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In this paper, a POD reduced-order interpolation model for solving the in situ pyrolysis process of tar-rich coal is employed to predict the flow and heat transfer performance in the porous media region so as to save computational resources and realize fast calculations. Numerical simulation using the finite volume method (FVM) is firstly used to obtain sample data, based on the samples through the primary function and spectral coefficients of the solutions. The physical field information and parameter distribution under different conditions of inlet temperature, inlet velocity and permeability are predicted. The results are compared with those of FVM to verify the accuracy of the calculated results. The relative mean deviation (RME) of the results of the POD prediction of each parameter for each working condition was synthesized to be no more than 5%. The performance of in situ pyrolysis of tar-rich coal is then investigated, and the oil and gas production are predicted. As the inlet velocity increases from 0.3 m/s to 0.9 m/s, the fraction of high-quality oil and gas production reaches 0.47 and then decreases to 0.38. Increasing the inlet temperature and permeability has a negative effect on the fraction of high-quality hydrocarbon production, after which the quality fraction of high-quality oil and gas dropped sharply to about 0.22. Porosity has a positive impact on the oil and gas production. When the porosity reaches 0.3, the quality fraction of high-quality oil and gas can reach 0.27. [ABSTRACT FROM AUTHOR]

Tea polyphenol and epigallocatechin gallate (EGCG) were considered as key components of tea. The rapid prediction of these two components can be beneficial for tea quality control and product development for tea producers, breeders and consumers. This study aimed to develop reliable models for tea polyphenols and EGCG content prediction during the breeding process using Fourier Transform–near infrared (FT-NIR) spectroscopy combined with machine learning algorithms. Various spectral preprocessing methods including Savitzky–Golay smoothing (SG), standard normal variate (SNV), vector normalization (VN), multiplicative scatter correction (MSC) and first derivative (FD) were applied to improve the quality of the collected spectra. Partial least squares regression (PLSR) and least squares support vector regression (LS-SVR) were introduced to establish models for tea polyphenol and EGCG content prediction based on different preprocessed spectral data. Variable selection algorithms, including competitive adaptive reweighted sampling (CARS) and random forest (RF), were further utilized to identify key spectral bands to improve the efficiency of the models. The results demonstrate that the optimal model for tea polyphenols calibration was the LS-SVR with Rp = 0.975 and RPD = 4.540 based on SG-smoothed full spectra. For EGCG detection, the best model was the LS-SVR with Rp = 0.936 and RPD = 2.841 using full original spectra as model inputs. The application of variable selection algorithms further improved the predictive performance of the models. The LS-SVR model for tea polyphenols prediction with Rp = 0.978 and RPD = 4.833 used 30 CARS-selected variables, while the LS-SVR model build on 27 RF-selected variables achieved the best predictive ability with Rp = 0.944 and RPD = 3.049, respectively, for EGCG prediction. The results demonstrate a potential of FT-NIR spectroscopy combined with machine learning for the rapid screening of genotypes with high tea polyphenol and EGCG content in tea leaves. [ABSTRACT FROM AUTHOR]

The open circuit voltage of lithium ion batteries in equilibrium state, as a vital thermodynamic characteristic parameter, is extensively studied for battery state estimation and management. However, the time-consuming relaxation process, usually for several hours or more, seriously hinders the widespread application of open circuit voltage. In this paper, a novel voltage relaxation model is proposed to predict the final open circuit voltage when the lithium ion batteries are in equilibrium state with a small amount of sample data in the first few minutes, based on the concentration polarization theory. The Nernst equation is introduced to describe the evolution of relaxation voltage. The accuracy and effectiveness of the model are verified using experimental data on lithium ion batteries with different kinds of electrodes (LiCoO2/mesocarbon-microbead and LiFePO4/graphite) under different working conditions. The validation results show that the presented model can fit the experimental results very well and the predicted values are quite accurate by taking only 5 min or less. The satisfying results suggest that the introduction of concentration polarization theory might provide researchers an alternative model form to establish voltage relaxation models. [ABSTRACT FROM AUTHOR]