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This article analyses the possibility of using hydrogen as fuel in furnaces used in the metallurgical industry. The research was conducted for a selected continuous furnace. For this purpose, based on actual measurements, a heat balance of the furnace was prepared to determine its energy indicators. These values were used to verify the developed numerical model in IPSEpro 7.0 software. Numerical calculations were performed for three variants: pure natural gas; 30% hydrogen, 70% natural gas; and 100% hydrogen. The determined values of gas and combustion air streams allowed for achieving the assumed charge temperature in the heating technology. Calculations of the impact of the excess combustion air ratio on process parameters were also carried out. It was found that no changes are required in the exhaust gas removal system, but verification of the fan supplying air to cool the exhaust gases before the recuperator is necessary. The amount of hydrogen required to fuel the continuous furnace also increases significantly (nearly threefold), which may also affect operating costs. At the same time, the emission of carbon dioxide into the atmosphere is completely reduced, which may be an important criterion when considering modernization options for heating furnaces in the metallurgical industry. [ABSTRACT FROM AUTHOR]

The paper proposes applying an in-house mathematical model of a liquid flat-plate solar collector to calculate the collector time constant. The described model, proposed for the first time in an earlier study, is a one-dimensional distributed parameter model enabling simulations of the collector operation under arbitrarily variable boundary conditions. The model is based on the solution of energy balance equations for all collector components. The formulated differential equations are solved iteratively using an implicit difference scheme. To obtain a stable numerical solution, it is necessary to use appropriate steps of time and spatial division. These were found by comparing the results obtained from the model with the results of the analytical solution available in the literature for the transient state, which constitutes the novelty of the present study. The accuracy of the results obtained from the model was verified experimentally by comparing the measured and calculated history of the fluid temperature at the outlet of the collector. The calculation of the collector time constant is proposed in the paper as an example of the model's practical application. The results of the time constant calculation were compared with the values obtained experimentally on the test stand. This is another novelty of the presented research. The analysed collector instantaneous efficiency was then calculated for selected outdoor conditions. The presented mathematical model can also be used to verify the correctness of the collector operation. By comparing, on an ongoing basis, the measured and calculated values of the fluid temperature at the collector outlet, conclusions can be drawn about the process of solar glass fouling or glycol gelling. The simplicity of the model and the low computational demands enable such comparisons in an online mode. [ABSTRACT FROM AUTHOR]

This study investigates the crucial role of Carbon Capture and Storage (CCS) technology in mitigating CO2 emissions from Poland's power systems, which is essential not only for meeting climate targets but also for maintaining energy security in the country. Acknowledging natural gas as a transitional fuel, the focus is on evaluating the decarbonization potential of the natural gas combined cycle (NGCC) power plant. The NGCC with and without an amine-based carbon capture unit was modeled using IPSEpro (SimTech, version 7.0). It was found that the annual CO2 emission from 435.68 MWe (net) NGCC can be reduced from 1,365,501 tons (357.8 kgCO2/MWh) to 136,556 tons (42.9 kgCO2/MWh). On the other hand, the CCS reduced the net electric power of the NGCC from 435.68 MW to 363.47 MW and the net energy efficiency from 55.60% to 46.39%. Nonetheless, these results demonstrate the potential of using the amine-based CO2 capture technology in NGCC systems. This is especially important in the context of the decarbonization of the Polish power system. [ABSTRACT FROM AUTHOR]

Broadly defined climate protection is a powerful incentive in the search for environmentally friendly refrigeration technologies. Adsorption chillers are considered to be one such technology; however, their main disadvantages include a low cooling capacity, a low energy efficiency ratio (EER), and cyclic operation. Thus, a great deal of effort is being put into improving adsorption-chiller performance. In this paper, the influence of the spray angle, the number of nozzles, and the water flow rate through the nozzles on adsorption-chiller performance was investigated. Adsorption-chiller performance was investigated mainly in terms of the cooling capacity (CC), the energy efficiency ratio (EER), and the specific cooling power (SCP). The results indicated that the chiller's cooling capacity increased from about 210 W to 316 W and that the EER increased from 0.110 to 0.167 when the spray angle of the nozzles was increased from 90° to 120°. It was also reported that increasing the flow rate of water through the nozzles did not improve the average cooling capacity or the other performance parameters but resulted in more stable operation of the chiller. Additionally, using six nozzles instead of three improved the average cooling capacity and EER tenfold. [ABSTRACT FROM AUTHOR]

Adsorption systems are alternatives to compressor cooling systems. Apart from many advantages, these systems are characterized by low COP and SCP parameters. One of the most promising options to improve the performance of adsorption chillers is the replacement of the stationary bed with a fluidized one. A fluidized bed significantly increases the heat and mass transfer within the bed, enables better contact between gas and solid phases, and results in the proper mixing of adsorbent particles. This paper presents the possibility of using fluidized beds in adsorption chillers. This paper shows the results of CFD numerical modelling of the operation of a fluidized bed for an adsorption chiller and simulations of the bed temperature profiles during the adsorption and desorption processes of sorbent in a fluidized bed. This article presents an analysis of CFD simulation results for the optimal angle of heat exchangers. [ABSTRACT FROM AUTHOR]

Adsorption cooling technology is a promising alternative to replace conventional solutions. However, adsorption chillers still need to be improved in terms of performance parameters. One of the most important factors affecting their efficiency is the characteristics of the adsorbent, which should have the highest adsorption capacity and enable efficient heat transport in the bed. The objective of this paper is to present current developments in the field of composite sorbents with silica gel matrix as modern and very promising materials and then perform a detailed analysis of them. The paper summarises the methods of synthesis of composite sorbents and the current knowledge concerning these materials. The analysis focuses on a comparison of the available data, particular taking into account the types of matrixes, so that the analysis provides a clear and qualitative basis for further research. As a result of exploring the state of the art, this subject is found to be insufficiently described; therefore, these materials are comprehensively analysed in terms of their properties and the impact of their use on the COP (coefficient of performance) and SCP (specific cooling power) of adsorption chillers. Based on the analysis of the literature, the most promising directions for further research are also indicated. [ABSTRACT FROM AUTHOR]

Many attempts are made worldwide to create cheap, efficient, and eco-friendly water desalination systems. Passive solar stills (SS) are considered to be such. This paper presents the results of the experimental and theoretical investigation of the effects of using phase-change materials (PCM) on the performance of SS. The experiments were conducted for two paraffin waxes, as PCM and 1.0, 2.5, and 5.0 kg of PCM were used. The results of the experimental studies were used to validate a mathematical model, which was based on the energy balance ordinary differential equations. The equations were solved numerically since the approximate solutions obtained numerically are sufficient and relatively simple as compared to the exact analytical solutions. A theoretical analysis was then carried out and a novel and detailed dependence on the water evaporation rate as a function of water temperature and the difference between water and cover temperature was determined. It was also found that the productivity of the SS with PCM strongly depends on the operating conditions. For uniform initial temperatures of the SS, its productivity decreases with an increasing PCM-to-water mass ratio, and the maximum decrease is 10.8%. If the SS is not thermally insulated, the PCM can take the role of a thermal insulator and increase productivity by 1.1%, but there is an optimal PCM-to-water mass ratio. The greatest increase in productivity, by up to 47.1%, can be obtained when the PCM is heated outside the SS and inserted into the SS when the water temperature starts to decrease. In this case, the productivity increases with the increasing PCM-to-water mass ratio. These outcomes fill a knowledge gap caused by a lack of justification for why in some cases, the application of PCM fails to improve the productivity of SS. [ABSTRACT FROM AUTHOR]

Adsorption chillers produce cold energy, using heat instead of electricity, thus reducing electrical energy consumption. A major industrial waste, fly ash, can be converted to zeolite and used in adsorption chillers as an adsorbent. In this research, three different types of zeolites were synthesised from fly ash via a hydrothermal reaction in an alkaline solution (NaOH). The obtained samples (Na-A zeolites) were modified with K2CO3 to increase the water adsorption capacity of these samples. Phase and morphology analyses shows that desired zeolites formed properly but other crystalline phases also exist along with nonporous amorphous phases. The determined specific surface areas for Na-A zeolite (12 h) and Na-A zeolite (24 h) are 45 m2/g and 185 m2/g respectively, while the specific surface area for synthesized 13X zeolite is almost negligible. Water-isotherm for each of these samples was measured. Considering the application of adsorption chillers, average adsorption capacity was very low, 1.73% and 1.27%, respectively, for the two most probable operating conditions for synthesized 13X zeolite, whereas no water was available for the evaporation from Na-A zeolite (12 h) and Na-A zeolite (24 h). This analysis implies that among the synthesized materials only 13X zeolite has a potential as an adsorber in sorption chillers. [ABSTRACT FROM AUTHOR]

Solar-powered adsorption chillers are a particularly interesting alternative to energy-intensive conventional refrigeration systems. Integration of the adsorption chiller with solar collectors is a very promising concept since the increase in solar radiation coincides with the increased demand for cooling. Such a solution is very economical and environmentally friendly. It also fits in with current trends related to energy policy and sustainable development. The article presents the results of tests conducted for a two-bed adsorption chiller integrated with solar collectors. The tests were performed on selected days of the summer period (July and August) at the KEZO Research Centre PAS in Jablonna (Poland). Based on the results obtained, the performance parameters of the adsorption chiller were determined, and the problems associated with the integration of all components of the system were identified and discussed. The values of the determined Coefficient of Performance (COP) and cooling capacity for the tested adsorption chiller are, depending on the day on which the tests were conducted, from 0.531 to 0.692 and from 5.16 kW to 8.71 kW, respectively. Analysis of the test results made it possible to formulate conclusions related to the design of integrated systems of adsorption chillers with solar collectors. [ABSTRACT FROM AUTHOR]

This work focuses on the impact of carrier gas on the quantity and quality of pyrolytic products received from intermediate pyrolysis of the brewer's spent grain. In this study, three types of carrier gases were tested: argon, nitrogen, and carbon dioxide at three temperatures of 500, 600, and 700 °C. On the basis of the process conditions, the yield of products was determined. The ultimate analysis of the char was performed, and for selected chars, the combustion properties were determined. Gas chromatography of the organic fraction of oil was performed, and the compounds were determined. Additionally, microscale investigation of the spent grain pyrolysis was performed by thermogravimetric analysis. The results showed that there were no significant differences in product yields in various atmospheres. Char yield changed only with temperature from 28% at 500 °C up to 19% at 700 °C. According to ultimate analysis, the char from CO2 pyrolysis was approximately 2% richer in carbon and this fact did not influence on the combustion properties of the char. The oil fraction was characterized mainly by acids with a maximum content of 68% at 600 °C in an argon atmosphere and the acid concentration depended on the carrier gas as follows line: Ar > N2 > CO2. [ABSTRACT FROM AUTHOR]

Due to a high risk of power outages, a heat-driven adsorption chillers are gaining the attention. To increase the efficiency of the chiller, new adsorbents must be produced and examined. In this study, four newly developed silica–based porous materials were tested and compared with silica gel, an adsorber commonly paired with water. Extended sorption tests using mercury intrusion porosimetry, gas adsorption, and dynamic vapor sorption were performed. The morphology of the samples was determined using a scanning electron microscope. The thermal properties were defined using simultaneous thermal analysis and a laser flash method. Metal organic silica (MOS) nanocomposites analysed in this study had thermal properties similar to those of commonly used silica gel. MOS samples have a thermal diffusivity coefficient in the range of 0.17–0.25 mm2/s, whereas silica gel of about 0.2 mm2/s. The highest water adsorption capacity was measured for AFSMo-Cu and equal to 33–35%. For narrow porous silica gel mass uptake was equal about 25%. In the case of water adsorption, it was observed that the pore size of the sorbent is essential, and adsorbents with pore sizes higher than 5 nm, are most recommended in working pairs with water. [ABSTRACT FROM AUTHOR]

This paper presents experimental determination of the heat transfer coefficient and the friction factor in an internally rifled tube. The experiment was carried out on a laboratory stand constructed in the Department of Energy of the Cracow University of Technology. The tested tube is used in a Polish power plant in a supercritical circulating fluidized bed (CFB) boiler with the power capacity of 460 MW. Local heat transfer coefficients were determined for Reynolds numbers included in the range from ~6000 to ~50,000, and for three levels of the heating element power. Using the obtained experimental data, a relation was developed that makes it possible to determine the dimensionless Chilton–Colburn factor. The friction factor was also determined as a function of the Reynolds number ranging from 20,000 to 90,000, and a new correlation was developed that represents the friction factor in internally ribbed tubes. The local heat transfer coefficient and the friction factor obtained during the testing were compared with the CFD modelling results. The modelling was performed using the Ansys Workbench application. The k-ω, the k-ε and the transition SST (Share Stress Transport) turbulence models were applied. [ABSTRACT FROM AUTHOR]

In the face of increasing demands with regard to the share of renewable energy sources in the energy mix, adsorption chillers are becoming a potentially important part of the energy transition. A key component of this type of equipment is the heat exchanger in the adsorption bed, the design of which affects both heat and mass transfer. This study includes an analysis of the geometry and materials used to manufacture such heat exchangers. The geometry analysis is mainly based on the evaluation of the impact of the different dimensions of the exchanger components on heat and mass transfer in the bed. The second part of the study focuses on material-related issues where the main emphasis is on the analysis of the thermal inertia of the exchanger. The paper analyses the latest research on the design of exchangers in adsorption beds, mainly from 2015–2021. Currently, the commonly used SCP and COP coefficients and various test conditions do not provide sufficient information for comparative analysis of adsorption bed heat exchangers, so the authors propose to introduce a new index for the evaluation of heat exchangers in terms of the effect of the design parameters on the energy efficiency of an adsorption chiller. [ABSTRACT FROM AUTHOR]

Adsorption chillers with desalination functionality, being devices characterised by very low electricity consumption, provide an alternative to conventional sources of cooling and water. The option of desalinating water means that the use of a single device enables obtaining two useful products. Adsorption chillers are not widely used at present. due to their low performance characteristics; these are, however, constantly being improved. This paper presents a verification of the possibility of increasing the cooling coefficient of performance (COP) and specific cooling power (SCP) of a laboratory adsorption chiller by optimising the length of cycle times and using a copper additive to silica gel with a mass fraction of 15% to increase heat transport in the bed. The choice of copper among other considered additives was determined by the conclusions from the research on the sorption kinetics of various mixtures, price and availability, and a high thermal conductivity. The device was operated in a two-bed mode aimed at producing cooling. The adsorbate was distilled water. The results were compared with those obtained under similar conditions when the beds were only filled with silica gel. As a result of the testing, it was found that the use of the copper additive with the sorbent increased both the COP and SCP. The tests were performed for different cycle times, of 100, 200, 300 and 600 s. With increasing cycle time COP also increased. In contrast, the specific cooling power increased only up to a certain point, whereafter its value decreased. [ABSTRACT FROM AUTHOR]

Adsorption refrigeration systems are promising, sustainable solutions for many cooling applications. The operating range and the performance of an adsorption cooling cycle are strongly dependent on the properties of adsorbents, adsorbates, and bed coatings. Therefore, further research and analysis may lead to improved performance of adsorption coolers. In this paper, studies on working pairs using natural refrigerants and the properties of adsorbent coatings were reviewed. The selected working pairs were then thermodynamically characterised and ranked in terms of refrigerant evaporation temperature values. This was found to be a key parameter affecting the applicability of a given adsorbent/adsorbate pair and the value of SCP (Specific Cooling Power), COP (Coefficient of Performance) parameters, which are now commonly used comparison criteria of adsorption chillers. In the analysis of the coating studies, the focus was on the effect of individual parameters on the performance of the cooling system and the effect of using coated beds compared to packed beds. It was found that a fundamental problem in comparing the performance of different cooling systems is the use of different operating conditions during the tests. Therefore, the analysis compares the performance of the systems along with the most important thermodynamic cycle parameters for the latest studies. [ABSTRACT FROM AUTHOR]

The article presents experimental results of the metal-based and carbon nanotube additives influence on sorption kinetics of a silica-gel-based adsorption bed in an adsorption chiller. The purpose of the doping is to improve the efficiency of sorption processes within the bed by use of metallic and non-metallic additives characterized by higher thermal diffusivity than basic adsorption material. The higher the thermal conductivity of the bed, the faster the sorption processes take place, which directly translates into greater efficiency of the refrigerator. In this study, sorption kinetics of pure silica gel sorbent doped with a given amount of aluminum (Al) and copper (Cu) powders and carbon nanotubes (CNT) were analyzed. The tests were performed on DVS Dynamic Gravimetric Vapor Sorption System apparatus used for dynamic vapor sorption measurements. A decrease in the amount of adsorbed water was observed with an increase in the mass share of the additives in the performed studies. Experimental results show that, CNTs seems to be the most promising additive as the sorption process time was reduced with the smallest decrease in water uptake. Any significant reduction of adsorption time was noted in case of the Al addition. Whereas, in case of Cu doping, delamination of the mixture was observed. [ABSTRACT FROM AUTHOR]

The paper is focused on the idea of multi-fuel combustion in a large-scale circulating fluidized bed (CFB) boiler. The article discusses the concept of simultaneous coal and syngas combustion. A comprehensive three-dimensional computational fluid dynamics (CFD) model is developed, which allows us to describe complex phenomena that occur in the combustion chamber of the CFB boiler burning coal and syngas produced from coal sludge. [ABSTRACT FROM AUTHOR]

This paper presents the results of numerical computations for a large-scale OFz-425 CFB (circulating fluidized bed) boiler utilizing coal and syngas. Four different operating scenarios are considered, including the reference variant, corresponding to the conventional, mono-combustion of bituminous coal, and three tests involving replacement of secondary air and part of the coal stream with syngas fed by start-up burners. Pressure, gas velocity, temperature, and carbon dioxide distribution in the combustion chamber are discussed in the paper. The results indicate that the syngas supply leads to an increase in local temperature and carbon dioxide concentrations. The proposed concept is not advisable as it may lead to frequent emergency stops of the CFB boiler. [ABSTRACT FROM AUTHOR]

Adsorption chillers are characterized by low electricity consumption, lack of moving parts, and high reliability. The disadvantage of these chillers is their large weight due to low adsorbent sorption capacity. Therefore, the attention is turned to finding a sorbent with a high water sorption capacity and enhanced thermal conductivity to increase chiller efficiency. The article discusses the impact of selected adhesives used for the production of an adsorption bed in order to improve heat exchange on its surface. Experiments with silica gel with three commercial types of glue on metal plates representing heat exchanger were performed. The structure of samples was observed under a microscope to determine the coverage of adsorbent by glue. To determine the kinetics of the free adsorption, the amounts of moisture adsorbed and the desorption dynamics the prepared samples of coated bed on metal plates were moisturized and dried in a moisture analyzer. Samples made of silica gel mixed with the adhesive 2-hydroxyethyl cellulose, show high adsorption capacity, low dynamic adsorption, and medium dynamic desorption. Samples containing adhesive poly(vinyl alcohol) adsorb less moisture, but free adsorption and desorption were more dynamic. Samples containing the adhesive hydroxyethyl cellulose show lower moisture capacity, relatively dynamic adsorption, and lower dynamic desorption. [ABSTRACT FROM AUTHOR]