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This work aims to understand the distribution and migration mechanisms of U and Mo between surface sediment and water in acid mine drainage (AMD) regions near a molybdenum mining region. A series of river sediment and water samples near the Jinduicheng mining area, one of the largest deposits of molybdenite ore in Asia, were collected and analyzed. Our results indicate that: (1) The pH value of river water samples increases with distance from upstream to downstream, while the pH has poor correlation with Mo and U; (2) The content of Mo and U in the sediment are significantly higher than the background value, which suggests potential pollution; (3) The content of Mo and U in the water and sediments in the lower reaches of the Wenyu river is significantly linearly related with the distance from the mining area, suggesting that AMD is a potential source; (4) BCR analysis shows that Mo in river sediments mainly existed as the residual, while U mainly existed as the non-residual; (5) The distribution coefficient Kd(Mo) exceeds Kd(U), indicating that Mo is enriched in sediments while U is more prone to porewater. [ABSTRACT FROM AUTHOR]

The oxidation/weathering of molybdenite (MoS2) is too slow to be monitored, even under pure oxygen and high temperatures, while it proceeds rapidly through humid air. The adsorption of water molecules on molybdenite is necessary for the wet oxidation/weathering of molybdenite. Therefore, we employ kinetic Monte Carlo modeling to clarify the adsorption isotherm, site preferences and kinetics of water on different surfaces of molybdenite. Our results indicate that (1) the adsorption capacity and adsorption rate coefficient of H2O on the (110) surface are significantly larger than those on the (001) surface at a temperature of 0~100 °C and a relative humidity of 0~100%, suggesting that the (110) surface is the predominant surface controlling the reactivity and solubility of molybdenite in its interaction with water; (2) the kinetic Monte Carlo modeling considering the adsorption/desorption rate of H2O, dissociation/formation rate of H2O and adsorption/desorption of dissociated H indicates that the adsorption and dissociation of H2O on the (110) surface can be completed in one microsecond (ms) at 298 K and in wet conditions; (3) the adsorption and dissociation of H2O on molybdenite are not the rate-limiting steps in the wet oxidation/weathering of molybdenite; and (4) kinetic Monte Carlo modeling explains the experimental SIMS observation that H2O and OH (rather than H+/H− or H2O) occupy the surface of MoS2 in a short time. This study provides new molecular-scale insights to aid in our understanding of the oxidation/weathering mechanism of molybdenite as the predominant mineral containing molybdenum in the Earth's crust. [ABSTRACT FROM AUTHOR]

The paleosedimentary environment and paleoclimate of the Neogene Guantao Formation in the Liaodong sub-uplift of Bohai Bay Basin in China, which is an important oil and gas exploration horizon, are not clear owing to the lack of quantitative analysis. The paleosedimentary environment and paleoclimate can be qualitatively or semi-quantitatively reconstructed by sedimentary geochemical indicators sensitive to the environment and climate. Based on the evaluation of whether the elements and isotopes can effectively record paleosedimentary environment and paleoclimate information or not, the paleoclimate (temperature and humidity), paleoenvironment (salinity, water depth, redox conditions), and evolution of the paleoenvironment and paleoclimate are studied by analyzing the trace elements, carbon and oxygen isotopes, strontium isotopes, whole-rock mineral compositions, and clay minerals of mudstones of the Guantao Formation in the Liaodong sub-uplift, Bohai Bay Basin. The study results show that (1) according to the trace element distribution patterns, high concentrations of continental elements (Ti, Zr, Th), clay minerals, and detrital content, the Guantao Formation is a product of proximal deposits, and the provenance mainly originates from the intermediate–acidic magmatic rocks near surrounding uplifts. (2) The paleoclimate during the sedimentation of the Guantao Formation was mainly semi-arid and semi-humid, as revealed by the Sr/Cu ratio. However, the high Rb/Sr and 87Sr/86Sr ratios demonstrate that the paleoclimate is relatively warm and humid. (3) The paleosedimentary temperature calculated by the Sr content and δ18O is roughly 30 °C, indicating that the Guantao Formation was deposited in a subtropical to tropical climate. (4) The Guantao Formation was deposited in continental freshwater according to the Li, Ni, and Sr content, Sr/Ba ratios, 87Sr/86Sr ratios, and salinity index Z. (5) The water depth of the paleoenvironment of the Guantao Formation is mainly in nearshore shallow water, reflected by the Mn/Ti ratio and calculated by the Co content, and the oxidizing condition of the paleoenvironment of the Guantao Formation, reflected by the U/Th, V/Cr, and Ni/Co ratios, is in a good coupling relationship with this environment. (6) As revealed by the variations in the geochemical data in the section, the temperature, humidity, and water depth of the Guantao Formation gradually increased from the early to late period, while the salinity gradually decreased, and the chemical weathering effect gradually increased. [ABSTRACT FROM AUTHOR]

Air pollution is becoming increasingly serious along with social and economic development in the southwest of China. The distribution characteristics of particle matter (PM) were studied in Chengdu from 2016 to 2017, and the changes of PM bearing water-soluble ions and heavy metals and the distribution of secondary ions were analyzed during the haze episode. The results showed that at different pollution levels, heavy metals were more likely to be enriched in fine particles and may be used as a tracer of primary pollution sources. The water-soluble ions in PM2.5 were mainly Sulfate-Nitrate-Ammonium (SNA) accounting for 43.02%, 24.23%, 23.50%, respectively. SO42−, NO3−, NH4+ in PM10 accounted for 34.56%, 27.43%, 19.18%, respectively. It was mainly SO42− in PM at Clean levels (PM2.5 = 0~75 μg/m3, PM10 = 0~150 μg/m3), and mainly NH4+ and NO3− at Light-Medium levels (PM2.5 = 75~150 μg/m3, PM10 = 150~350 μg/m3). At Heavy levels (PM2.5 = 150~250 μg/m3, PM10 = 350~420 μg/m3), it is mainly SO42− in PM2.5, and mainly NH4+ and NO3− in PM10. The contribution of mobile sources to the formation of haze in the study area was significant. SNA had significant contributions to the PM during the haze episode, and more attention should be paid to them in order to improve air quality. [ABSTRACT FROM AUTHOR]

Cd and Pb in farmland topsoil are controlled by many factors. To identify the source of potential toxic metals in the farmland topsoil around Mianyuan River, the chemical analysis and multivariate statistical analysis are performed in this study. The results indicate the following: (1) The concentration of Cd and Pb in soil exceed the background value of Chinese soil elements. (2) Cd is significantly enriched in the whole region and Pb is locally enriched, both of them are more or less influenced by human activities. (3) The contents of Cd and Pb increase significantly following the flow direction of river. (4) P b isotope analysis indicates that the main source of Pb in the soil include the air dust, coal and phosphate plant, and the contribution of them decreases successively. (5) Linear correlation analysis and principal component analysis show that the main sources of Cd in the soil are mining phosphate rock, air dust, phosphate plant and coal mining. [ABSTRACT FROM AUTHOR]