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A high proportion of renewable generators are widely integrated into the power system. Due to the output uncertainty of renewable energy, the demand for flexible resources is greatly increased in order to meet the real-time balance of the system. But the investment cost of flexible resources, such as energy storage equipment, is still high. It is necessary to propose a method for determining the capacity of energy storage scientifically. An optimization and planning method of energy storage capacity is proposed. It is characterized by determining the optimal capacity of energy storage by carrying out 8760 hours of time series simulation for a provincial power grid with energy storage. Firstly, the current situation of power supply and demand for provincial power grids is analyzed. The difficulty of realizing a power balance at different time scales is analyzed. Then, the source load balancing solutions at different time scales are proposed. The difficulty of a long-term power balance can be alleviated by flexibly adjusting the power on the tie-line of the provincial power grid. And the difficulty of a short-term power balance can be met through energy storage. In addition, an optimal planning model of an energy storage system is established with the power supply cost as the objective function. The optimal capacity of the energy storage is determined by comparing the objective function of different planning schemes. Finally, a case study is carried out. It is found that flexible adjustment of interprovincial interconnection lines can reduce the maximum demand for electricity from 8.439 billion kWh to 2.299 billion kWh. At the same time, the curtailment ratio of renewable electricity can be decreased from 12.6% to 5.0% by using energy storage. However, the average power supply cost of the system gradually increases from 0.307 CNY/kWh to 0.485 CNY/kWh. It is necessary to fully tap into the various values of energy storage equipment. [ABSTRACT FROM AUTHOR]

Blend proton exchange membranes (BPEMs) were prepared by blending sulfonated poly(aryl ether nitrile) (SPAEN) with phosphorylated poly(vinylbenzyl chloride) (PPVBC) and named as SPM-x%, where x refers to the proportion of PPVBC to the weight of SPAEN. The chemical complexation interaction between the phosphoric acid and sulfonic acid groups in the PPVBC–SPAEN system resulted in BPEMs with reduced water uptake and enhanced mechanical properties compared to SPAEN proton exchange membranes. Furthermore, the flame retardancy of the PPVBC improved the thermal stability of the BPEMs. Despite a decrease in ion exchange capacity, the proton conductivity of the BPEMs in the through-plane direction was significantly enhanced due to the introduction of phosphoric acid groups, especially in low relative humidity (RH) environments. The measured proton conductivity of SPM-8% was 147, 98, and 28 mS cm−1 under 95%, 70%, and 50% RH, respectively, which is higher than that of the unmodified SPAEN membrane and other SPM-x% membranes. Additionally, the morphology and anisotropy of the membrane proton conductivities were analyzed and discussed. Overall, the results indicated that PPVBC doping can effectively enhance the mechanical and electrochemical properties of SPAEN membranes. [ABSTRACT FROM AUTHOR]

The energy crisis and environmental issues are becoming more severe due to the long-term consumption of fossil fuels. Therefore, novel energy-conversion devices with high energy density and environmental friendliness are expected to provide reliable alternatives to traditional fossil-based energy systems. However, because of the inevitable use of costly precious metals as the electrode catalysts for such devices, their popularization is seriously hindered. Transition metal nitrides (TMNs) exhibit similar surface and adsorption properties to noble metals because the atomic distance between metal atoms increases and the d-band center of metal atoms downshifts after nitrogen atoms enter the metal lattice. TMNs have become one of the best electrode materials to replace noble metal-based electrocatalysts in next-generation energy-storage and energy-conversion devices. In this review, the recent developments in the electrocatalytic application of TMNs are covered. First, we discuss the structure and activity origin of TMNs and introduce the common synthesis methods for the preparation of TMNs. Subsequently, we illustrate the applications of mono-metallic TMNs and multi-metallic TMNs in oxygen-reduction reaction, oxygen-evolution reaction, and bifunctional oxygen reduction and evolution reactions. Finally, we summarize the challenges of TMNs encountered at the present stage, and expect their future development. [ABSTRACT FROM AUTHOR]

Electrochemical water splitting has wide applicability in preparing high-density green energy. The Proton exchange membrane (PEM) water electrolysis system is a promising technique for the generation of hydrogen due to its high electrolytic efficiency, safety and reliability, compactness, and quick response to renewable energy sources. However, the instability of catalysts for electrochemical water splitting under operating conditions limits their practical applications. Until now, only precious metal-based materials have met the requirements for rigorous long-term stability and high catalytic activity under acid conditions. In this review, the recent progress made in this regard is presented and analyzed to clarify the role of precious metals in the promotion of the electrolytic decomposition of water. Reducing precious metal loading, enhancing catalytic activity, and improving catalytic lifetime are crucial directions for developing a new generation of PEM water electrolysis catalysts. A summary of the synthesis of high-performance catalysts based on precious metals and an analysis of the factors affecting catalytic performance were derived from a recent investigation. Finally, we present the remaining challenges and future perspectives as guidelines for practical use. [ABSTRACT FROM AUTHOR]

Different from the traditional concrete mixing procedure, the innovative post-filling coarse aggregate concrete (PFCC) reduces the cost of pumping concrete by increasing the coarse aggregate content and reducing the usage of cement. Previous studies have shown that PFCC enhances the compressive strength, elastic modulus, and flexural strength of concrete. In this paper, the shear behavior of 13 post-filling coarse aggregate concrete beams and 3 control beams was tested to determine the relationships between the shear performance of the beam and the post-filling coarse aggregate ratio, concrete strength grade, shear span ratio and stirrup reinforcement ratio. The results showed that the ultimate shear capacity of beam specimen increases first and then decreases with the increase in post-filling coarse aggregate ratio, reaching the maximum at 15% post-filling ratio. The results also indicated that the ultimate shear capacity of the beam increases with the increase in concrete strength grade and stirrup ratio. However, experimental results exhibited that the ultimate shear capacity decreases as the shear span ratio increases. This study provides a reference for the application of post-filling coarse aggregate concrete in engineering practice. [ABSTRACT FROM AUTHOR]

Flows of two immiscible liquids through inclined pipes are often encountered in industrial processes. The interfacial characteristics in inclined pipes are of significance for understanding the mechanism of flow pattern transition and modeling the flow parameters. This paper developed a novel experimental technique to access the interface characteristics of liquid-liquid flows, during which optical and electrical methods were successfully combined by matching the refractive index and conductivity of the flows. A planar laser-induced fluorescence (PLIF) system was set up with a continuous laser and high-speed camera. Organic and aqueous phases were chosen to match refractive indices. The liquid-liquid interface in the middle of the pipe could be clearly visualized by the PLIF system. Meanwhile, two conductance parallel-wire array probes (CPAPs) were designed to reconstruct the liquid-liquid interfaces at upward and downward pipe cross-sections. The performances of the CPAP were validated using the PLIF results and employed to investigate the liquid-liquid interfacial structures. The interfacial shape and its instability were uncovered using the reconstructed interfaces by the CPAPs. [ABSTRACT FROM AUTHOR]

Polyethylene (PE) membranes coated with nano-Al2O3 have been improved with water-dispersed poly(p-phenylene terephthamide) (PPTA). From the scanning electron microscope (SEM) images, it can be seen that a layer with a honeycombed porous structure is formed on the membrane. The thus-formed composite separator imbibed with the electrolyte solution has an ionic conductivity of 0.474 mS/cm with an electrolyte uptake of 335%. At 175 °C, the assembled battery from the synthesized composite separator explodes at 3200 s, which is five times longer than the battery assembled from an Al2O3-coated polyethylene (PE) membrane. The open circuit voltage of the assembled battery using a composite separator drops to zero at 600 s at an operating temperature of 185 °C, while the explosion of the battery with Al2O3-coated PE occurs at 250 s. More importantly, the interface resistance of the cell assembled from the composite separator decreases to 65 Ω. Hence, as the discharge rate increases from 0.2 to 1.0 C, the discharge capacity of the battery using composite separator retains 93.5%. Under 0.5 C, the discharge capacity retention remains 99.4% of its initial discharge capacity after 50 charge–discharge cycles. The results described here demonstrate that Al2O3/PPTA-coated polyethylene membranes have superior thermal stability and ion diffusion. [ABSTRACT FROM AUTHOR]

Polyethylene (PE) membranes coated with nano-Al 2 O 3 have been improved with water-dispersed poly(p-phenylene terephthamide) (PPTA). From the scanning electron microscope (SEM) images, it can be seen that a layer with a honeycombed porous structure is formed on the membrane. The thus-formed composite separator imbibed with the electrolyte solution has an ionic conductivity of 0.474 mS/cm with an electrolyte uptake of 335%. At 175 °C, the assembled battery from the synthesized composite separator explodes at 3200 s, which is five times longer than the battery assembled from an Al 2 O 3 -coated polyethylene (PE) membrane. The open circuit voltage of the assembled battery using a composite separator drops to zero at 600 s at an operating temperature of 185 °C, while the explosion of the battery with Al 2 O 3 -coated PE occurs at 250 s. More importantly, the interface resistance of the cell assembled from the composite separator decreases to 65 Ω. Hence, as the discharge rate increases from 0.2 to 1.0 C, the discharge capacity of the battery using composite separator retains 93.5%. Under 0.5 C, the discharge capacity retention remains 99.4% of its initial discharge capacity after 50 charge-discharge cycles. The results described here demonstrate that Al 2 O 3 /PPTA-coated polyethylene membranes have superior thermal stability and ion diffusion.