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This experimental study evaluated the performance of modified asphalt mixtures prepared by incorporating 2%, 4%, and 6% linear low-density polyethylene (LLDPE) by weight of asphalt binder through a series of tests. The microstructural analyses using scanning electron microscopy (SEM) were conducted on asphalt samples to assess the engineering properties of the asphalt mixes. Finally, ANOVA statistical analysis has been employed to determine the statistical significance of the differences in all tests' means. Based on laboratory findings, the Marshall stability test result showed that the modified asphalt mixes up to 4% LLDPE had enhanced performance by 12.7% compared to the control mix. A significant decrease (up to 31.3%) in binder penetration was demonstrated due to the incorporation of LLDPE into the asphalt mix. The softening point of the LLDPE–asphalt mixes was increased by up to 17.6%. It was also demonstrated that the incorporation of such LLDPE dosages maintains the flow limits within the specified range; however, the flow of the asphalt mix with 4% LLDPE was 3.17 mm which is the nearest to the average value of the upper and lower acceptable limits. The air voids of mixes with LLDPE content more than 4% by was decreased to less than 4% which is not recommended in high-temperature climates to control mixture bleeding. Microscopic analysis revealed an improvement in the densification of asphalt microstructures, attributed to the LLDPE particles significantly changing the rheology and viscosity of the base mixture and making the hot asphalt mixture more homogeneous. Based on the physical and rheological properties investigated in this study, it could be concluded that 4% LLDPE produces the best performance in asphalt mixtures. Overall, the ANOVA analysis demonstrated that the incorporation of LLDPE into asphalt mixes has a significant impact on all of their properties. [ABSTRACT FROM AUTHOR]

This study underscores the potential of utilizing natural volcanic tuffs (NVTs) as supplementary cementitious materials (SCMs) in alignment with global sustainability efforts aimed at mitigating the cement industry's negative impacts on both the economy and the environment. Experimental investigations were conducted on concrete mixtures containing 10%, 20%, 30%, 40%, and 50% NVT as partial cement replacements to assess their influence on concrete's mechanical and microstructural properties. Based on the findings, concrete samples with 10% NVT replacements exhibited increased flexural and compressive strengths of 35.6% and 5.6%, respectively, compared with ordinary concrete after 28 days. The depth of water penetration in the concrete samples was significantly reduced by the inclusion of NVT, with a maximum reduction of 56.5%. Microstructural analysis using scanning electron microscopy (SEM) revealed enhanced densification of the concrete microstructures, attributed to the high pozzolanic activity of NVT use in cement-based composites. Analysis of variance (ANOVA) revealed statistically significant relationships between NVT content and both the compressive and flexural strengths of the concrete samples. In conclusion, substituting 10% cement with NVT not only enhances the mechanical properties of concrete but also decreases the energy demand for cement production and reduces carbon dioxide (CO2) emissions, thus contributing to more sustainable construction practices. [ABSTRACT FROM AUTHOR]

As urbanization increases, buildings require greater amounts of energy for heating and cooling, thereby necessitating the search for effective solutions. The courtyard is often considered a viable option; however, the limited availability and high cost of land resulting from rapid urbanization hinder its widespread use. Consequently, a courtyard with a cluster of buildings is proposed as a feasible solution to address land scarcity. Nonetheless, further investigation is required to effectively integrate this solution into neighborhood urban planning. This study examines the influence of three variables—courtyard orientation, courtyard size, and the arrangement of buildings around the courtyard—on the provision of cooling and heating for buildings. The research focuses on 216 experimental scenarios simulated using Revit software, which excels in its ability to accurately interpret input data and conduct real-time analysis depending on the variables of the building design. The results were recorded for the facades and ground, and the shaded area was computed for each scenario; following these measurements, the shadow areas on both the facade and ground were converted into percentages. The testing involved a group of buildings surrounding courtyards of four different shapes (square, rectangle, triangle, and circle). This approach aimed to identify the most efficient design for implementation in neighborhood planning contexts. The findings indicate that the shape of the courtyard significantly impacts cooling and heating of buildings. Specifically, the square courtyard is unsuitable for countries with Mediterranean climates, such as Jordan, as it can reduce shade coverage by 30%, leading to higher temperatures. Conversely, employing a rectangular courtyard results in a higher proportion of shadows compared to other shapes. The study further demonstrates the influence of the examined variables on the efficacy of the courtyard in cooling and heating of buildings. [ABSTRACT FROM AUTHOR]

In the absence of industry data, organisms, and researchers leverage free and available data, specifically building and demolition permits. Geospatial processing is essential to integrate information from various files into a single GIS layer containing all relevant attributes for analysis. This article proposes a Geographic Information System (GIS) processing model aimed at monitoring construction and demolition dynamics in the European metropolis of Lille to quantify the urban production of mineral waste from buildings. Author methodology is based on that that the deposit potential can be analyzed using the observation of the spatiotemporal dynamics of building and demolition permits. The results demonstrate that combining construction and demolition (C&D) permits with other GIS layers allows us to produce data to quantify demolition surfaces per year in a given French area. The applicability of this methodology extends to all French regions, providing insights into the impact of crises on deconstruction activities and C&D waste generation. The study focuses on C&D French public data bases (French government and European Metropolis of Lille) attributed to the region (area) of the European Metropolis of Lille (MEL) between 2013 and 2022. Some data for 2022 were incomplete due to ongoing treatment, emphasizing the importance of understanding the dynamics of demolition rates or surfaces to identify data gaps or errors. Historical trajectories of C&D permits were quantified and analyzed, revealing over 21,000 permits granted from 2013 to 2022, categorized by site type (new construction, rehabilitations, prior declarations, and demolitions). Construction sites during this period covered approximately 3,345,948 m2, constituting 20% of the MEL's building stock, while demolition sites amounted to 1,977,911 m2, equivalent to 5% of the total area of buildings in the metropolis. Employing GIS allowed for a spatial analysis, visualizing data by municipality, urban fabric, and year. The analysis highlighted territories with high and low potential for demolition and construction, as well as the most impacted urban fabrics and dynamic periods. The article discusses potential crisis impacts (e.g., COVID-19 or economic downturns) and the implications of incomplete data. Finally, the study demonstrates how these findings can be utilized to quantify C&D waste, leveraging GIS and the production rate calculation method (GRC). [ABSTRACT FROM AUTHOR]

This paper presents a study on the effects of graphene nanoplatelets (GNPs) on the mechanical behavior of 3D-printed burnt clay, the most sustainable and green construction material, under constant printing parameters. Mixes with different nanofilament contents—0.1%, 0.2%, and 0.3% by clay weight—were printed and tested under compression and bending loadings. The results obtained on the printed samples were compared with those fabricated using the molding method. The samples' microstructures were then analyzed using a scanning electron microscope (SEM). Energy dispersive X-ray (EDX) analysis was employed to obtain the elemental distributions. The testing results were then statistically analyzed using a t-statistical method to investigate the impact of using GNPs on the properties of 3D-printed clay. Strength test results showed that mixes containing a low GNP content, i.e., 0.1 wt.%, attained higher compressive and flexural strengths than those containing higher contents, i.e., 0.2 and 0.3wt.%. The results additionally highlighted that the efficiency of GNPs was better observed in the printed samples rather than the molded ones, indicating that the printing process contributed to a better and more uniform dispersion of GNPs in the clay matrix. The t-statistical analysis confirmed that a significant improvement in compressive strength could be obtained using a GNP content of 0.1 wt.%, regardless of the fabrication method. On the other hand, significant flexural strength improvements were observed in the printed samples at all GNP dosages. Micrographs of GNP-modified clay supported the strength results obtained in this study. In summary, this research work signified the importance of using nanofilaments in 3D printing applications in order to achieve the desired elements' mechanical properties. [ABSTRACT FROM AUTHOR]

This paper studied the effect of fly ash (FA) and natural pozzolana (NP) as partial cement substitutes on sustainable concrete permeability and mechanical and microstructural properties. Batches with 10, 20, 30, 40, and 50% FA and NP replacements for cement were prepared and tested for compressive strength after 7, 28, and 56 curing days and for flexural strength after 28 curing days. Permeability testing was conducted on all samples. A qualitative microstructural analysis was performed using scanning electron microscopy (SEM) and energy-dispersive X-ray (EDX). The mechanical properties results showed slight strength improvements when replacing the cement with low percentages of the pozzolanic materials. The compressive strengths of the batches with 10% FA and NP replacements of cement showed compressive strength increases of 11.63 and 8.75%, respectively, compared to that of plain concrete. On the other hand, the flexural strength for the batches with FA replacement of cement achieved at least a 15.6% increase compared to that of the control. Moreover, FA and NP replacement of cement had a positive impact on batch permeability, with decreased permeability values reaching 78.3 and 56.5%, respectively, compared to that of the control. Furthermore, the microstructural analysis indicated that adding FA and NP would enhance cement hydration by the formation of dense hydration products such as calcium–silicate–hydrate (C-S-H) crystals, which increased hardened concrete strength. Finally, the cost analysis showed that the batch with a 10% FA replacement of cement is the ideal one in this study. [ABSTRACT FROM AUTHOR]

Large quantities of dredged sediments and recycled concrete materials are generated every year all over the world. The disposal of these large quantities in landfills represents serious environmental problems. Furthermore, high-quality raw materials for construction are depleting, and their use cannot be sustained. The valorization of dredged sediments and recycled concrete materials as alternative construction materials has the potential to reduce the impact of these two issues. In this context, this study aims at investigating the feasibility of using dredged sediments and recycled concrete aggregates as alternative raw material for road subgrade construction. Various mix designs were prepared using dredged sediments and recycled concrete aggregates. The mixes were then treated with quicklime and road binder as specified in the French soil treatment guide. Their physical, mechanical, and geotechnical properties confirmed the feasibility of using recycled concrete aggregates and dredged sediments up to a certain percentage in road subgrade construction. Moreover, they showed that the mixes containing 20% of dredged sediments met road subgrade minimum physical and mechanical properties, such as immediate bearing capacity, unconfined compression strength, indirect tensile strength greater, and UCSI/UCS60 ratio. Finally, leaching tests were conducted to ensure the environmental safety of the various mixes. The results showed that the mixes met the thresholds for their use in road subgrade construction. The feasibility of using dredged sediments and recycled concrete aggregates in foundations and base layers will be studied in future projects. [ABSTRACT FROM AUTHOR]

This paper is a continuation of a previously published paper on this issue that studied the microencapsulation of calcium nitrate in urea-formaldehyde shell using Aerosol OT (AOT) in hexane solution. The aim of this paper is to determine the quantity of AOT that optimizes microcapsule distribution, diameter, and shell thickness. Different quantities of AOT, namely 0.25 g, 0.50 g, 1.5 g, and 2.5 g were dissolved in 180 g of hexane solution to prepare the continuous phase. A Scanning Electron Microscopy (SEM) was used to characterize the distribution and the diameters of the prepared microcapsules. A Transmission Electron Microscopy (TEM) was used to investigate the microcapsule shell thicknesses. The SEM images have shown that using 0.25 g of AOT may be insufficient to totally polymerize the whole quantity of the core materials into fully independent capsules. On the other hand, using 0.50 g of AOT has shown a uniform distribution and almost complete polymerization of the core material components into distinct microcapsules. Higher quantities of AOT (i.e., 1.50 g and 2.5 g) have resulted in agglomerated microcapsules and nonuniform distributions. The results have also demonstrated that the quantity of AOT does not have a significant impact on the microcapsule diameter. Microcapsule average shell thicknesses were found to decrease by increasing AOT amount up to 0.50 g and to increase again due to the agglomeration witnessed for increased AOT quantity. Accordingly, 0.50 g of AOT was recommended for the preparation of calcium nitrate microcapsules in future research work. [ABSTRACT FROM AUTHOR]

This paper proposes a method for the determination of the optimum surfactant amount to achieve the highest strength for carbon nanotubes (CNT) cementitious composites. The method is based on combining the results of a chemical and a mechanical test. The chemical test was used to determine the remaining amount of surfactant after sonication by analyzing solutions containing CNTs, polycarboxylate surfactant, and water. On the other hand, the mechanical test was used to determine the optimum polycarboxylate surfactant amount that achieved the composite's highest strength by conducting flexural and compressive tests on cement paste specimens prepared using various surfactant concentrations (i.e., 0.03%, 0.08%, 0.12%, 0.15%, 0.32%, and 0.60%). The results show a strong relationship between the paste's strength and the surfactant's concentration. The mixes prepared using 0.08% surfactant-to-cement weight fraction achieved the highest flexural and compressive strengths. Increasing the surfactant-to-cement weight fraction beyond 0.08% resulted in a reduction in the flexural and compressive strengths. This shows the importance of the proposed method in determining the remaining amount of free surfactant in the solution after sonication, and in preventing overdosing that will adversely affect the flexural and compressive strengths of CNT–cement composites. [ABSTRACT FROM AUTHOR]

The micro-encapsulation procedure of calcium nitrate in urea-formaldehyde shell is well known. The most recent developed method for the synthesis of the calcium nitrate self-healing micro-capsules was based on the in-situ polymerization using water-in-oil emulsion. Although the microcapsules' yield was significantly improved using this approach, incorporating the micro-capsules into concrete mixes has been found to reduce strength. One potential strength reduction cause might be the presence of sulfonic acid as a component in the continuous (oil) phase. As the anionic surfactant, Aerosol OT (AOT) has been widely used to prepare water-in-oil emulsions and to form aggregates in non-polar solvents; submicron calcium nitrate refined microcapsules were synthesized using AOT in hexane solution. While the aqueous phase in the original encapsulation procedure has not been altered, the continuous organic phase was prepared by dissolving AOT in hexane. The prepared microcapsules were characterized using Scanning Electron Microscopy (SEM). The preliminary assessment of the effect of incorporating of the refined microcapsules into cementitious materials has been carried out by preparing mortar mixes using 75% capsules' concentration (by weight of cement). The reported yield values, average shell thickness, and average diameter of the prepared microcapsules were found satisfactory. Moreover, the mortar samples containing calcium nitrate refined microcapsules that were prepared using the proposed method did not experience significant reduction in their mechanical properties. Hence, such encapsulation procedure may be adopted for further investigation of the self-healing efficiency in cementitious materials of the microcapsules prepared using the proposed procedure. Future work shall be directed towards this end. [ABSTRACT FROM AUTHOR]

Sediment dredging is necessary and vital to preserve maritime activities and prevent floods. The management of these sediments represent an environmental challenge for many countries all over the world. This study focuses on evaluating the feasibility of using dredged sediments for the manufacturing of compressed earth blocks (CEB). The alternative construction material has the potential of reducing the need for dredged sediment onshore storage or ocean dumping. Several experimental tests have been conducted on two geopolymer types, which were obtained by mixing sediments from the northern region of France, fly ash (FA), and grounded blast furnace slag (GBFS). The geopolymers, which were activated using an eight-molar concentrated sodium hydroxide solution (NH), were cured at a temperature of 50 °C. The results have shown that a geopolymer content of 36% of FA and 10% of GBFS along with (NH) alkaline solution has significantly improved the mechanical properties of CEBs, which have outperformed those of Portland Cement-stabilized traditional blocks. The use of NH has resulted in the formation of crystalline calcium silicate hydrate (C-S-H) amorphous gel. Adding GBFS to the mix has enhanced the geopolymer paste compressive strength and microstructure because of the formation of additional C-S-H. The valorization of dredged sediments in CEB based on geopolymer stabilization can contribute to the reduction of the CO2 footprint of the construction industry. [ABSTRACT FROM AUTHOR]

This paper investigates the potential utilization of the Tunnel Boring Machine (TBM) muck generated from Doha's Metro Gold Line in different construction applications. The properties of the raw TBM muck were studied, and the results were compared to the specifications of Qatari Construction Standards (QCS 2014) of concrete aggregates, fill material under buildings and road subgrades. Compared to the requirements of concrete aggregates, the results indicated that the gradation of the raw TBM muck does not comply with the QCS 2014 requirements, and hence, sieving and screening may be essential. Moreover, the tests' results showed that the properties of the muck meet the requirements of the concrete coarse aggregates, except for the water absorption, loss by magnesium sulphate soundness, loss by Los Angeles abrasion and the acid-soluble sulphate. As fill material under buildings or road subgrades, the gradation of the TBM muck complies with the QCS 2014 requirements, while the liquid limit and plasticity index are higher than the QCS 2014 permissible limits. Additionally, the morphological structure and the elemental composition of the raw TBM muck were determined by employing Scanning Electron Microscopy (SEM) and Energy Dispersive X-ray analysis (EDX), respectively. Digital images were also taken at larger scale to draw a full picture of the TBM muck morphology. A mixture of rough-rounded to angular-elongated shaped particles with relatively large voids could be observed. The EDX analysis demonstrated the presence of silicon (Si) as the predominant component of the muck, which may alter the Coefficient of Thermal Expansion (CTE) values for mixtures prepared using TBM muck. Hence, further investigations should be performed on the mechanical and thermal properties of mixtures containing TBM muck as aggregates' replacement, and further work should be directed toward this end. [ABSTRACT FROM AUTHOR]

This study investigated the potential utilization of the TBM muck obtained from the Gold Line of the Doha Metro Project as a partial replacement of coarse aggregates in concrete mixes. First, the TBM muck particles were screened to coarse aggregate standard sizes. Then, concrete mixes were prepared using 0%, 25%, 50%, and 75% TBM muck replacement of coarse aggregates. The compressive and flexural strengths were determined for all mixes at 28 and 56 days. Moreover, the results obtained were validated using EDX analysis and SEM images. A t-statistical analysis did not show a significant impact of TBM muck usage on the compressive strength results of the concrete mixes. However, another t-statistical analysis showed that TBM muck replacement of coarse aggregates had adversely affected the flexural strength results. The EDX analysis indicated the presence of Na+ ions, which can replace the Ca2+ ions in the C-S-H gel, cause discontinuities of it, and hence reduce the strength at later ages. Finally, the SEM images showed that the ettringite and carbon hydroxide (C-H) contents in the mixes with TBM muck were higher than that of the control mix, while the C-S-H gel was less in such mixes. [ABSTRACT FROM AUTHOR]

This study investigated the potential use of Zerdezas dam Calcined Sediments (CS) and El-Hadjar Blast Furnace Slag (GGBS) from northern Algeria as a partial replacement of cement (C) in normal hardening hydraulic road binders. Two binder mix designs were optimized using a Response Surface Methodology (RSM). The first mix, 50C35GGBS15CS, consisted of 50% cement, 35% blast furnace slag, and 15% calcined sediment. The second mix, 80C10GGBS10CS, consisted of 80% cement, 10% blast furnace slag, and 10% calcined sediments. The tests of workability, setting time, volume expansion, compressive and flexural strengths, porosity, and SEM were conducted to ensure that both mixes meet the standard requirements for road construction binders. The two proposed mixes were qualified as normal hardening hydraulic road binder. The reuse of the sediments will contribute to a better disposal of dam sediments and steel industry waste and to preserve natural resources that are used for manufacturing cement. It will also contribute to the environmental impact reduction of cement clinker production by reducing greenhouse gas emissions. [ABSTRACT FROM AUTHOR]