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Understanding the composition, formation and evolution of the oldest continental crust is crucial for comprehending the mechanism and timing of crustal growth and differentiation on early Earth. However, the preservation of the ancient continental crust is limited due to extensive reworking by later tectonothermal events. In the Lulong area of eastern Hebei, abundant ca. 3.8–3.4 Ga detrital zircons of the fuchsite quartzite have been previously identified. Nonetheless, the provenance and Hf isotopic compositions of the fuchsite quartzite remain unclear. In this study, we present new detrital zircon ages and Hf isotopic for the fuchsite quartzite in the Lulong area to establish the timing of deposition, the provenance and the regional stratigraphic relationship. Zircon U-Pb dating indicates that the fuchsite quartzite was deposited between 3.3–3.1 Ga and most grains were sourced from the 3.8 Ga TTG gneisses and Paleoarchean magmas. Field investigations and regional correlations reveal that the fuchsite quartzite from the Lulong area is equivalent to that of the Caozhuang area. Zircon Hf isotopic data from eastern Hebei Province (Lulong and Caozhuang areas) and Anshan and Xinyang areas indicate that the oldest crustal growth event of North China Craton occurred in the Hadean. [ABSTRACT FROM AUTHOR]

The production of synthetic iron castings in Russia comprises 50% of all alloys produced; therefore, increasing their smelting efficiency is an urgent task in the industry. This process depends primarily on the efficiency of industrial frequency induction crucible furnaces using acid lining. In the present study, the properties of quartzite, which forms the basis of such a lining, were investigated. An analysis of the proposed variants for changing the composition of the acid lining for use at temperatures of 1550–1600 °C was conducted. Following the preliminary temperature treatment of raw quartzite, which was then subjected to a sintering regime, we determined the conditions under which it was possible to obtain a phase state, allowing for the operation of the lining at temperatures above 1450 °C. We determined the use of an electrocorundum of two fractions as an additive to the traditional composition of the acid lining. The industrial testing of a new liner composition for the smelting of synthetic cast iron in an induction crucible melting furnace with a single steel scrap-metal filling was assessed, which required the use of an increased amount of carburizing agent. The positive results obtained can be explained by the study of the spent lining, which withstood 345 smelting methods of genophasic rent analysis. The results of the test are based on the results obtained in a study conducted on the finished coating of the product. [ABSTRACT FROM AUTHOR]

In this paper, we outline a study conducted on altered rocks in Central Kazakhstan, in particular, focusing on secondary quartzites. The study reveals a connection between copper-porphyry deposits in Central Kazakhstan and secondary quartzites. Recent research has unveiled gold mineralization in various secondary quartzite massifs, which has spurred further investigations in the region. Over the past three decades, extensive studies have been conducted that have demonstrated similarities among the gold deposits in this area and epithermal gold-silver deposits in volcanic-plutonic arcs around the world. By identifying patterns in the distribution of gold mineralization and developing regional exploration criteria, researchers have comprehensively assessed 48 secondary quartzite massifs and have prioritized promising areas for further exploration. Valuable findings have emerged from detailed examinations of the Akgirek and Birlestik massifs, which have involved drilling exploration wells up to a depth of 250 m. These investigations have shed light on the depth distribution of metasomatites and their association with gold mineralization. Consequently, these findings strengthen our belief in the significant potential for gold mineralization in the secondary quartzites of the Jungar-Balkhash folded system. [ABSTRACT FROM AUTHOR]

The Korean Peninsula mainly comprises the Paleoproterozoic Gwanmo, Nangnim, Gyeonggi, and Yeongnam massifs from north to south. The Paleoproterozoic basement is rarely exposed in the Paleozoic Taebaeksan basin, which is located in the northeastern part of the Okcheon belt between the Gyeonggi and Yeongnam massifs. One of the most important issues in the tectonic interpretation of the Korean Peninsula is whether Paleoproterozoic rocks in the Taebaeksan basin have an affinity with those in the Gyeonggi or Yeongnam massifs. To solve this problem, we focused on the petrogenesis of the Imgye gabbroic diorite, Jungbongsan granite, and Jangsan quartzite in the Imgye area of the Taebaeksan basin. The Imgye gabbroic diorite shows mafic to intermediate compositions with slightly enriched LREEs compared to HREEs, slightly positive Rb, K, and Pb anomalies, and negative Ta, Nb, and P anomalies. The Imgye gabbroic diorite formed in a volcanic arc tectonic setting. The geochemical compositions of the Jungbongsan granite show enriched LREEs compared to HREEs with negative Eu anomalies, and reveal strong positive Rb, Th, K, and Pb anomalies with negative Ba, Ta, Nb, Sr, P, Eu, and Ti anomalies. This Jungbongsan granite also formed in an arc tectonic setting like the Imgye gabbroic diorite. LA-ICP-MS zircon age dating of the Imgye gabbroic diorite gives an intrusion age of 1948 ± 21 Ma, whereas SHRIMP U–Pb zircon age dating on the Jungbongsan granite yields an emplacement age of 1873 ± 14 Ma. The εHf(t) values of the Imgye gabbroic diorite are from 3.5 to 9.7, whereas those of the Jungbongsan granite are from −2.9 to 0.6. These data imply that the Imgye gabbroic diorite formed from a depleted mantle in the arc tectonic environment, whereas the Jungbongsan granite formed by reworking pre-existing crust material in the arc environment. The detrital zircons in the Jangsan quartzite show ages ranging from 3.06 to 1.85 Ga, with a peak concentration of ca. 2.5 Ga. Previous studies have suggested that the northern Gyeonggi and Nangnim massifs underwent collision-related magmatism and metamorphism at ca. 1.93–1.90 Ga, and then post-collisional magmatism and metamorphism at ca. 1.89–1.83 Ga, whereas the southern Gyeonggi massif underwent subduction-related magmatism and metamorphism at ca. 1.94–1.92 Ga, and then post-collision-related magmatism and metamorphism at ca. 1.84–1.78 Ga. By contrast, subduction-related events were recognized in the northern Yeongnam massif at ca 2.02–1.96 Ga and 1.90–1.85 Ga. This work, combined with the previous studies, suggests that the Paleoproterozoic basement in the Imgye area of the Taebaeksan basin can be correlated with the Paleoproterozoic basement of the northern Yeongnam massif rather than with those of the Nangnim and Gyeonggi massifs. [ABSTRACT FROM AUTHOR]

In Juazeiro de Piauí and Castelo do Piauí, two cities in northeast Brazil, mined morisca rock is widely used in civil construction for external coating applications. Aiming at a sustainable practice for its extraction, which includes the economical use of the tailings from its mining, this work presents a solution for the use of discarded materials from processing morisca from Piauí. In this context, an analysis of the results of using morisca as a substitute for clay materials for applications in red ceramics are presented. For the analyses, XRF, XRD, microgranulometry, limits of consistency, TG, DTG, and a set of technological tests inherent to ceramic materials were used. It was concluded that morisca powder is viable as a clay substitute for red ceramic applications. [ABSTRACT FROM AUTHOR]

The current sedimentological and petrographical research of the Abbottabad Formation has been carried out in order to understand the formation and evolution of the Proto-Tethys Ocean during the Cambrian on the northern margin of the Indian Plate. The Muzaffarabad region is located east of the Upper Indus Basin and the southern part of the Hazara Kashmir Syntaxis. The geological history of the region varies from the Precambrian to the recent period. The Cambrian Abbottabad Formation is well exposed along the Hazara Kashmir Syntaxis at the core of the 500-m-thick Muzaffarabad anticline. The Abbottabad Formation is an unconformity-bounded allo-stratigraphic unit. It has an unconformable lower contact with the Late Precambrian Dogra Formation and an unconformable upper contact with the Paleocene Hangu Formation. The Abbottabad Formation has been divided into four lithofacies, from bottom to top, namely, thinly interbedded dolomite and shale, cherty-stromatolitic dolomite, oxidized limonitic-brecciated zone, and quartzite, with significant lithological changes. Petrographic studies revealed four types of dolomites: fine crystalline dolomite (Dol. I), dolomitic cryptocrystalline chert (Dol. II), algal mat-stromatolitic dolomite (Dol. III), and intraclastic-dolo-grain stone (Dol. IV). The mineral composition of dolostone was analyzed using X-ray diffraction (XRD) and found to be consistent with previous petrographic studies. The dolomite mineral content decreased from base to top, while chert increased towards the top. Elemental weight percentages through energy dispersive X-ray (EDX) analysis show different elements constitute the minerals found in the dolostone, as confirmed by petrographic and XRD analysis. Using outcrop data, facies information, and geochemical data, a modified depositional model of the Abbottabad Formation was developed. During the Early Cambrian period, the formation was deposited in a shallow subtidal to supratidal setting of the Proto-Tethys Ocean. The top of this deposit marks the Cambrian–Paleocene boundary. Because of the progressively coarsening outcrop sequences, this formation seems to be at the very top of the Proto-Tethys Ocean's shallow marine system. [ABSTRACT FROM AUTHOR]

First of all, the smelting equipment is the most important component of a foundry's main production process and therefore requires constant reproduction. This is ensured by timely and high-quality maintenance and repair, the cost of which is 8–12% of the total costs. The technical and economic conditions of the enterprise itself depend on this, as the productivity of workers during production is directly related to the technical condition of the equipment and its downtime for repairs. An important factor in ensuring a melting furnace's reproduction is a replacement of the worn lining, which leads to downtime of the smelting furnace and reduces the efficiency of its operation. The amount of torque required depends directly on the compound used. The quality of the manufacturing and sintering process of the lining, which provides the necessary durability, is affected by the heat capacity of the materials used when they are affected by the melting temperature of the alloys. In the present work, using the BRUKER D8 ADVANCE diffractometer, the Shimadzu XRF-1800 spectrometer and the STA 449 F1 Jupiter synchronous thermal analyzer, we probed the changes in the heat capacity of quartzite and PKMVI-3 under the action of temperatures of 200–1550 °C. This technology allows the manufacture of a lining that maintains high stability during operations at 1550–1600 °C melting modes. [ABSTRACT FROM AUTHOR]

Concrete is classified as a multi-composite material comprising three phases: coarse aggregate, mortar, and interfacial transition zone (ITZ). Fine and coarse aggregates occupy approximately 70–85% by volume, of which coarse aggregate typically constitutes more than two-thirds of the total quantity of aggregate by volume. The current study investigates the concrete performance produced using various recycled construction and by-product industrial waste coarse aggregates. Six types of coarse aggregates: manufactured limestone, quartzite, natural scoria, by-product industrial waste aggregate, and two sources of recycled concrete aggregates with densities ranging from 860 to 2300 kg/m3 and with different strength properties were studied. To determine the coarse aggregate contribution to the overall concrete performance, lean and rich concrete mixtures (Mix 1 and Mix 2) were used. Mix 1 (lean mixture) consisted of a ratio of water to cement (w/c) of 0.5 and cement content of 300 kg/m3, whereas a higher quantity of cement of 500 kg/m3 and a lower w/c ratio of 0.3 were used for Mix 2 (rich mixture). The results showed that while the compressive strength for different aggregate types in Mix 1 was comparable, the contribution of aggregate to concrete performance was very significant for Mix 2. Heavyweight aggregate produced the highest strength, while the lightweight and recycled aggregates resulted in lower mechanical properties compared to normal weight aggregates. The modulus of elasticity was also substantially affected by the coarse aggregate characteristics and even for Mix 1. The ACI 363R-92 and CSA A23.3-04 appeared to have the best model for predicting the modulus of elasticity, followed by the ACI-318-19 (density-based formula) and AS-3600-09. The density of coarse aggregate, and hence concrete, greatly influenced the mechanical properties of concrete. The water absorption percentage for the concrete produced from various types of aggregates was found to be higher for the aggregates of higher absorption capacity. [ABSTRACT FROM AUTHOR]

Understanding mass transfer associated with fluids circulation and deformation in the Alpine orogeny is often complex due to common multistage crystallization. For example, in two emblematic and historic Pb-Ag deposits of the French Alps, Macôt-la Plagne (MP) and Peisey-Nancroix (PN), a sedimentary or orogenic origin is still debated. To discriminate between the metallogenic models of the two deposits, an integrative methodology combining field, microstructural, mineralogical, thermobarometrical, and geochronological data was here applied for establishing detailed Pressure–Temperature–Time–Deformation (P-T-t-d) mineralization conditions. Both deposits are located in Permo-Triassic quartzite of the External Briançonnais domain along the Internal Briançonnais Front (Internal Western Alps). The ore mainly occurs as veins and disseminated textures containing galena, pyrite, and variable content of tetrahedrite–tennantite and chalcopyrite. Quartz porphyroclasts and sulfide microstructures indicate a dynamic recrystallization of the quartzite during the main fluid mineralization episode. Chlorites and K-white micas (phengite) chemical analysis and thermodynamic modeling from compositional maps indicate an onset of the mineralization at 280 °C, with a main precipitation stage at 315 ± 35 °C and 6.25 ± 0.75 kbar. In situ U-Pb dating on monazite, cogenetic with sulfides, gives ages around 35 Ma for both deposits. The integrative dataset converges for a cogenetic MP-PN Alpine Pb-Ag mineralization during deformation in relation to the thrusting of the "Nappe des Gypses" and the Internal Briançonnais at the metamorphic peak. [ABSTRACT FROM AUTHOR]

The main purpose of industrial frequency induction crucible smelters (IGM) is the smelting of synthetic cast iron, using metal filling scrap in the amount of 30–35%, at a temperature not exceeding 1450 OZ C. The basis of the lining used is quartzite, which undergoes polymorphic transformations in the pre-treatment process to form tridimite. The efficiency of using these furnaces is significantly increased when using a metal casting consisting of a single steel scrap, but for this purpose, the melting mode has to be raised to 1550–1600 °C, which will reduce the resistance of the lining. The structural transformation of quartzite is strongly influenced by the state of water in it. In this work, studies have been carried out for changes in the water condition in the quartzite of the brand PCMVI-3 under the action of temperatures of 200–1550 °C. The Shimadzu XRF-1800 spectrometer established the actual chemical composition of the investigated quartzite and found that the amount of impurities in it is 0.66%. A derivative study of STA 449 F1 Jupiter found two endothermic effects. The first, at 170 °C, relates to the loss of adsorbed water. The second, at a temperature of 570 °C, passes without the loss of mass of the sample, and it is accompanied by the beginning of the process of the destruction of point defects in the form of Al-OH groupings. From a temperature of 620–630 °C, no mass changes associated with water removal were detected. The BRUKER D8 ADVANCE diffractometer investigated phase changes during the removal of moisture from the quartzite at temperatures of 200 and 800 °C and subsequent cooling and then during the heating used to sinter the lining. As a result, it has been established that the sheet in which the quartzite contains only chemically bound moisture, after sintering, turns into cristobalite and provides a more stable exposure to sudden temperature changes. This makes it possible to use up to 90% of the steel scrap in metal filling, which increases the efficiency of the melting furnace and the production of castings in general. [ABSTRACT FROM AUTHOR]

The efficiency of the production of foundry products depends on the reliable operation of the melting furnace including, therefore, the durability of its lining. The most common material adopted for the production of an acid furnace crucible lining is quartzite, in which during the pretreatment (heating to 800 °C followed by holding), a tridymite phase appears that maintains a constant volume at 840–1470 °C for a long time and provides high lining durability of 300–350 melts, but only when using melting temperature regimes not exceeding 1500 °C. However, the absence of iron scrap leads to the smelting of synthetic iron from only one steel scrap using higher melting temperatures (1550–1570 °C), which sharply reduces the lifetime of the lining to 220 melts. This work is devoted to research aimed at establishing technology for the pretreatment with the original quartzite, which ensures the formation of a phase state that successfully withstands elevated temperatures for a long time. The studies were carried out using a Bruker D8 ADVANCE diffractometer and a Shimadzu XRF-1800 X-ray wave-dispersive spectrometer. The work consisted of drying samples of the original quartzite at temperatures of 200 and 800 °C with subsequent exposure to temperatures of 200, 400, 600, 870, 1000, 1200, 1470 and 1550 °C. As a result, the conditions for pretreatment of quartzite were established, during which during its further use, a cristobalite phase can be obtained, which makes it possible manufacture a high-temperature lining that ensures its high durability. The introduction of this technology will ensure the efficiency of the production of foundry products for enterprises operating induction crucible furnaces at industrial frequency. [ABSTRACT FROM AUTHOR]

The development of artificial stone from the agglutination of polymeric resin using industrial wastes can be a viable alternative from a technical, economic, and sustainable point of view. The main objective of the present work was to evaluate the physical, mechanical, and structural properties of artificial stones based on quartzite waste added into a synthetic, epoxy, or biodegradable polyurethane polymer matrix. Artificial stone plates were produced through the vacuum vibration and compression method, using 85 wt% of quartzite waste. The material was manufactured under the following conditions: 3 MPa compaction pressure and 90 and 80 °C curing temperature. The samples were characterized to evaluate physical and mechanical parameters and microstructure properties. As a result, the artificial stone plates developed obtained ≤0.16% water absorption, ≤0.38% porosity, and 26.96 and 10.7 MPa flexural strength (epoxy and polyurethane resin, respectively). A wear test established both artificial quartzite stone with epoxy resin (AS-EP) and vegetable polyurethane resin (AS-PU) high traffic materials. Hard body impact resistance classified AS-EP as a low height material and AS-PU as a very high height material. The petrographic slides analysis revealed that AS-EP has the best load distribution. We concluded the feasibility of manufacturing artificial stone, which would minimize the environmental impacts that would be caused by this waste disposal. We concluded that the production of artificial rock shows the potential and that it also helps to reduce environmental impacts. [ABSTRACT FROM AUTHOR]

We experimentally determined the hydraulic properties of fractures within various rock types, focusing on a variety of Variscan rocks. Flow-through experiments were performed on slate, graywacke, quartzite, granite, natural fault gouge, and claystone samples containing an artificial fracture with a given roughness. For slate samples, the hydraulic transmissivity of the fractures was measured at confining pressures, pc, at up to 50 MPa, temperatures, T, between 25 and 100 °C, and differential stress, σ, acting perpendicular to the fracture surface of up to 45 MPa. Fracture transmissivity decreases non-linearly and irreversibly by about an order of magnitude with increasing confining pressure and differential stress, with a slightly stronger influence of pc than of σ. Increasing temperature reduces fracture transmissivity only at high confining pressures when the fracture aperture is already low. An increase in the fracture surface roughness by about three times yields an initial fracture transmissivity of almost one order of magnitude higher. Fractures with similar surface roughness display the highest initial transmissivity within slate, graywacke, quartzite and granite samples, whereas the transmissivity in claystone and granitic gouge material is up to several orders of magnitude lower. The reduction in transmissivity with increasing stress at room temperature varies with composition and uniaxial strength, where the deduction is lowest for rocks with a high fraction of strong minerals and associated high brittleness and strength. Microstructural investigations suggest that the reduction is induced by the compaction of the matrix and crushing of strong asperities. Our results suggest that for a given surface roughness, the fracture transmissivity of slate as an example of a target reservoir for unconventional EGS, is comparable to that of other hard rocks, e.g., granite, whereas highly altered and/or clay-bearing rocks display poor potential for extracting geothermal energy from discrete fractures. [ABSTRACT FROM AUTHOR]

The greater demand for high-quality iron ores has forced the iron and steel industries to utilize low-grade iron ores, such as banded hematite quartzite (BHQ). In the present work, a striped hematite quartzite sample from the Haraginadoni area, in the Sandur schist belt, Ballari District, Karnataka, India, was subjected to characterization studies and conventional mineral processing methods to produce pellet-grade concentrate, assayed as Fe > 63.0%, SiO2 + Al2O3 < 7%, (Al2O3/SiO2 < 0.5). The sample was analyzed as 35.70% Fe, 47.44% SiO2, 0.75% Al2O3, 0.06% Mn, 0.07% TiO2, 0.03% P, 0.02% S, and 0.83% LOI. We focused on two routes of beneficiating BHQ samples: (1) conventional gravity followed by reverse floatation and (2) magnetic separation followed by cleaning of magnetic concentrate by reverse floatation. Route 1, achieved pellet-grade concentrate through assaying, and was 63.73% Fe, 6.20% SiO2, 0.19% Al2O3, 0.03% Al2O3/SiO2, and 0.23% LOI, D80 45 µm, with 70.1% Fe recovery and 62.8% concentration efficiency at 39.6 wt% yield. Using Route 2, the process consisted of WHIMS at −74 µm, D80 54 µm, 10,000 Gauss, and with a 3 mm ball matrix, followed by flotation of the WHIMS concentrate, which produced a concentrate through assaying and was 63.34% Fe, 6.30% SiO2, 0.20% Al2O3 (0.03 Al2O3/SiO2), and 0.20% LOI with 77.4% Fe recovery, achieving a 68.8% concentration efficiency at 44.0 wt% yield, meeting pellet-grade specifications. Comparing and analyzing both routes for the concentration methods, Route 2, i.e., WHIMS and the reverse flotation of WHIMS concentrate, was amenable compared to Route 1. [ABSTRACT FROM AUTHOR]

Based on the LA-ICP-MS U-Pb zircon ages of four metamorphic samples, we discuss the geochronology and provenance of the Guadaiza nappe, an allochthonous unit that underlies the Ronda peridotites (Betic Cordilleras, Spain). The Guadaiza nappe is composed of Triassic marbles overlying a metapelitic sequence with schists and migmatites. Zircons from a quartzite interlayered with the marbles yield a maximum depositional age of ca. 289 Ma that supports the Triassic age. The idiomorphic morphology of these Paleozoic zircon crystals and the lack of late-Variscan metamorphism (ca. 300 Ma) supports a proximal source area, and suggests that the marbles were discordantly deposited over the metapelitic sequence, along the northern margin of the Alboran microplate. The zircon patterns from the metapelitic sequence mainly yield Paleoproterozoic (ca. 1.6–2.5 Ga), Tonian–Stenian (ca. 1000 Ma), Ediacaran–Cryogenian (ca. 600 Ma) and Paleozoic (ca. 500 Ma) age clusters. These results suggest provenance from areas within the triangle bound by the West African Craton, the Metasaharan Craton and the Hun Superterrane during the Paleotethys opening (Silurian–Devonian). A Silurian–Carboniferous deposition age for the schist protoliths is constrained by the youngest detrital zircon population (ca. 443 Ma) and the Variscan age of their migmatization by an additional peak of around 299 Ma in the migmatites. [ABSTRACT FROM AUTHOR]

Kendale Hecala is located on the Ambar River in the Upper Tigris Basin, province of Diyarbakır in Southeast Anatolia. Various raw materials, including obsidian, radiolarite, chert, jasper, chalcedony, and quartzite, were used in the lithic industry. Obsidian artefacts constitute an average of 64% of the chipped stone assemblage. Technological analysis reveals that obsidian was brought to the settlement as nodules and chipped into various tools at the settlement. Understanding the operational sequence of the lithic industry, chaîne opératoire, including the distribution of raw material from source to site, is important to demonstrate the socio-cultural organization of the settlement in Southeastern Anatolia during the Ubaid period. In order to identify source varieties, the obsidian artefacts uncovered from Ubaid layers of Kendale Hecala were analyzed by macro-observations, and the characterization of archaeological samples was performed using a handheld XRF. Multivariate analysis of the data indicates the use of obsidian from different resources at the settlement, including Nemrut Dağ, Bingöl B, and Group 3d. [ABSTRACT FROM AUTHOR]

A comprehensive understanding of geological, structural geological, hydrogeological and geotechnical features of the host rock are essential for the design and performance evaluation of surface and underground excavations. The Hungarian National Radioactive Waste Repository (NRWR) at Bátaapáti is constructed in a fractured granitic formation, and Telfer Gold Mine in Australia is excavated in stratified siltstones, sandstones and quartzites. This study highlights relationships between GSI chart ratings and calculated GSI values based on RMR rock mass classification data. The paper presents linear equations for estimating GSI from measured RMR89 values. Correlations between a and b constants were analyzed for different rock types, at surface and subsurface settings. [ABSTRACT FROM AUTHOR]

In order to investigate the weathering characteristics of rocks in response to freeze-thaw conditions in northern latitudes, we analysed meteorological data from the Ny-Ålesund region in Norway, and observed changes in the physical and mechanical properties of rocks of dolomite and quartzite. To assess the effects of freeze-thaw weathering on these rock properties, 900 cycles of long-term freeze-thaw tests were conducted for the sampled rocks in two locations. P-wave velocity, absorption, shore hardness, and the uniaxial compressive strength of the sampled rocks were measured at every 150 cycles in order to analyse physical and mechanical mediator variables of freeze-thaw weathering. It was found that an increasing number of freeze-thaw cycle on the sampled rocks decreases uniaxial compressive strength, shore hardness, and P-wave velocity and increases absorption. [ABSTRACT FROM AUTHOR]

The mechanistic approach has proven so far to be flexible and successful for simulation of the grinding process. The basic idea underlying mechanistic models, namely the matrix and population balance models, is based on the identification of natural events during grinding. Since each model has its own capabilities and limitations, their combined use may offer additional advantages on this aspect. In this study, the matrix model and the selection function, namely the probability of breakage of the population balance model, were combined through a MATLAB code to predict the size distribution of the grinding products of quartz, marble, quartzite and metasandstone. The modeling results were in very good agreement with the particle size distributions obtained after grinding the feeds in a ball mill. [ABSTRACT FROM AUTHOR]

At present, quartzite is widely used across many industries. The properties of quartzite significantly affect the technology used during the preparation of the raw materials as well as the technology used for manufacturing the final product, which may be intended for further operation at different temperatures. The purpose of the study was to create a scheme for the transformation of quartzite that would describe the changes in the parameters of its lattice parameter upon heating and would offer guidance regarding the drying technology and technology required to obtain tridymite. A Bruker D8 Advance diffractometer was used to study changes in the phase composition of quartzite at the temperatures of 200, 400, 600, 879, 1000, 1200, 1470, and 1550 °C. A detailed scheme of transformations of PKMVI-1 quartzite with a SiO2 content of at least 97.5% at normal pressure was proposed for crystalline modifications formed during its heating. As a result of this research, the changes in the parameters of the lattice parameter—such as the average interplanar distance davg, the volume of the unit cell Vavg, the density of the unit cell Davg, and the molecular weight Mavg—were established. [ABSTRACT FROM AUTHOR]

The main objective was to determine the deleterious potential of quartzite mining tailings subjected to different ASR alkali–silica reaction tests. The studies included petrographic analysis, chemical analysis of cements, expansion tests in mortar bars and concrete prisms, and microstructural analysis. Petrographic analysis of quartzites indicated high percentages of deformed quartz (95%), and were classified as potentially reactive. Two types of HES high early strength cement with alkaline equivalents of 0.749% and 0.61%, respectively, were selected. Of the 8 samples analyzed by the accelerated method in mortars, only 2 quartzite samples and 1 diabasium sample indicated potentially reactive behavior. The accelerated and long-term methods in concrete prisms proved to be effective and were consistent with the deleterious potential of the samples. All analyzed samples were diagnosed with the ASR gel. In the microstructural analysis, in addition to the ASR products, other expansive products of late ettringite were detected. Reaction mitigation methods are proposed so that quartzite waste can be used as an alternative aggregate in concrete, and thus contribute to the reduction of mine tailings and, consequently, reduce the negative environmental impact from mining. [ABSTRACT FROM AUTHOR]

Remote sensing techniques are leading methodologies for landslide characterization and monitoring. However, they may be limited in highly vegetated areas and do not allow for continuously tracking the evolution to failure in an early warning perspective. Alternative or complementary methods should be designed for potentially unstable sites in these environments. The results of a six-month passive seismic monitoring experiment on a prone-to-fall quartzite tower are here presented. Ambient seismic noise and microseismicity analyses were carried out on the continuously recorded seismic traces to characterize site stability and monitor its possible irreversible and reversible modifications driven by meteorological factors, in comparison with displacement measured on site. No irreversible modifications in the measured seismic parameters (i.e., natural resonance frequencies of the tower, seismic velocity changes, rupture-related microseismic signals) were detected in the monitored period, and no permanent displacement was observed at the tower top. Results highlighted, however, a strong temperature control on these parameters and unusual preferential vibration directions with respect to the literature case studies on nearly 2D rock columns, likely due the tower geometric constraints, as confirmed by 3D numerical modeling. A clear correlation with the tower displacement rate was found in the results, supporting the suitability of passive seismic monitoring systems for site characterization and early waning purposes. [ABSTRACT FROM AUTHOR]

We present a detailed description of the tectono-stratigraphic architecture of the eclogite-facies Internal Piedmont Zone (IPZ) metaophiolite, exposed in the Lanzo Valleys (Western Alps), which represents the remnant of the Jurassic Alpine Tethys. Seafloor spreading and mantle exhumation processes related to the Alpine Tethys evolution strongly conditioned the intra-oceanic depositional setting, which resulted in an articulated physiography and a heterogeneous stratigraphic succession above the exhumed serpentinized mantle. "Complete" and "reduced" successions were recognized, reflecting deposition in morphological or structural lows and highs, respectively. The "complete" succession consists of quartzite, followed by marble and calcschist. The "reduced" succession differs for the unconformable contact of the calcschist directly above mantle rocks, lacking quartzite and gray marble. The serpentinite at the base of this succession is intruded by metagabbro and characterized at its top by ophicalcite horizons. Mafic metabreccia grading to metasandstone mark the transition between the "complete" and "reduced" successions. The character of the reconstructed succession and basin floor physiography of the IPZ metaophiolite is well comparable with the Middle Jurassic–Late Cretaceous succession of both the Queyras Complex (External Piedmont Zone) and the Internal Ligurian Units (Northern Apennines) and with modern slow-spreading mid-ocean ridges. [ABSTRACT FROM AUTHOR]

This article deals with material research of selected types of quartz and quartzites in order to determine the priority of their use in the production of ferrosilicon and pure silicon, respectively. The highest quality quartzes and quartzites are commonly used in metallurgy, but not all types of these silicon raw materials are suitable for the production of ferrosilicon and pure silicon, despite their similar chemical composition. Behavior differences can be observed in the process conditions of heating and carbothermic production of ferrosilicon and silicon. These differences depend, in particular, on the nature and content of impurities, and the granularity (lumpiness) and microstructure of individual grains. The research focused primarily on determining the physicochemical and metallurgical properties of silicon raw materials. An integral part of the research was also the creation of a new methodology for determining the reducibility of quartzes (or quartzites), which could be used for real industrial processes and should be very reliable. The results of the laboratory experiments and evaluation of the physicochemical and metallurgical properties of the individual quartzes (or quartzites) are presented in the discussion. Based on comparison of the tested samples' properties, their priority of use was determined. This research revealed the highest quality in quartzite from Sweden (Dalbo deposit) and Ukraine (Ovruč deposit) and quartz from Slovakia (Švedlár deposit). The use of these raw materials in industrial conditions is expected to result in the achievement of better production parameters, such as higher yield and product quality and lower electricity consumption. [ABSTRACT FROM AUTHOR]

The metamorphic sole, tectonically welded to the base of the Samail ophiolite in a supra-subduction system, is assumed to play the main role in strain accumulation during later thrusting onto the Arabian Plate (i.e., during obduction). The present study deals with five quartzite samples representative of the upper amphibolite and lower greenschist facies parts of the sole. Whole-rock textures obtained by neutron time-of-flight technique were coupled with microstructural observation using electron backscatter diffraction analyses. The quartz microstructural fabrics and textures in the upper and lower parts of the sole represent grain boundary migration and [c]-in-Y textures and subgrain rotation recrystallization and {r}-in-Z textures, respectively. The shear sense in these samples points to top-to-the-SW to SSW shear. One sample of the upper part, yielding a higher calcite amount, is later overprinted by bulging and displays top-to-the-NNE shear. We postulate to differentiate two main deformation steps. The first is the overall present subgrain rotation and grain boundary migration recrystallization combined to top ~SW shear is related to the sole accretion to the ophiolite and the eventually following thrusting onto the Arabian Plate. The second is correlated to a post-obduction extensional top-to-the-NNE shearing, which is associated with tectonic thinning of the ophiolite and mainly documented in the underlying autochthonous units. [ABSTRACT FROM AUTHOR]

Plasma furnace processing has the potential to transform solar cell production. If informed decisions regarding silicon ore and mineral exploration can be made such that waste streams are also of high economic value, then production is ultimately more environmentally integrated. This study presents results from a spot check of the Kinnikinic Quartzite, ~4.5 km east of Arco, Butte County, Idaho (43.639091°, −113.243295°), for ore quality. The mineralogical and geochemical characteristics are explored within the context of a planned plasma furnace project at the sampled site and are compared to previous consulting reports. X-ray diffraction analysis detected only quartz, while scanning electron microscopy identified quartz grains, secondary quartz cement, trace amounts of potassium feldspar, minor iron oxides, and secondary illite. The bulk chemical characterization of 20 samples (including repeats) reports several wt. % variation in SiO2 from 96.47 to 99.66. Other notable chemical components include Al2O3, K2O, CaO, and Rb, all consistent with the presence of potassium feldspar (and illite). Gold concentrations vary from below detection (n = 12 out of 20) to a maximum concentration of 0.086 ppm. Total sum REE concentrations vary from 13 to 143 ppm. Conservatively and optimistically, assuming ideal extraction and recovery in plasma furnace operation, a resulting waste stream would have approximately 15.2 ppm (0.488 oz./metric ton) gold and 3400 ppm REE in the average waste. Gold (and REE extraction) may, however, be complicated by the presence of Fe and Cu if cyanide approaches were implemented. Gold concentrations are significantly lower than reported in previous work, warranting further characterization of this unit locally and regionally in order to characterize ore potential. This study works to demonstrate the possibility of evaluating other potential silicon ore units, such as the St. Peter Sandstone in Illinois and Missouri, for the co-production of materials in support of an emerging green economy. [ABSTRACT FROM AUTHOR]

Quartzites and paragneisses of the Archean granulite series of the Anabar Shield (Siberian Craton, Russia) are described geochemically. The Sm-Nd isotope systematics of the rocks and the U-Pb age (SHRIMP II) and geochemistry of zircons from quartzites and paragneisses are studied. Newly formed zircons from quartzites display geochemical characteristics of the magmatic type and were produced by rock anatexis upon granulite-facies metamorphism. The Paleoproterozoic age of the latest detrital zircons, 2250 ± 24 Ma, constrains the maximum age of sedimentary rock deposition. The anatectic rims around detrital zircons were formed ca. 2000 ± 9 Ma ago. The time of deposition of the sedimentary protolith of gneisses and quartzites falls within the age interval of the above-mentioned dates and is tentatively accepted as 2.1 Ga. The presence of Paleoproterozoic metasedimentary rocks in the Daldyn Group implies the tectonic heterogeneity of the series and the existence of Paleoproterozoic rock bodies among the predominant Archean rock sequences. [ABSTRACT FROM AUTHOR]

This article provides a geological review and results of the structural, metamorphic, and geochronological studies of the Pechenga frame outcrops located in the NW part of the Central-Kola terrain and the Ingozero massif outcrops situated in the northeastern part of the Belomorian mobile belt of the Kola Region (NW Baltic Shield). As a result of the work, the deformation scales and ages of the geological processes at the Neo-Archaean–Paleoproterozoic stage of the area's development were compiled, and the reference rocks were dated. The petrochemical and geochemical characteristics of the Ingozero rocks are similar to those of tonalite–trondhjemite–granodiorite (TTG) complexes established on other Archaean shields. The isotope U–Pb dating of individual zircon grains from the biotite gneisses provided the oldest age for magmatic protolith of the Ingozero gneisses, which is 3149 ± 46 Ma. Sm–Nd model ages showed that the gneisses protolite initial melt formed at 3.1–2.8 Ga. Ages of metamorphic processes were determined by using isotope U–Pb dating ID TIMS (isotope dilution thermal ionization mass spectrometry): Biotite gneisses—2697 ± 9 Ma; amphibole–biotite gneisses—2725 ± 2 Ma and 2667 ± 7 Ma; and biotite–amphibole gneisses 2727 ± 5 Ma. Ages of granitoids, which cut the deformed gneisses, are 2615 ± 8 Ma and 2549 ± 31 Ma for plagiogranites and pegmatoid veins in gneisses, respectively. The following age sequence of geological processes was established by using U–Pb zircon dating: 2.8 Ga—The time of the garnet–biotite gneiss metamorphism; 2722 ± 9 Ma—The granodiorite crystallization time; 2636 ± 41 Ma—The aplite emplacement age and 2620 ± 16 Ma—The age of pegmatites origin, which marked final stages of the Archaean evolution; 2587 ± 5 Ma—The age of gabbros emplacement and 2507 ± 7 Ma—The age of gabbros metamorphism; 2522–2503 Ma—The origin time of the iron quartzite interpreted as the age of gabbros and biotite gneiss metamorphism. [ABSTRACT FROM AUTHOR]

A detailed characterization of the mineralogy corresponding to the low-grade diagenetic-metamorphic sequence of the clastic rocks from the Beni Mezala antiform has allowed the processes implied in their origin to be stablished, integrating them in the geodynamic evolution of the Rif-Betic mountain range during the Alpine orogeny. A progressive evolution towards chemical and textural equilibrium was observed. The illite "crystallinity" (CIS) ranges from diagenetic-lower anchizone in Ghomaride complex (CIS: 1.50–0.37 Δ°2θ) to epizone in the deepest Federico units (CIS: 0.29–0.21 Δ°2θ). The main phyllosilicates in the diagenetic samples are illite (2M1-1M polytypes) and kaolinite, with mixed-layer illite/smectite and chlorite, but the mixed layers disappear in the lower anchizone samples, which show sudoite and dickite. Pyrophyllite is also present in the upper anchizone (0.43–0.29 Δ°2θ) whereas the epizone samples show muscovite (2M1-3T polytypes), chlorite, paragonite, and intermediate micas. The chlorite geothermometers give a T range of 150 to 400 °C, and the b parameter of 2M1 micas (8.992–9.029 Å) indicates low to intermediate pressure regional metamorphism (1–3 kbar) although the wide range of phengitic substitution in micas and the 3T polytype suggest a wider pressure range in coherence with the clockwise PTt evolution for the Rif Cordillera during the Alpine orogeny. [ABSTRACT FROM AUTHOR]

The Bargiolina quartzite from Monte Bracco (western Alps, northern Italy) represents one of the most important historical ornamental stones of the Piedmont region. Known and used since the prehistoric age as substituting material for chert, it was celebrated by Leonardo da Vinci, and exploited at least since the XIII century, peaking in the XX century. It was extensively used in the construction of basilicas and noble palaces by famous architects of Piedmontese Baroque, for internal and external stone cladding. There are four main commercial and chromatic varieties, and the main technical feature is the regular schistosity, to obtain very thin natural split slabs. The different varieties have a homogeneous mineralogical composition and microstructure: A fine and homeoblastic grain size, and a granular—lepidoblastic texture, with regularly spaced schistose domains. The main rock-forming minerals are quartz, phengite, small amounts of K-feldspar and traces of plagioclase and chlorite. The yield rate of quarries is about 20%, and the poor exploitation planning of the past led to only partly exploited quarry benches, with a very poor residual yield. The large amount of quartz-rich quarry waste and the presence of kaolin-rich gneisses suggests the potential for novel applications in the field of industrial minerals. [ABSTRACT FROM AUTHOR]

Crystal preferred orientation of 47 samples of quartzite and eight samples of associated marbles from the Bergell Alps have been analyzed with time-of-flight neutron diffraction and EBSD. The results show a clear distinction of texture types for quartzites transformed from Triassic sandstones and quartz layers in gneiss. Textures of Triassic quartzites are overall weak and display a maximum of c-axes perpendicular to the foliation or a crossed girdle perpendicular to the lineation. Pole figures for positive rhombs {10 1 ¯ 1} show a maximum perpendicular to the foliation and negative rhombs {01 1 ¯ 1} generally display a minimum. Based on polycrystal plasticity models this texture type can be attributed to a combination of basal and rhombohedral slip. Asymmetry of the distributions is attributed to simple shear and local strain heterogeneities. The relatively weak texture is partially caused by muscovite limiting dislocation motion and grain growth, as well as adjacent layers of marble that accommodate significant strain. Most quartz layers in gneiss, including mylonites, display a texture with a-axes parallel to the lineation and a c-axis maximum in the intermediate fabric direction. This texture type can be attributed to dominant prismatic slip. Many samples are recrystallized and recrystallization appears to strengthen the deformation texture. The study shows good agreement of neutron diffraction and EBSD. Neutron diffraction data average over larger volumes and maximum pole densities are generally lower and more representative for the bulk material. With EBSD the microstructure and mechanical twinning can be quantified. [ABSTRACT FROM AUTHOR]