be linear combinations of the parameters of the distribution and the moments of a Gaussian density, and can be computed exactly. This is a convenient result, since then the probability intervals can be easily calculated from existing Chi-squared distribution tables. The test is applied to assess the weekly solar irradiance data stability for a twelve-year period. It shows that the density is acceptably stable overall, except for some eventual and localised dates. It is also shown that the usual probability intervals implemented in stability testing are larger than those of the equivalent Chi-squared distribution under comparable conditions. This implies that the common upper tail interval values for rejecting the null stability hypothesis are larger. [ABSTRACT FROM AUTHOR]

In this study, the performance and stability of inverted bulk heterojunction (BHJ) polymer solar cells (PSCs) is enhanced by doping zinc oxide (ZnO) with 0-6 wt % cetyltrimethylammonium bromide (CTAB) in the sol-gel ZnO precursor solution. The power conversion efficiency (PCE) of the optimized 3 wt % CTAB-doped ZnO PSCs was increased by 9.07%, compared to a PCE of 7.31% for the pristine ZnO device. The 0-6 wt % CTAB-doped ZnO surface roughness was reduced from 2.6 to 1 nm and the number of surface defects decreased. The X-ray photoelectron spectroscopy binding energies of Zn 2p3/2 (1021.92 eV) and 2p1/2 (1044.99 eV) shifted to 1022.83 and 1045.88 eV, respectively, which is related to strong chemical bonding via bromide ions (Br-) that occupy oxygen vacancies in the ZnO lattice, improving the PCE of PSCs. The concentration of CTAB in ZnO significantly affected the work function of PSC devices; however, excessive CTAB increased the work function of the ZnO layer, resulting from the aggregation of CTAB molecules. In addition, after a 120-hour stability test in the atmosphere with 40% relative humidity, the inverted device based on CTAB-doped ZnO retained 92% of its original PCE and that based on pristine ZnO retained 68% of its original PCE. The obtained results demonstrate that the addition of CTAB into ZnO can dramatically influence the optical, electrical, and morphological properties of ZnO, enhancing the performance and stability of BHJ PSCs. [ABSTRACT FROM AUTHOR]

This article proposes a new type of single-layer combined lattice shell (NSCLS); which is based on aluminum alloy honeycomb panels. Six models with initial geometric defect were designed and precision made using numerical control equipment. The stability of these models was tested. The results showed that the stable bearing capacity of NSCLS was approximately 16% higher than that of a lattice shell with the same span without a reinforcing plate. At the same time; the properties of the NSCLS were sensitive to defects. When defects were present; its stable bearing capacity was decreased by 12.3% when compared with the defect-free model. The model with random defects following a truncated Gaussian distribution could be used to simulate the distribution of defects in the NSCLS. The average difference between the results of the nonlinear analysis and the experimental results was 5.7%. By calculating and analyzing nearly 20,000 NSCLS; the suggested values of initial geometric defect were presented. The results of this paper could provide a theoretical basis for making and revising the design codes for this new combined lattice shell structure. [ABSTRACT FROM AUTHOR]

The development of active and stable photocatalysts for the degradation of volatile organic compounds under visible light is important for efficient light utilization and environmental protection. Titanium dioxide doped with nitrogen is known to have a high activity but it exhibits a relatively low stability due to a gradual degradation of nitrogen species under highly powerful radiation. In this paper, we show that the combination of N-doped TiO2 with bismuth tungstate prevents its degradation during the photocatalytic process and results in a very stable composite photocatalyst. The synthesis of Bi2WO6–TiO2-N composites is preformed through the hydrothermal treatment of an aqueous medium containing nanocrystalline N-doped TiO2, as well as bismuth (III) nitrate and sodium tungstate followed by drying in air. The effect of the molar ratio between the components on their characteristics and photocatalytic activity is discussed. In addition to an enhanced stability, the composite photocatalysts with a low content of Bi2WO6 also exhibit an enhanced activity that is substantially higher than the activity of individual TiO2-N and Bi2WO6 materials. Thus, the Bi2WO6–TiO2-N composite has the potential as an active and stable photocatalyst for efficient purification of air. [ABSTRACT FROM AUTHOR]

The unstoppable growth of human population that occurs in parallel with all manufacturing activities leads to a relentless increase in the demand for resources, cultivation land, and energy. In response, currently, there is significant interest in developing strategies to optimize any available resources and their biowaste. While solutions initially focused on recovering biomolecules with applications in food, energy, or materials, the feasibility of synthetic biology in this field has been demonstrated in recent years. For instance, it is possible to genetically modify Saccharomyces cerevisiae to produce terpenes for commercial applications (i.e., against malaria or as biodiesel). But the production process, similar to any industrial activity, generates biowastes containing promising biomolecules (from fermentation) that if recovered may have applications in different areas. To test this hypothesis, in the present study, the lipid composition of by-products from the industrial production of β-farnesene by genetically modified Saccharomyces cerevisiae are studied to identify potentially bioactive compounds, their recovery, and finally, their stability and in vitro bioactivity. The assayed biowaste showed the presence of triterpenes, phytosterols, and 1-octacosanol which were recovered through molecular distillation into a single fraction. During the assayed stability test, compositional modifications were observed, mainly for the phytosterols and 1-octacosanol, probably due to oxidative reactions. However, such changes did not affect the in vitro bioactivity in macrophages, where it was found that the obtained fraction decreased the production of TNF-α and IL-6 in lipopolysaccharide (LPS)-induced inflammation. [ABSTRACT FROM AUTHOR]

In the case of capsule-based dry powder inhalation systems (DPIs), the selection of the appropriate capsule is important. The use of gelatin, gelatin-PEG, and HPMC capsules has become widespread in marketed capsule-based DPIs. We aimed to perform a stability test according to the ICH guideline in the above-mentioned three capsule types. The results of the novel combined formulated microcomposite were more favorable than those of the carrier-free formulation for all capsule types. The use of HPMC capsules results in the greatest stability and thus the best in vitro aerodynamic results for both DPI powders after six months. This can be explained by the fact that the residual solvent content (RSC) of the capsules differs. Under the applied conditions the RSC of the HPMC capsule decreased the least and remained within the optimal range, thus becoming less fragmented, which was reflected in the RSC, structure and morphology of the particles, as well as in the in vitro aerodynamic results (there was a difference of approximately 10% in the lung deposition results). During pharmaceutical dosage form developments, emphasis should be placed in the case of DPIs on determining which capsule type will be used for specific formulations. [ABSTRACT FROM AUTHOR]

CO preferential oxidation (PROX) is an effective method to clean reformate H2 streams to feed low-temperature fuel cells. In this work, the PROX and CO oxidation reactions were studied on preformed Au nanoparticles (NPs) supported on TiO2 anatase. Preformed Au NPs were obtained from gold cores stabilized by dodecanethiols or trimethylsilane-dendrons. A well-controlled size of ca. 2.6 nm and narrow size distributions were achieved by this procedure. The catalysts were characterized by high-resolution transmission electron microscopy and ex situ and in situ X-ray photoelectron spectroscopy (XPS). The XPS results showed that the preformed Au NPs exhibited high thermal stability. The different ligand-derived Au catalysts, as well as a conventional gold catalyst for comparison purposes, were loaded onto cordierite supports with 400 cells per square inch. The activity and selectivity of the samples were evaluated for various operation conditions. The catalyst prepared using dodecanethiol-capped Au NPs showed the best performance. In fact, CO conversions of up to 70% at 40% CO2 selectivity and 90% O2 conversion were observed operating at 363 K in H2-rich atmospheres. The performance of the best catalysts was subsequently tested on stainless steel microreactors. A 500-hour stability test was carried out under a real post-reformate stream, including 18 vol.% CO2 and 29 vol.% H2O. A mean CO conversion of ca. 24% was measured for the whole test operating at 453 K and a gas hourly space velocity (GHSV) of 1.3 × 104 h−1. These results reveal our dodecanethiol- and carbosilane-derived Au catalysts as extremely promising candidates to conduct a PROX reaction while avoiding deactivation, which is one of the major drawbacks of Au/TiO2 catalysts. [ABSTRACT FROM AUTHOR]

In this study, Li4Ti5O12 (LTO) electrodes with different types of water-soluble binders are successfully coated upon aluminum foil. Electrodes containing solely sodium alginate (SA) as a binder or a mixed PVDF/carboxymethyl cellulose (CMC) binder show the most stable performance in 1 M LiPF6 in EC/DMC 1:1 in half cell vs. Li, with respect to cycle stability over 100 cycles at 1 C. The electrodes processed with a mixture of PVDF/SA show considerable fading and slightly worse values for rate capability. Each one of the different binders used is eco-friendly, and the whole processing can be performed without the use of organic solvents. Further advantages covering the whole production and recycling process, as well as safety issues during operation, encourage deeper research in this area. [ABSTRACT FROM AUTHOR]

The accuracy of short-term demand forecasting is critical for real-time operation management of urban rail transit, which largely depends on the choice of time resolution. Although there have been continuous improvements in forecasting models, the basic issue has not been well addressed. In this regard, the predictability of short-term demand in terms of time resolution setting and the corresponding model selection have been addressed in this study. Two methods have been considered: the demand forecasting with the past demand during the same time slot on the same weekday (the same period method); and that with continuous time series demand exactly before the forecasted time slot (time series method). The predictability for these two methods was respectively measured by the similarity of the same period and the stability of the time series. Consequently, the influence of time resolution on the predictability of short-term demand for urban rail transit has been evaluated. With the methods proposed, this study conducted an analysis on five-week smartcard data in the Beijing subway system. Results suggest that the predictability of short-term demand presented remarkable heterogeneity in both time and space. The predictability of demand forecasting at station level has been summarized into different levels, and the corresponding methods can be selected for each class. Generally, to ensure a desirable accuracy, forecasting can be made at a 10-min and 60-min interval on weekdays and weekends, respectively. The same period method works better for the short-term demand forecasting on weekdays. While the time series method performs better for prediction on weekends. As for short-time OD (origin-destination) demand, the time series method with a 10-min interval, which is supplemented by the same period method, can generate acceptable forecasting results. In brief, this study provides suggestions on the time resolution and method selection for short-term demand forecasting. [ABSTRACT FROM AUTHOR]